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Modulus maximum

Oscillatory shear data for two nearly monodisperse linear polymers with M/Me = 40, reduced by their terminal loss modulus maximum. Triangles are the storage modulus G and circles are the loss modulus G". Filled symbols are for polybutadiene with... [Pg.385]

Figure 1 PE and TPS-based composites. From top to the bottom modulus, maximum strength and elongation at break ratios versus fibre volume fraction... Figure 1 PE and TPS-based composites. From top to the bottom modulus, maximum strength and elongation at break ratios versus fibre volume fraction...
Dynamic loss modulus maximum. b Calculated from data in Refs., 58, 77, 01. [Pg.308]

The IR rheooptical technique was applied to study the molecular processes that take place along the stress-strain curve of PET yams. The results indicate that the first modulus maximum marks the breakdown of the amorphous entanglement network and the start of molecular uncoiling by gauche-to-trans transitions. In addition, stress develops on the crystals and particularly on tie molecules with a short contour length in the amorphous domains. Ultimately, molecular fracture of taut-tie molecules (extended chains of polymers between crystals) causes the modulus to pass through a second... [Pg.31]

Maximum tensile strength Maximum tensile modulus Maximum flexural strength Maximum flexural modulus... [Pg.541]

Table 5.2 The flexural modulus, maximum stress, energy at break and hot recoverable strain of the CIM and SCORIM processed PLLA... Table 5.2 The flexural modulus, maximum stress, energy at break and hot recoverable strain of the CIM and SCORIM processed PLLA...
The decrease of Young s modulus, maximum tensile load and cristallinity can be related to the concentration by using the following empirical models respectively (Abbes etal., 2010) ... [Pg.61]

Figure 4.16 Determination of the glass transition temperature. Different methods of calculation include onset of storage modulus decrease, inflection point (derivative maximum), loss modulus maximum, or tan 8 maximum. Figure 4.16 Determination of the glass transition temperature. Different methods of calculation include onset of storage modulus decrease, inflection point (derivative maximum), loss modulus maximum, or tan 8 maximum.
In case of the composites with different fibre content, elastic modulus, maximum tensile strength and notched impact strength increase with increasing fibre content, but unnotched impact strength decreases with increasing fibre length. [Pg.1379]

In Figure 5.24 the predicted direct stress distributions for a glass-filled epoxy resin under unconstrained conditions for both pha.ses are shown. The material parameters used in this calculation are elasticity modulus and Poisson s ratio of (3.01 GPa, 0.35) for the epoxy matrix and (76.0 GPa, 0.21) for glass spheres, respectively. According to this result the position of maximum stress concentration is almost directly above the pole of the spherical particle. Therefore for a... [Pg.187]

Chains of polybutadiene were trapped in the network formed by cooling a butadiene-styrene copolymer until phase separation occurred for the styrene, effectively crosslinking the copolymer. At 25°C the loss modulus shows a maximum which is associated with the free chains. This maximum occurst at the following frequencies for the indicated molecular weights of polybutadiene ... [Pg.197]

Maximum Service Temperature. Because the cellular materials, like their parent polymers (204), gradually decrease in modulus as the temperature rises rather than undergoing a sharp change in properties, it is difficult to precisely define the maximum service temperature of cellular polymers. The upper temperature limit of use for most cellular polymers is governed predominantly by the plastic phase. Fabrication of the polymer into a... [Pg.414]

Molybdenum, a typical transition element, has the maximum number, five, of unpaired Ad electrons, which account for its high melting point, strength, and high modulus of elasticity. There are many similarities between molybdenum and its horizontal and vertical neighbors in the periodic system. [Pg.463]

Fiber type Density, g/cm Strength, GPa Elongation, % Modulus, GPa Maximum use temperature, °C... [Pg.240]

Al—Li. Ahoys containing about two to three percent lithium [7439-93-2] Li, (Fig. 15) received much attention in the 1980s because of their low density and high elastic modulus. Each weight percent of lithium in aluminum ahoys decreases density by about three percent and increases elastic modulus by about six percent. The system is characteri2ed by a eutectic reaction at 8.1% Li at 579°C. The maximum soHd solubiHty is 4.7% Li. The strengthening precipitate in binary Al—Li ahoys is metastable Al Li [12359-85-2] having the cubic LI2 crystal stmcture, and the equhibrium precipitate is complex cubic... [Pg.113]

Catalyst Effectiveness. Even at steady-state, isothermal conditions, consideration must be given to the possible loss in catalyst activity resulting from gradients. The loss is usually calculated based on the effectiveness factor, which is the diffusion-limited reaction rate within catalyst pores divided by the reaction rate at catalyst surface conditions (50). The effectiveness factor E, in turn, is related to the Thiele modulus,

first-order rate constant, a the internal surface area, and the effective diffusivity. It is desirable for E to be as close as possible to its maximum value of unity. Various formulas have been developed for E, which are particularly usehil for analyzing reactors that are potentially subject to thermal instabilities, such as hot spots and temperature mnaways (1,48,51). [Pg.516]

The characteristics of soluble sihcates relevant to various uses include the pH behavior of solutions, the rate of water loss from films, and dried film strength. The pH values of sihcate solutions are a function of composition and concentration. These solutions are alkaline, being composed of a salt of a strong base and a weak acid. The solutions exhibit up to twice the buffering action of other alkaline chemicals, eg, phosphate. An approximately linear empirical relationship exists between the modulus of sodium sihcate and the maximum solution pH for ratios of 2.0 to 4.0. [Pg.7]


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See also in sourсe #XX -- [ Pg.418 ]

See also in sourсe #XX -- [ Pg.418 ]




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