Mixed glues

Mixed glue Combination of animal and/or plant glues with synthetic adhesives. 

Core thickness (mm) Mixed glue per single glue line (g/m ... 

The final addition of hexamethylenetetramine illustrates the use of a formaldehyde donor to partially denature or cross-link the dispersed proteins. This adds further granular character to the mixed glue, lengthens its working life, and improves the water and mold resistance of the cured adhesive film. 

To maintain the highest possible phenolic solids content in the mixed glue (preferably in the range 30 to 40%). 

Mixed Glues. Starches and dextrins also are used in combination with other raw materials in adhesives. For example, the resistance to water of starch-based adhesives can be improved by the addition of melamine-formaldehyde or urea-formaldehyde resins. Mixtures of starch-based adhesives or dextrin-based adhesives with synthetic resin dispersions are also used. 

Moisture-reactivated coatings are produced from dextrin glues, dextrin emulsions, mixed glues, and remoistenable hot-melt adhesives. 

Casein is used to fortify flour, bread, and cereals. Casein also is used for glues and microbiological media. Calcium caseinate is made from a pressed casein, by rinsing, treating with calcium hydroxide [1305-62-0], heating, and mixing foUowed by spray drying. A product of 2—4% moisture is obtained. 

The term epoxy is familiar to nonchemists because of the widespread use of epoxy glues and resins. These are crosslinked polyether thermoplastics made from a liquid resin which is typically a mixture of bisphenol A diglycidyl ether (70) and a polymer (71 Scheme 86). The liquid resin is cured or hardened to the final resin by mixing with a crosslinking reagent, which can be an acid, a di- or poly-alcohol, or a di- or poly-amine (Scheme 86). 

This makes a mix with a viscosity of 5000-7000 centipoise. The total mix solids are 40% and the resin solids in the mix are 26%. A mix like this would be used on Douglas fir veneer at the rate of about 55 pounds per 1000 square feet of veneer surface (double glue line basis). The 43% solids resin would be used at about 500 cps viscosity. 

However, it has to be considered that it is neither the content of free formaldehyde itself nor the molar ratio which eventually should be taken as the decisive and the only criterion for the classification of a resin concerning the subsequent formaldehyde emission from the finished board. In reality, the composition of the glue mix as well as the various process parameters during the board production also determine both performance and formaldehyde emission. Depending on the type of board and the manufacturing process, it is sometimes recommended to use a UF-resin with a low molar ratio F/U (e.g. F/U = 1.03), hence low content of free formaldehyde, while sometimes the use of a resin with a higher molar ratio (e.g. F/U = 1.10) and the addition of a formaldehyde catcher/depressant will give better results [17]. Which of these two, or other possible approaches, is the better one in practice can only be decided in each case by trial and error. 

Addition of melamine in various forms (pure melamine, MF/MUF-powder resin, melamine acetates) to an UF-resin during the application of the glue mix. In the case of the addition of pure melamine the UF-resin must have a rather high molar ratio, otherwise there is not enough formaldehyde available to react with the melamine in order to incorporate it into the resin. 

Special resins consist of a two-phase system composed of a mix of a highly condensed, and no longer soluble, PF-resin with a standard type PF-resin [63]. Another two-phase resin is composed of a highly condensed PF-resin, still in an aqueous solution, and of a PF dispersion [64]. The purpose of such special resins is the gluing of wet wood, where the danger of overpenetration of the resin into the wood surface exists and would cause a starved glue line. 

Acid-induced gelling reactions of PF resins can cause severe deterioration of the wood substrate and therefore have lost any importance in the wood adhesives field. Pizzi et al. [85] describe a procedure for the neutralization of acid-hardened PF glue lines by partly using as hardener a mix of p-toluene sulfonic acid with a... 

In the manufacture of pure resorcinol resins, the reaction can be violently exothermic unless controlled by the addition of alcohols. Because the alcohols perform other useful functions in the glue mix, they are left in the liquid adhesive. PRF adhesives are generally prepared firstly by reaction of phenol with formaldehyde to form a PF resol polymer, that has been proved to be in the greatest percentage, and often completely, linear [95], In the reaction step that follows the resorcinol chemical is added in excess to the PF-resol to react it with the PF-resin -CH2OH groups to form PRF polymers in which the resorcinol groups can be resorcinol chemical or any type of resorcinol-formaldehyde polymer. 

Beside of the viscosity of the glue resin itself also the viscosity of the glue mix plays an important role. A higher dilution of the resin gives a higher volume to be spread and with this a better distribution of the resin on the particles or fibers with hence better bonding strength [173]. This also saves costs. 

The target of the development of adhesive resins is to achieve high reactivities mitigated by consideration of the storage stability of the resin or the pot life of the glue mix. The reactivity of a glue resin and of a glue mix is determined by various parameters ... 

Because of the reasons described above, the core layer and face layers are glued separately, that is, the core layer contains rather coarse particles, but the face layers contains rather fine particles. However, the two distributions might overlap to some extent. This separate gluing enables one to use different compositions of the glue resin mixes (e.g. different addition of water and hardener) and different gluing factors for the individual layers. 

The moisture content of the glued particles is the sum of the wood moisture content and the water which is part of the applied glue mix. Therefore, the moisture content of the glued particles mainly depends on the gluing factor. Usual moisture contents of glued particles are 6.5-8.5% in the core layer and 10-13% in the face layer for UF, and 11-14% in the core layer and 14-18% in the face layer for PF. 

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