Microwave magnetron

Figure 9-34. General sehematie of the microwave installation for plasma treatment of gas-separating polymer membranes (1) modulation system (2) power supply (3) microwave magnetron (4) plasmatron ...

The most dramatic evolution of a microwave power source is that of the cooker magnetron for microwave ovens (48). These magnetrons are air-cooled, weigh 1.2 kg, generate weU over 700 W at 2.45 GHz into a matched load, and exhibit a tube efficiency on the order of 70%. AppHcation is enhanced by the avaHabiHty of comparatively inexpensive microwave power and microwave oven hardware (53). The cost of these tubes has consistently dropped (11) since their introduction in the eady 1970s. As of this writing (ca 1995), cost is < 15/tube for large quantities. For small quantities the price is < 100/tube. 

Some power tubes can be operated without the need for a protective ferrite isolator. One example is the cooker magnetron (700 W) used in modern microwave ovens (57). At higher power levels, such as 25 kW, it is more common to employ a protective ferrite device, particularly in the form of a circulator (58), as shown in Figure 3. This results in a power loss equivalent to a few percentage points in system efficiency. The ferrite circulator prevents reflected power from returning to the power tube and instead directs it into an auxiHary dummy load. The pulling of tube frequency is thus minimised. 

The price of cooker magnetrons at ca 700 W was in the range of several hundred dollars in the 1960s (11). As of the mid-1990s, this price is < 15. Total sales of microwave ovens worldwide exceed 20 x 10 /yr. The majority of homes in Japan and the United States have microwave ovens (94). European homes should foUow before the year 2000 (95). 

Food. The most successful appHcation of microwave power is that of food processing (qv), cooking, and reheating. The consumer industry surpasses all other microwave power appHcations. Essentially all microwave ovens operate at 2450 MH2 except for a few U.S. combination range models that operate at 915 MH2. The success of this appHance resulted from the development of low cost magnetrons producing over 700 W for oven powers of 500-800 W (Table 3). 

The frequency of microwave radiation lies between that of IR radiation and high frequency radio waves and the boundaries between these regions are not fixed [221]. The microwaves are generated in a transmitter (magnetron) which possesses a stalk which penetrates Uke a radio antenna into a hollow energy guide (Fig. 48). This leads the electromagnetic waves into the reaction chamber (power about... 

In addition to microwave plasma, direct current (dc) plasma [19], hot-filament [20], magnetron sputtering [21], and radiofrequency (rf) [22-24] plasmas were utilized for nanocrystalline diamond deposition. Amaratunga et al. [23, 24], using CH4/Ar rf plasma, reported that single-crystal diffraction patterns obtained from nanocrystalline diamond grains all show 111 twinning. 

This chapter provides a detailed description of the various commercially available microwave reactors that are dedicated for microwave-assisted organic synthesis. A comprehensive coverage of microwave oven design, applicator theory, and a description of waveguides, magnetrons, and microwave cavities lies beyond the scope of this book. Excellent coverage of these topics can be found elsewhere [1—4]. An overview of experimental, non-commercial microwave reactors has recently been presented by Stuerga and Delmotte [4],... 

Based on their microwave digestion system, Milestone offers the MicroSYNTH labstation (also known as ETHOS series) multimode instrument (Fig. 3.4 and Table 3.1), which is available with various accessories. Two magnetrons deliver 1000 W microwave output power and a patented pyramid-shaped microwave diffuser ensures homogeneous microwave distribution within the cavity [12]. 

Consequently, which strategy is utilized in reaction optimization experiments is highly dependent on the type of instrument used. Whilst multimode reactors employ powerful magnetrons with up to 1500 W microwave output power, monomode reactors apply a maximum of only 300 W. This is due to the high density microwave field in a single-mode set-up and the smaller sample volumes that need to be heated. In principle, it is possible to translate optimized protocols from monomode to multimode instruments and to increase the scale by a factor of 100 without a loss of efficiency (see Section 4.5). 

High power microwaves are generated by vacuum tubes. The magnetron and klystron are the most commonly used tubes for the generation of continuous waves power for microwave processing. Power is normally launched from the microwave tube into a transmission line or waveguide, where it travels to a load or termination such an antenna or a microwave heating applicator. 

When microwaves travel along a waveguide terminated by the microwave heating application (for example a resonant cavity loaded by the object to be heated) a reflected wave travels back towards the source. The wave traveling towards the termination is called the incident wave and the wave traveling back to the magnetron is... 

Fig. 10.1 Microwave batch reactor 1. micro-wave cavity, 2. magnetron, 3. stirring bar, 4. alir minum plate, 5. magnetic stirrer, 6. IR pyrometer, 7. switch on/off, 8. watercooler.

Fig. 10.2 Schematic diagram of the microwave batch reactor 1. reaction vessel, 2. retaining cylinder, 3. top flange, 4. cold finger, 5. pressure meter, 6. magnetron, 7. power meters, 8. power supply, 9. stirrer, 10. fiber optic thermometer,...

Fig. 14.5 A modified MW oven for microwave photochemistry experiments. A. magnetron, B. reaction mixture with the EDL and a magnetic stir bar, C. aluminum plate, D. magnetic stirrer, E. infrared pyrometer, F. circulating water in a glass tube, G. dummy load inside the oven cavity [88]. With permission from Elsevier Science.

Fig. 14.7 A reactor for microwave photochemistry derived from the Synthewave 402 (Prolabo). A. medium-pressure Hg lamp, B. window hermetic to MW radiation, C. reaction mixture, D. magnetron, E. regulator, F. IR sensor. Adapted from Ref. [92],...

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