Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Methods, Polymer Characterization, Compositions

Analytical investigations may be undertaken to identify the presence of an ABS polymer, characterize the polymer, or identify nonpolymeric ingredients. Fourier transform infrared (ftir) spectroscopy is the method of choice to identify the presence of an ABS polymer and determine the acrylonitrile—butadiene—styrene ratio of the composite polymer (89,90). Confirmation of the presence of mbber domains is achieved by electron microscopy. Comparison with available physical property data serves to increase confidence in the identification or indicate the presence of unexpected stmctural features. Identification of ABS via pyrolysis gas chromatography (91) and dsc ((92) has also been reported. [Pg.204]

Compressive Behavior. The most kiformative data ki characterising the compressive behavior of a flexible foam are derived from the entire load-deflection curve of 0—75% deflection and its return to 0% deflection at the speed experienced ki the anticipated appHcation. Various methods have been reported (3,161,169—172) for relating the properties of flexible foams to desked behavior ki comfort cushioning. Other methods to characterize package cushioning have been reported. The most important variables affecting compressive behavior are polymer composition, density, and cell stmcture and size. [Pg.413]

In conclusion one can say that SEC is a very powerful method for polymer characterization, especially in combination with other composition sensitive or absolute calibration methods. A big advantage is also that the sample amount is fairly small, typically 10 mg. For more complex polymers, such as polyelectrolytes, enthalpic effects often become dominant and also for rather high molecular weight polymers chromatographic methods such as field-flow fraction (FFF) techniques might be more suitable. For fast routine measurements linear columns are often used. [Pg.232]

Narkis, M., Chen, E. J. H. and Pipes, R. B., Review of methods for characterization of interfacial fiber-matrix interactions, Polym. Composites, 9, 245 (1988). [Pg.561]

This volume provides an overview of polymer characterization test methods. The methods and instrumentation described represent modern analytical techniques useful to researchers, product development specialists, and quality control experts in polymer synthesis and manufacturing. Engineers, polymer scientists and technicians will find this volume useful in selecting approaches and techniques applicable to characterizing molecular, compositional, rheological, and thermodynamic properties of elastomers and plastics. [Pg.258]

The metal oxides prepared by conventional baking or by the CVD method are, in general, chemically stable, crystalline materials, and show excellent mechanical, electrical, optical, and physical properties. Flexible porous gel films obtained by the surface sol-gel process are totally different. In this chapter, we described a new preparative method for ultrathin metal oxide films by stepwise adsorption of various metal alkoxides. We named this method the surface sol-gel process. Structural characterization of the gel films thus obtained, the electrical property, and formation of nano-composites with organic compounds, were also explained. The soft porous gel contains many active hydroxyl groups at the surface and interior of the film. This facilitates adsorption of organic compounds, and consequent preparation of ultrathin metal oxide/polymer nano-composite films and organization of functional small molecules. In the nano-composites, proper selection of polymer components leads to the design of new materials with unique electrical, optical, and chemi-... [Pg.210]

Size exclusion chromatography is the premier polymer characterization method for determining molar mass distributions. In SEC, the separation mechanism is based on molecular hydrodynamic volume. For homopolymers, condensation polymers and strictly alternating copolymers, there is a correspondence between elution volume and molar mass. Thus, chemically similar polymer standards of known molar mass can be used for calibration. However, for SEC of random and block copolymers and branched polymers, no simple correspondence exists between elution volume and molar mass because of the possible compositional heterogeneity of these materials. As a result, molar mass calibration with polymer standards can introduce a considerable amount of error. To address this problem, selective detection techniques have to be combined with SEC separation. [Pg.9]

A number of multidimensional analyses have been developed that provide powerful methods for characterizing these polymers. Linking a liquid chromatogram to a pyrolysis gas chromatograph [l 9] can determine the breadth of the composition distribution, as the method fractionates the SAN copolymer before pyrolysis. This information is useful for determining the source of variation in SAN copolymer properties. Composition drift towards high acrylonitrile-containing fractions can lead to undesirable yellow color, and excessively broad composition drift can cause opacity and brittleness in the material due to phase separation... [Pg.286]

This book covers some of the significant advances in hyphenated chromatographic separation methods for polymer characterization. Chromatographic separation techniques in this volume include size-exclusion chromatography, liquid chromatography, and field flow fractionation methods that are used in conjunction with information-rich detectors such as molecular size-sensitive or compositional-sensitive detectors or coupled in cross-fractionation modes. [Pg.3]

Size-exclusion chromatography (SEC) is the premier polymer characterization method for determining MWDs. As discussed in this volume and summarized in the following section, by hyphenating SEC with selective detectors, one can, in principle, completely characterize a polymer in terms of its molecular parameters and chemical composition in the time it takes to do a typical SEC analysis. [Pg.6]

The characterization of polymer chemical composition is important in numerous practical applications. The polymer identification can be done using various techniques. One of them is the chemical method, which involves reagents that are able to react with the polymer. Oxidation, for example using periodic acid or lead tetraacetate, can be applied to polymers containing 1,2 diol groups, ozonolysis can be applied to polymers containing double bonds, hydrolysis can be applied to esters and amides [4]. [Pg.26]

Analysis of Polymers. The repeat unit structure of a synthetic polymer usually is known from the method of synthesis. Compositions of copolymers often are determined by elemental analysis when one monomer contains an element not present in the other monomer. Soluble polymers are often characterized by their molecular weights and molecular weight distribution, but insolubility prevents such characterization of cross-linked polymers. [Pg.10]

Infrared spectroscopy is a widely used method to characterize polymers and copolymers. However, for determination of the composition and microstructure... [Pg.597]

IR spectroscopy is a popnilar method for characterizing polymers. This spectroscopy may used to identify the composition of polymers, to monitor polymerization processes, to characterize polymer structure, to examine polymer surface, and to investigate polymer degradation processes. There are several reports of use of IR spectroscopy to evaluate grafting of acrylic monomers onto natural materials as carboxymethyl cellulose (CMC) and chicken feathers (CF) (Martinez et al, 2003, 2005, Vasile et al, 2004, Zohuriann-Mehr et al, 2005, Joshi and Sinha, 2006). [Pg.245]

The fundamental difficulty is that polymeric substances cannot be obtained in a stmcturally and molecularly uniform state, unlike low-molecular-weight compounds. Thus, macromolecular materials of the same analytical composition may differ not only in their structure and configuration (see Sect. 1.2) but also in molecular size and molecular weight distribution they are polydisperse, i.e., they consist of mixtures of molecules of different size. Hence, it is understandable that the expression identical is not, in practice, applicable to macromolecules. Up to the present time, there is no possibility of preparing macromolecules of absolutely uniform stmcture and size. It follows, therefore, that physical measurements on polymers can only yield average values. The aforementioned peculiarities of macromolecular substances mean that the methods of characterization suitable for low-molecular-weight compounds are frequently not applicable or only applicable in a substantially modified form often completely new methods of investigation must be employed. [Pg.66]

GPC/DRI/FrlR - The GPC/DRI/FTIR instrument is complementary to the UV detector for compositional distribution. It runs at 135° C in TCB and can be used for EP analysis. Typical applications include ethylene content as a function of molecular weight, maleic anhydride content in maleated EP, or PCL content in caprolactone-g-EP copolymers. The FTIR detector is off-line so that 5-10 fractions of the eluant are collected on KBr plates and analyzed. This procedure gives calibration of IR absorption bands. This method is much more labor intensive than the other techniques and should be used with discretion. (Source Cheremisinoff, N.P. Polymer Characterization Laboratory Techniques and Analysis, Noyes Publishers, New Jersey, 1996). [Pg.115]


See other pages where Methods, Polymer Characterization, Compositions is mentioned: [Pg.7]    [Pg.7]    [Pg.7]    [Pg.7]    [Pg.204]    [Pg.554]    [Pg.201]    [Pg.69]    [Pg.351]    [Pg.137]    [Pg.31]    [Pg.304]    [Pg.95]    [Pg.40]    [Pg.287]    [Pg.579]    [Pg.1184]    [Pg.359]    [Pg.201]    [Pg.352]    [Pg.296]    [Pg.194]    [Pg.83]    [Pg.169]    [Pg.224]    [Pg.781]    [Pg.282]    [Pg.345]    [Pg.77]    [Pg.267]   


SEARCH



Characterization compositional

Characterization methods

Composite characterization

Composite methods

Composition method

Polymer characterization

Polymer method

© 2024 chempedia.info