Metallic overview

Metallaboranes, and /-Block metallaboranes, overview, 3,133-174 Metallacarboranes 7-block metal characteristics, 3, 200 deblock metal overview, 3, 175-264 early transition elements, 3, 201 /-block metal characteristics, 3, 246 /-block metal overview, 3, 175-264 late transition elements, 3, 221 linked cage and multi-decker complexes, 3, 245 mid-transition elements, 3, 214 Metallacarbynes, molybdenum, and palladium complexes, 8, 211... 

Beamish FE and Van Loon JC (1977) Analysis of Noble Metals, Overview and Selected Methods. London Academic Press. 

Fig. 3. An overview of atomistic mechanisms involved in electroceramic components and the corresponding uses (a) ferroelectric domains capacitors and piezoelectrics, PTC thermistors (b) electronic conduction NTC thermistor (c) insulators and substrates (d) surface conduction humidity sensors (e) ferrimagnetic domains ferrite hard and soft magnets, magnetic tape (f) metal—semiconductor transition critical temperature NTC thermistor (g) ionic conduction gas sensors and batteries and (h) grain boundary phenomena varistors, boundary layer capacitors, PTC thermistors.

Physical Properties. An overview of the metallurgy (qv) and soUd-state physics of the rare earths is available (6). The rare earths form aUoys with most metals. They can be present interstitiaUy, in soUd solutions, or as intermetaUic compounds in a second phase. Alloying with other elements can make the rare earths either pyrophoric or corrosion resistant. It is extremely important, when determining physical constants, that the materials are very pure and weU characteri2ed. AU impurity levels in the sample should be known. Some properties of the lanthanides are Usted in Table 3. 

Reference 37 provides excellent overviews of metallic films, materials science of thin magnetic recording materials, and the potential technological significance. 

Naphthenic acids have been the topic of numerous studies extending over many years. Originally recovered from the petroleum distillates to minimise corrosion of refinery equipment, they have found wide use as articles of commerce in metal naphthenates and other derivatives. A comprehensive overview of the uses of naphthenic acid and its derivatives can be found in References 1 and 2. A review of the extensive research on carboxyUc acids in petroleum conducted up to 1955 is available (3), as is a more recent review of purification, identification, and uses of naphthenic acid (4). 

C. E. TiU, The Riquid-Metal Reactor. Overview of the Integrated Fast Reactor Rationale and Basis for Its Development, Presented to National Academy Sciences Committee on Future Nuclear Power, Argonne National Laboratory, Chicago, lU., Aug. 1989. 

Overview. Three approaches are used to make most sol—gel products method 1 involves gelation of a dispersion of colloidal particles method 2 employs hydrolysis and polycondensation of alkoxide or metal salts precursors followed by supercritical drying of gels and method 3 involves hydrolysis and polycondensation of alkoxide precursors followed by aging and drying under ambient atmospheres. 

This article addresses the synthesis, properties, and appHcations of redox dopable electronically conducting polymers and presents an overview of the field, drawing on specific examples to illustrate general concepts. There have been a number of excellent review articles (1—13). Metal particle-filled polymers, where electrical conductivity is the result of percolation of conducting filler particles in an insulating matrix (14) and ionically conducting polymers, where charge-transport is the result of the motion of ions and is thus a problem of mass transport (15), are not discussed. 

Because LEED theory was initially developed for close packed clean metal surfaces, these are the most reliably determined surface structures, often leading to 7 p factors below 0.1, which is of the order of the agreement between two experimental sets of 7-V curves. In these circumstances the error bars for the atomic coordinates are as small as 0.01 A, when the total energy range of 7-V curves is large enough (>1500 eV). A good overview of state-of-the-art LEED determinations of the structures of clean metal surfaces, and further references, can be found in two recent articles by Heinz et al. [2.272, 2.273]. 

The study of microstructures in relation to important properties of metals and alloys, especially mechanical properties, continues apaee. A good overview of eurrent concerns can be found in a multiauthor volume published in Germany (Anon. 1981), and many chapters in my own book on physieal metallurgy (Cahn 1965) are devoted to the same issues. 

Nowick (1996) has outlined the researches done on crystal defects during the period 1949-1959 and called this the "golden age of crystal defects . A recent, very substantial overview (Kraftmakher 1998) admirably surveys the linkage between vacancies in equilibrium and thermophysical properties of metals this paper includes a historical table of 32 key papers, on a wide range of themes and techniques, 1926-1992. 

Crystal structure, crystal defects and chemical reactions. Most chemical reactions of interest to materials scientists involve at least one reactant in the solid state examples inelude surfaee oxidation, internal oxidation, the photographie process, electrochemieal reaetions in the solid state. All of these are critieally dependent on crystal defects, point defects in particular, and the thermodynamics of these point defeets, especially in ionic compounds, are far more complex than they are in single-component metals. I have spaee only for a superficial overview. 

According to an early historical overview (Jones 1960), the numerous attempts to understand the sintering process in both ceramics and metals fall into three periods (1) speculative, before 1937 (2) simple, 1937-1948 (3) complex, 1948 onwards. The complex experiments and theories began just at the time when metallurgy underwent its broad-based quantitative revolution (see Chapter 5). 

Baker, A.A., Bonded Composite Repair of Metallic Aircraft Components — Overview of Australian Activities, AGARD (Advisory Group for Aerospace Research and Development) Conference of Composite Repair of Military Aircraft Structures, 3-5 October 1994, Seville. 

We have not attempted to cover all or even most aspects of crown chemistry and some may say that the inclusions are eclectic. We felt that anyone approaching the field would need an appreciation for the jargon currently abounding and for the so-called template effect since the latter has a considerable bearing on the synthetic methodology. We have, therefore, included brief discussions of these topics in the first two chapters. In chapters 3—8, we have tried to present an overview of the macrocyclic polyethers which have been prepared. We have taken a decidedly organic tack in this attempting to be comprehensive in our inclusion of alkali and alkaline earth cation binders rather than the compounds of use in transition metal chemistry. Nevertheless, many of the latter are included in concert with their overall importance. 

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