Metal redistribution

It should be noted that the three parts of the electric field— across the M/O interface, across the bulk of the oxide, and across the O/S interface—are determined by entirely different factors [cf. Section III(l)]. Hence, any imposed change of the potential level of the metal redistributes itself among the three parts in a manner which cannot be predicted without detailed knowledge of the kinetics of the processes taking place in each of them. 

The specific objectives of the experiment were to determine critical concentrations of Pt necessary for stable passivity of the surface alloy in IN H2SO4 and to aid understanding of the mechanisms of noble metal redistribution. 

Mehta, A., Flora, S.J.S. (2001). Possible role of metal redistribution, hepatotoxicity and oxidative stress in chelating agents induced hepatic and renal metallothionein in rats. Food. Chem. Toxicol. 39 1029-38. 

YSZ-SrCoo.4Feo.603 a Found metal redistribution after 7 h operation 69,70... 

Despite a few drawbacks/side effects associated with MiADMSA, these results suggest that MiADMSA may be a future drug of choice because of its lipophilic character and the absence of any metal redistribution. However, significant copper loss requires further studies (Mehta et al., 2002 Mehta et al., 2006). Moderate toxicity after repeated administration of MiADMSA may be reversible after the withdrawal of the chelating agent. 

Alkyltin Intermedia.tes, For the most part, organotin stabilizers are produced commercially from the respective alkyl tin chloride intermediates. There are several processes used to manufacture these intermediates. The desired ratio of monoalkyl tin trichloride to dialkyltin dichloride is generally achieved by a redistribution reaction involving a second-step reaction with stannic chloride (tin(IV) chloride). By far, the most easily synthesized alkyltin chloride intermediates are the methyltin chlorides because methyl chloride reacts directiy with tin metal in the presence of a catalyst to form dimethyl tin dichloride cleanly in high yields (21). Coaddition of stannic chloride to the reactor leads directiy to almost any desired mixture of mono- and dimethyl tin chloride intermediates ... 

The other commercially important routes to alkyltin chloride intermediates utilize an indirect method having a tetraalkjitin intermediate. Tetraalkyltins are made by transmetaHation of stannic chloride with a metal alkyl where the metal is typicaHy magnesium or aluminum. Subsequent redistribution reactions with additional stannic chloride yield the desired mixture of monoalkyl tin trichloride and dialkyltin dichloride. Both / -butjitin and / -octjitin intermediates are manufactured by one of these schemes. 

A number of less hindered monoalkylboranes is available by indirect methods, eg, by treatment of a thexylborane—amine complex with an olefin (69), the reduction of monohalogenoboranes or esters of boronic acids with metal hydrides (70—72), the redistribution of dialkylboranes with borane (64) or the displacement of an alkene from a dialkylborane by the addition of a tertiary amine (73). To avoid redistribution, monoalkylboranes are best used /V situ or freshly prepared. However, they can be stored as monoalkylborohydrides or complexes with tertiary amines. The free monoalkylboranes can be hberated from these derivatives when required (69,74—76). Methylborane, a remarkably unhindered monoalkylborane, exhibits extraordinary hydroboration characteristics. It hydroborates hindered and even unhindered olefins to give sequentially alkylmethyl- and dialkylmethylboranes (77—80). 

Primary dialkylboranes react readily with most alkenes at ambient temperatures and dihydroborate terminal acetylenes. However, these unhindered dialkylboranes exist in equiUbtium with mono- and ttialkylboranes and cannot be prepared in a state of high purity by the reaction of two equivalents of an alkene with borane (35—38). Nevertheless, such mixtures can be used for hydroboration if the products are acceptable for further transformations or can be separated (90). When pure primary dialkylboranes are required they are best prepared by the reduction of dialkylhalogenoboranes with metal hydrides (91—93). To avoid redistribution they must be used immediately or be stabilized as amine complexes or converted into dialkylborohydtides. 

When two conducting phases come into contact with each other, a redistribution of charge occurs as a result of any electron energy level difference between the phases. If the two phases are metals, electrons flow from one metal to the other until the electron levels equiUbrate. When an electrode, ie, electronic conductor, is immersed in an electrolyte, ie, ionic conductor, an electrical double layer forms at the electrode—solution interface resulting from the unequal tendency for distribution of electrical charges in the two phases. Because overall electrical neutrality must be maintained, this separation of charge between the electrode and solution gives rise to a potential difference between the two phases, equal to that needed to ensure equiUbrium. 

For straight metal pipe under internal pressure the formula for minimum reqiiired w thickness is applicable for D /t ratios greater than 6. Tme more conservative Barlow and Lame equations may also be used. Equation (10-92) includes a factor Y varying with material and temperature to account for the redistribution of circumferential stress which occurs under steady-state creep at high temperature and permits slightly lesser thickness at this range. 

The transfer of an element from the metal to the slag phase is one in which the species goes from the charge-neutralized metallic phase to an essentially ionic medium in the slag. It follows that there must be some electron redistribution accompanying the transfer in order that electro-neutrality is maintained. A metallic atom which is transfened must be accompanied by an oxygen atom which will absorb the elecuons released in the formation of tire metal ion, thus... 

Net-tension failures can be avoided or delayed by increased joint flexibility to spread the load transfer over several lines of bolts. Composite materials are generally more brittle than conventional metals, so loads are not easily redistributed around a stress concentration such as a bolt hole. Simultaneously, shear-lag effects caused by discontinuous fibers lead to difficult design problems around bolt holes. A possible solution is to put a relatively ductile composite material such as S-glass-epoxy in a strip of several times the bolt diameter in line with the bolt rows. This approach is called the softening-strip concept, and was addressed in Section 6.4. 

Electronic absorption spectra are produced when electromagnetic radiation promotes the ions from their ground state to excited states. For the lanthanides the most common of such transitions involve excited states which are either components of the ground term or else belong to excited terms which arise from the same 4f" configuration as the ground term. In either case the transitions therefore involve only a redistribution of electrons within the 4f orbitals (i.e. f—>f transitions) and so are orbitally forbidden just like d—>d transitions. In the case of the latter the rule is partially relaxed by a mechanism which depends on the effect of the crystal field in distorting the symmetry of the metal ion. However, it has already been pointed out that crystal field effects are very much smaller in the case of ions and they... 

We have developed a theory that allows to determine the effective cluster interactions for surfaces of disordered alloys. It is based on the selfconsistent electronic structure of surfaces and includes the charge redistribution at the metal/vacuum interface. It can yield effective cluster interactions for any concentration profile and permits to determine the surface concentration profile from first principles in a selfconsistent manner, by... 

Another problem associated with sodium appears in the form of sodium chloride. Chlorides tend to reactivate aged metals by redistributing the metals on the equilibrium catalyst and allowing them to cause more damage. 

Bohnenkamp and Engell and Caplan et have also reported rapid carbon loss from the steel during the initial stage of oxidation at higher temperatures (circa 850°C) followed by a much lower, or zero, loss of carbon later. Caplan et at. measured the COj evolution by infrared gas analysis and reported that the percentage of carbon loss from 0.1 %C, 0.4%C, 0.8%C and 1.2%C steels was overall very small and may be redistributed in the metal. There was no carbon loss detected at 700°C. The overall oxidation rates were all found to be parabolic at 850°C and less than the oxidation rate of pure Fe. In the Fe-C alloys the individual phases of FeO, FejO and... 

At any interface between two different phases there will be a redistribution of charge in each phase at the interface with a consequent loss of its electroneutrality, although the interface as a whole remains electrically neutral. (Bockris considers an interface to be sharp and definite to within an atomic layer, whereas an interphase is less sharply defined and may extend from at least two molecular diameters to tens of thousands of nanometres the interphase may be regarded as the region between the two phases in which the properties have not yet reached those of the bulk of either phase .) In the simplest case the interface between a metal and a solution could be visualised as a line of excess electrons at the surface of the metal and an equal number of positive charges in the solution that are in contact with the metal (Fig. 20.2). Thus although each phase has an excess charge the interface as a whole is electrically neutral. 

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