Metal catalyzed cross-couplings

From Other Alkenes-Transition Metal Catalyzed Cross-Coupling and Olefin... [Pg.103]

Heterocycles in metal-catalyzed cross-coupling reactions 98MI32. [Pg.209]

F. Diederich and P. J. Stang (eds.), Metal-Catalyzed Cross-Coupling Reactions, Wiley-VCH, Weinheim, 1998. [Pg.299]

Metal Catalyzed Cross-coupling Reactions Diederich, F. Stang, P. J., Eds. Wiley-VCH Weinheim, 1998. [Pg.20]

For overviews of applications of the Heck reaction in natural products synthesis, see (a) Link, J. T. Overman, L. E. In Metal-Catalyzed Cross-Coupling Reactions, Diederich, F., Stang, P. J., Eds. Wiley-VCH New York, 1998 Chapter 6. (b) Brase, S. de Meijere, A. In Metal-Catalyzed Cross-Coupling Reactions Diederich, F., Stang, P. J., Eds. Wiley New York, 1998 Chapter 3.6. (c) Nicolaou, K. C. Sorensen, E. J. Classics in Total Synthesis VCH New York, 1996 Chapter 31. These authors refer to the Heck reaction as "one of the true "power tools" of contemporary organic synthesis" (p. 566). [Pg.37]

The transition metal catalyzed cross coupling of an organohalide with a boronic acid derivative, the Suzuki-Miyaura coupling, has become one of the most popular ways of preparing biaryls.3 The reaction is very robust and can easily be scaled to provide multigrams of material.4... [Pg.70]

Sonogashira K (1998) In Diederich F, Stang PJ (eds) Metal catalyzed cross-coupling... [Pg.302]

Diederich F, Slang PJ (1998) Metal-catalyzed cross-coupling reactions. Wiley-VCH, Weinheim... [Pg.40]

Erase S, de Meijere A(2004) Cross-coupling of organic halides withalkenes The Heck reaction. In de Meijere A, Diederich F (eds) Metal-catalyzed cross-coupling reactions, 2nd edn. Wiley-VCH, Weinheim... [Pg.186]

K. Sonogashiea, in Metal-catalyzed Cross-coupling Reactions, F. Diedeeich, P. Stang (eds.), Wiley-VCH, Wein-heim, 1998, p. 223. I. Maeek, J. F. Noe-MANT, in Metal-catalyzed Cross-coupling Reactions, F. Diedeeich, P. Stang (eds.), Wiley-VCH, Weinheim, 1998, p. 271. [Pg.277]

Recent trend in the synthesis of olefinic pheromones is the use of transition metal-catalyzed cross coupling reaction for carbon-carbon bond formation. Scheme 8 summarizes a synthesis of the termite trail marker pheromone, (3Z,6Z)-3,6-dodecadien- l-ol (2) by Oehlschlager [19]. The key-step is the palladium-catalyzed cross-coupling of allylic chloride A and alkenylalane B. [Pg.9]

Isoxazoles are privileged aromatic heterocycles due to their wide spectrum of biological activities and their use as versatile building blocks in organic synthesis. Recent progress in the field of transition-metal-catalyzed cross-coupling reactions on isoxazole systems has been summarized and discussed <06EJO3283>. [Pg.288]

Metal-catalyzed cross-coupling reactions between organozinc derivatives and alkyl halides 405... [Pg.311]

Metal-catalyzed cross-coupling reactions of organozinc derivatives with aryl and vinyl halides 408... [Pg.311]

Knochel, P. Calaza, M. I. Hupe, E. In Metal-catalyzed Cross-coupling Reactions, 2nd ed. de Meijere, A., Diederich, F., Eds. Wiley ... [Pg.415]

E.-i. Negishi, in Metal-Catalyzed Cross-Coupling Reactions (Eds. F. Diederich,... [Pg.280]

Metal-catalyzed cross-couplings are key transformations for carbon-carbon bond formation. The applicability of continuous-flow systems to this important reaction type has been shown by a Heck reaction carried out in a stainless steel microreactor system (Snyder et al. 2005). A solution of phenyliodide 5 and ethyl acrylate 6 was passed through a solid-phase cartridge reactor loaded with 10% palladium on charcoal (Scheme 2). The process was conducted with a residence time of 30 min at 130°C, giving the desired ethyl cinnamate 7 in 95% isolated yield. The batch process resulted in 100% conversion after 30 min at 140°C using a preconditioned catalyst. [Pg.10]

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