Measurements centrifuge

As in sedimentation, the concentration of the particles in the elutriators affects the results of measurement. Also the velocity in the elutriators tends to be parabolic rather than uniform and thus introduces errors in measurement. Centrifugal force can also be applied like that in the sedimentation to enhance the performance. Different designs, including horizontal elutriators, are available. 

The water and sediment contents of crude oils is measured according to the standard methods NF M 07-020, ASTM D 96 and D 1796, which determine the volume of water and sediments separated from the crude by centrifuging in the presence of a solvent (toluene) and of a demulsifylng agent Table 8.13 gives the bottom sediment and water content of a few crude oils. 

The behavior of drops in the centrifugal field has been studied (211) and the residence times and mass-transfer rates have been measured (212). PodbieHiiak extractors have been widely used in the pharmaceutical industry, eg, for the extraction of penicillin, and are increasingly used in other fields as weU. Commercial units having throughputs of up to 98 m /h (26,000 gal/h) have been reported. 

Percentage of water imbibition is an important property in ease-of-care and quick-drying fabrics. This value is determined by measuring the moisture remaining in a fiber in equiUbrium with air at 100% rh while the fiber is being centrifuged at forces up to 1000 g. The average recorded value for acetate is 24% triacetate not heat-treated, 16% and heat-treated triacetate, 10%. 

The scale-up of filtration centrifuges is usually done on an area basis, based on small-scale tests. Buchner funnel-type tests are not of much value here because the driving force for filtration is not only due to the static head but also due to the centrifugal forces on the Hquid in the cake. A test procedure has been described with a specially designed filter beaker to measure the intrinsic permeabiHty of the cake (7). The best test is, of course, with a small-scale model, using the actual suspension. Many manufacturers offer small laboratory models for such tests. The scale-up is most reHable if the basket diameter does not increase by a factor of more than 2.5 from the small scale. 

Fat Content of Milk. Raw milk as well as many dairy products are routinely analyzed for their fat content. The Babcock test, or one of its modifications, has been a standard direct measure for many years and is being replaced by indirect means, particularly for production operations. The Babcock test employs a bottle with an extended and caHbrated neck, milk plus sulfuric acid [7664-93-9] to digest the protein, and a centrifuge to concentrate the fat into the caHbrated neck. The percentage of fat in the milk is read direcflv from the neck of the bottle with a divider or caHper, rea ding to... 

In dye-binding tests, milk is mixed with excess acidic dye solution where the protein binds the dye in a constant ratio and forms a precipitate. After the dye—protein interaction takes place, the mixture is centrifuged and the optical density of the supernatant is determined. Utilization of the dye is thus measured and from it the protein content determined. Several methods for appHcation of dye-binding techniques to milk are given (24,25). 

Sedimentation (qv) techniques, whether based on gravitational forces or centrifugation, derive the particle size from the measured travel rates of particles in a Hquid. Before the particle analysis is carried out, the sample is usually dispersed in a medium to break down granules, agglomerates, and aggregates. The dispersion process might involve a simple stirring of the powder into a Hquid, but the use of an ultrasonic dispersion is preferred. 

Every method, with the exception of imaging technologies, provides the measurement of an equivalent spherical diameter in one form or another. The spherical diameter information can be deduced indirectiy from the behavior of the particles passing through restricted volumes or channels under the influence of gravity or centrifugal force fields, and from interaction with many forms of radiation. 

Properties of copper—tin—lead alloys are Hsted in Table 10. The members of the tin bronze alloy group are cast using the centrifugal, continuous, permanent, plaster, and sand molding methods. Leaded tin—bronze alloys have minimum tensile strengths of 234—248 MPa (34,000—36,000 psi) as cast in sand molds, whereas the minimum tensile strengths for high leaded tin—bronze alloys are 138—207 MPa (20,000—30,000). The values are based on measurement of test bars cast in sand molds. 

Fig. 10. The Groth ZG 5 centrifuge. R, rotor R, stationary shaft T, Teflon seal K, K, chambers for gas scoops S, S2, scoops V, gas supply M, manometer Z, Z2, tapping points for enriched and depleted gas P, P2, vacuum chambers E, electromagnet for eddy current heating Tb, Tb2, temperature measuring devices K, cooling coil and D, D2, labyrinth seals.

For determination of the aerodynamic diameters of particles, the most commonly apphcable methods for particle-size analysis are those based on inertia aerosol centrifuges, cyclones, and inertial impactors (Lundgren et al.. Aerosol Measurement, University of Florida, Gainesville, 1979 and Liu, Fine Paiiicles—Aerosol Generation, Measurement, Sampling, and Analysis, Academic, New York, 1976). Impactors are the most commonly used. Nevertheless, impactor measurements are subject to numerous errors [Rao and Whitby, Am. Ind. Hyg. A.s.soc.]., 38, 174 (1977) Marple and WiUeke, "Inertial Impactors, in Lundgren et al.. Aerosol Measurement and Fuchs, "Aerosol Impactors, in Shaw, Fundamentals of Aerosol Sci-... 

G-Level Centrifugal acceleration G is measured in multiples of earth gravity g ... 

Note in Eq. (18-112) that Vg is the settling rate under Ig, and it is a function of the particle size and density and fluid properties. The ratio ( /2Vg is then related only to the operating speed and geometry of the centrifuge, as well as to the size recoveiy. It measures the required... 

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