Condition measurement

Several manufacturers of transducers and equipment were contacted to give their best solution of the problems. Two instruments and five types of transducers were selected for further experiments. The equipments were very different concerning the possibility for controlling the measuring conditions and the transducer frequencies where from 10 MHz to 25 MHz with different crystal diameters and focussing lenses. 

As a fist attempt to see the influence of the tube drawing and the industrial environment on measured data, some experiments were performed for improving the measuring chamber and guidance as well optimizing the measuring condition. The main results were ... 

However, the situation is much less complex for NMR spectra. Whereas measurement conditions may have a high impact on NMR spectra, chemical shift... 

Flow nozzles are commonly used in the measurement of steam and other high velocity fluids where erosion can occur. Nozzle flow coefficients are insensitive to small contour changes and reasonable accuracy can be maintained for long periods under difficult measurement conditions that would create unacceptable errors using an orifice installation. 

In research environments where the configuration and activity level of a sample can be made to conform to the desires of the experimenter, it is now possible to measure the energies of many y-rays to 0.01 keV and their emission rates to an uncertainty of about 0.5%. As the measurement conditions vary from the optimum, the uncertainty of the measured value increases. In most cases where the counting rate is high enough to allow collection of sufficient counts in the spectmm, the y-ray energies can stih be deterrnined to about 0.5 keV. If the configuration of the sample is not one for which the detector efficiency has been direcdy measured, however, the uncertainty in the y-ray emission rate may increase to 5 or 10%. 

Peracid Classification. Peracids can be broadly classified into organic and inorganic peracids, based on standard nomenclature. The limited number of inorganic peracids has required no subclassification scheme (4). However, the tremendous number of new organic peracids developed (85) has resulted in proposals for classification. Eor example, a classification scheme based on Hquid chromatography retention times and critical miceUization constants (CMC) of the parent acids has been proposed (89). The parent acids are used because of the instabiHty of the peracids under chromatographic and miceUization measurement conditions. This classification scheme is shown in Table 1. 

Field Measurement Conditions Those gathering samples must be aware of the temperature, pressure, flamm ihty, and toxic characteristics of the samples for which they will be responsible. This is particularly important when samples are taken from unfamihar locations. Sample ports will have to be blown down to obtain representative samples. Liquid samples will have to be vented. Temperatures above... 

Attention must be paid to the specific technical problems posed by measuring flow in industrial ventilating systems, such as high turbulence level and long time-variation of mean velocity. The LDA measurement conditions (statistically sufficient number of LDA data, suitably long duration of LDA measurements for recognition of long-term phenomena) must be carefully selected for an appropriate treatment of these problems. 

Fig. 3.1.4 Bioluminescence spectrum of Cypridina luciferin catalyzed by Cypridina luciferase (A), the fluorescence excitation spectrum of oxyluciferin in the presence of luciferase (B), the fluorescence emission spectrum of the same solution as B (C), and the absorption spectrum of oxyluciferin (D). The fluorescence of oxyluciferin alone and luciferase alone are negligibly weak. Measurement conditions A, luciferin (lpg/ml) plus a trace amount of luciferase in 20 mM sodium phosphate buffer, pH 7.2, containing 0.2 M NaCl B and C, oxyluciferin (20 pM) plus luciferase (0.2mg/ml) in 20 mM sodium phosphate buffer, pH 7.2, containing 0.2 M NaCl D, oxyluciferin (41 pM) in 20 mM Tris-HCl buffer, pH 7.6, containing 0.2 M NaCl. All are at 20°C.

Figure 21.22 shows the comparison between the XEL spectra of Ba3BP3 Oi2 Eu and that of Bi4Ge30i2 powders with the same measurement conditions. It is worthwhile to note that both spectra have a similar broad emission band. The integral area of the emission bands for Ba3BP30i2 Eu powders is... 

All these systems have been pnt into mathematical formnlae that can be transferred to each other, bnt possibly different measuring conditions mnst be taken into account. The British Standards Institnte and the International Standards Organization have edited general gnidance and test methods for the assessment of the colors of foods. ... 

It must be underlined that independently of the MS equipment characteristics, no information about stereo-chemistry can be obtained. In fact, cis and trans isomers of the corresponding carotenoid showed identical mass spectra, as did carotenoids with epoxide groups at 5,6 and 5,8 positions. In addition, special care should be taken in assigning carotenoid molecular masses to avoid confusion due to the various ions that may be formed depending on measurement conditions. 

It is important to note that most molecules are not rigid but may prefer a distrinct structure and the conformation of a molecule strongly depends on its specific environment. Hence, the crystal structure of a drug does not have to correspond to the receptor bound conformation. Also, a conformation in solution depends on the nature of the solvent and measuring conditions, and may change when the molecule is bound to the receptor [4]. In addition, different receptors or receptor subtypes can bind the same drug in different conformations. It is a general assumption and observation, but by far not a strict condition, that the conformation in aqueous solution is similar to the bound conformation and is a better representation of the bioactive conformation than an X-ray structure of the isolated molecule in the crystalline state. 

Identification of sources of analytical bias in method development and method validation is another very important application of reference materials in geochemical laboratories. USGS applied simplex optimization in establishing the best measurement conditions when the ICP-AES method was introduced as a substitute for AAS in the rapid rock procedure for major oxide determinations (Leary et al. 1982). The optimized measurement parameters were then validated by analyzing a number of USGS rock reference samples for which reference values had been established first by classical analyses. Similar optimization of an ICP-AES procedure for a number of trace elements was validated by the analysis of U S G S manganese nodule P-i (Montaser et al. 1984). 

SFC-NMR is available from 200 to 800 MHz, and is suitable for all common NMR-detected nuclei. SFC/SFE-NMR requires dedicated probe-heads for high pressure (up to 350 bar) and elevated temperature (up to 100 °C). SFC-NMR is carried out with conventional packed columns, using modifier, pressure and temperature gradients. The resolution of 1H NMR spectra obtained in SFE-NMR and SFC-NMR coupling under continuous-flow conditions approaches that of conventionally recorded NMR spectra. However, due to the supercritical measuring conditions, the 111 spin-lattice relaxation times 7) are doubled. 

It remains possible to check the correctness of the end-point detection by calibration on samples of known composition under the same measurement conditions a similar procedure consists in the differential titrations introduced by Pinkhof and Treadwell, who used a reference electrode, identical with the indicator electrode, but dipped it into a solution buffered to the end-point potential value67. 

The irradiation and measurement conditions for the analyses are given in the Table 4.2. 

Lack of reliable measurement is the first reason, as reliable ground-based measurements by scientific instruments have been made just in this century. These measure conditions only at the location of each instrument, and they are usually land-based, although 75% of the Earth is covered with water. We have been able to take precise, direct measurements only in the last four decades, and not until the advent of precision space borne instruments in the 1970s were we able to measure global temperatures at a range of altitudes across the entire atmosphere. 

The reason for this is that a series of strong interactions within a solid sample broaden the linewidth to such an effect that no signal appears to be present under these measurement conditions. 

Repeated measurements of the same measurand on a series of identical measuring samples result in random variations (random errors), even under carefully controlled constant experimental conditions. These should include the same operator, same apparatus, same laboratory, and short interval of the time between measurements. Conditions such as these are called repeatability conditions (Prichard et al. [2001]). The random variations are caused by measurement-related technical facts (e.g., noise of radiation and voltage sources), sample properties (e.g., inhomogeneities), as well as chemical or physical procedure-specific effects. 

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