Marine carbonate system

The application of these equations to the marine carbon system is illustrated by program ISOT01, which adds isotopes to the three-reservoir system of atmosphere, shallow ocean, and deep ocean presented in program DGC10 in Chapter 5. In subroutine EQUATIONS, equations 6 to 8 are for the stable isotope 13C, and equations 9 to 11 describe radiocarbon. The rest of the physical system is identical to that of program DGC10. 

The marine carbonate system is thought to participate in another set of interlinked processes that acts to regulate atmospheric CO2 levels over time scales of 5 to lOky. This shorter cycle is commonly referred to as carbonate compensation and appears... 

In order to understand the formation of beachrock, some fundamentals of the marine carbonate system (C02-H20-CaC03) and calcium carbonate precipitation and dissolution have to be considered. Only limited aspects of the subject can be discussed here as the topic is complex and treated at length in various textbooks (e.g. Lippmann, 1973 Berner, 1980 Morse and Mackenzie, 1990). 

Varney M (1996) The marine carbonate system. In Summerhayes CP and Thorpe SA (eds.) Oceanography an Illustrated Guide, pp. 182-194. London Manson Publishing. 

The carbon dioxide (physically) dissolved in water - we denote it as C02 aq) -is in equilibrium with gaseous atmospheric carbon dioxide C02(g). There is no way to separate non-ionic dissolved C02 aq) and H2CO3 therefore, it is often lumped into C02 aq). Analytically, DIC can be measured by acidifying the water sample, extracting the CO2 gas produced and measuring. The marine carbonate system represents the largest carbon pool in the atmosphere, biosphere and ocean, meaning it is of primary importance for the partition of atmospheric excess carbon dioxide produced by human activity. 

The advantage of the ISFET sensors includes reduced drift and noise due to stray currents as a result of the lower impedance compared to an ISE. A number of applications have been described for the determination of environmental water parameters, notably long-term unattended pH measurements in the open ocean. Precise seawater-pH data (better than 0.002 pH units) with good spatial and temporal coverage are particularly critical to appreciate ocean-acidification phenomena and their consequences on the marine carbonate system. 

The carbonate system plays a pivotal role in most global cycles. For example, gas exchange of CO2 is the exchange mechanism between the ocean and atmosphere. In the deep sea, the concentration of COi ion determines the depth at which CaCOs is preserved in marine sediments. 

Lithium isotope studies of sediments and sedimentary rocks have thus far concentrated on marine clastic and carbonate material. No systematic description of the effects of diagenetic processes on sediments has been made. Clay rich sediments are important to Li budgets in near-surface systems, as they concentrate Li relative to marine carbonates, which are among... 

Figure 15. Diagram showing the major components of the global calcium cycle with b Ca values (denoted as 5). The modem residence time of Ca in the oceans is about 1 million years (Holland 1978 1984). Abbreviations used are SW = seawater, Sed = sedimentation, clastic = clastic sediments, carb = marine carbonate sediments, hydrol = mid-ocean ridge hydrothermal systems, lith = continental lithosphere.

Kitano, Y. On factors influencing the polymorphic crystallization of calcium carbonate found in marine biological systems. In Recent researches in the fields of hydrosphere, atmosphere, and nuclear geochemistry. Tokyo, 1964, 305-319. 

At this stage in the development of the subject of the geochemistry of sedimentary carbonates, we have dealt primarily with the mineralogy and basic physical chemistry of the carbon system and some of its important phases. In the following chapters, this information and additional data and interpretations are utilized to explain the behavior of sedimentary carbonates in shallow water and deep marine environments, and during early and late diagenesis. The... 

Kristensen, E., and Blackburn, H. (1987) The fate of organic carbon and nitrogen in experimental marine sediment systems influence of bioturbation and anoxia. J. Mar. Res. 45, 231-257. 

So far we have discussed the occurrence of 14C in hydrological systems. In a similar way one can follow 13C. Its abundance in rocks, organic material, and groundwater is expressed in permil deviation of the 13C 12C ratio in the sample from that in a standard (PDB—a belamnite carbonate from the Pee Dee formation of South Carolina). Most marine carbonate rocks have <513C = — 2 to 0%o, whereas frequent values for organic material and C02 in soil are —28%o to — 20%o. Most plants have values around —23 + 3%o, but certain plants have more positive values, around —12 + 2%o (Tables 11.3-11.5 and Figs. 11.6 and 11.7). 

Carbon Dioxide and Alkalinity. Marine chemists sometimes adopt activity conventions quite different to those traditionally used in chemistry. It is useful to preface a discussion about the carbon dioxide-calcium carbonate system in the oceans with a brief outline of pH scales. 

Fig. 2.3.2. Comparison of the range in carbon isotopic composition for hermatypic corals, ahermatypic corals, and marine carbonate precipitated in isotopic equilibrium with the COj" — HCO5 — CO2 system of ambient seawater. All of the corals (111 hermatypes and 59 ahermatypes) were collected from shallow-water, reef surface environments at Heron Island, Australia. The length of the horizontal bars is equivalent to the mean one standard deviation (Weber, 1974).

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