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Magnetic fields equation

This non-relativistic equation in terms of four-component spinors has been studied in detail by Levy-Leblond [44,45], who has shown that it results automatically from a study of the irreducible representations of the Gahlei group and that it gives a correct description of spin. It is easy to see that in the absence of an external magnetic field, equation (63) is equivalent to the Schrodinger equation in the sense that after elimination of the small component ... [Pg.452]

The TDDFT equations quoted in this section describe a system in the absence of a magnetic field. Equations (40W50) therefore provide a method for calculating the unperturbed excitation energy... [Pg.61]

In a magnetic resonance experiment designed to record the rotational spectrum, the fixed radiation frequency would be close to the resonant zero-field frequency, with the mismatch being tuned with a swept magnetic field. Equation (9.95) enables us to calculate the behaviour of the levels as a function of magnetic field strength we show the results for both the TV = 1 and 2 rotational levels in figure 9.25, appropriate for the CN radical where yv=0 has the value 217.5 MHz [55]. [Pg.638]

ESR spectroscopy is a sensitive detection method designed to provide information on radicals. This method, also known as electron paramagnetic resonance (EPR) spectroscopy, is naturally a good choice for coupling to electrochemistry as radicals can easily be electrogenerated. ESR involves the detection of unpaired electrons which are affected by nearby nuclei. Radical spin states are modified by interaction with a magnetic field, equation (17). ... [Pg.6472]

Calculating the anomalous electric field from the second Maxwell s equation, and substituting it back into (12.13), we can cast the magnetic field equation in the form... [Pg.364]

The second order electric or magnetic field equations (12.1) can be written in operator form as... [Pg.381]

Spectra at Higher Magnetic Fields Equation 10.7 shows the direct proportionality between the magnetic field strength and the oscillator frequency for proton resonance, where v is the frequency in Hz and... [Pg.317]

Finally if we use the term in (1/r) for the magnetic field, equation (2.69), we obtain a result which is independent of the radius r of the absorbing sphere ... [Pg.41]

Introduction and experimental techniques. In previous sections we drew attention to the fact that, in both the classical and quantum theories, expressions derived for the intensity of resonance fluorescence from atoms subjected to an external magnetic field, equations (15,3) and (15.23) respectively, contain terms which may lead to a modulation of the intensity at the Larmor frequency or its second harmonic. This radio-frequency modulation has been observed in several different kinds of experiment, the simplest of which makes use of pulsed excitation and time-resolved detection of the fluorescent light. [Pg.512]

Fig.16.6. However, since in their experiments all three Zeeman levels were coupled by the r.f. magnetic field, equation (16.21) must be modified to... Fig.16.6. However, since in their experiments all three Zeeman levels were coupled by the r.f. magnetic field, equation (16.21) must be modified to...
TRIFOU is a combined Finite Elements/Boundary Integral formulation code. The BIM formulation in vacuum is suitable for NDT simulation where the probe moves in the air around the test block. The FEM formulation needs more calculation time, but tetrahedral elements enable a large variety of specimens and defect geometries to be modelled. TRIFOU uses a formulation of Maxwell Equations using magnetic field vector h, where h is decomposed as h = hs + hr (hj source field, and hr reaction field). [Pg.141]

The first equation (1) is the equation of state and the second equation (2) is derived from the measurement process. Finally, G5 (r,r ) is a row-vector that takes the three components of the anomalous ciurent density vector Je (r) = normal component of the induced magnetic field. This system is non hnear (bilinear) because the product of the two unknowns /(r) and E(r) is present. [Pg.328]

The magnetic field distribution near the surface of z = 0 separation is considered. The pattern has Ll = 0 magnetic permeability, over the pattern medium is 4 = 1. The equations for (p... [Pg.878]

The central equations of electromagnetic theory are elegantly written in the fonn of four coupled equations for the electric and magnetic fields. These are known as Maxwell s equations. In free space, these equations take the fonn ... [Pg.219]

By analogy, one is tempted to make the same division in equation (A2.1.7), regarding the first tenn as the work of creating the magnetic field in the absence of the specimen and the second, f dV(Uo dAT), as the... [Pg.329]

We now come back to the important example of two spin 1/2 nuclei with the dipole-dipole interaction discussed above. In simple physical tenns, we can say that one of the spins senses a fluctuating local magnetic field originatmg from the other one. In tenns of the Hamiltonian of equation B 1.13.8. the stochastic fiinction of time F l t) is proportional to Y2 (9,( ))/rjo, where Y, is an / = 2 spherical hannonic and r. is the... [Pg.1503]

For a quantum mechanical system pg is replaced by the appropriate operator, equation (bl.15.1) to obtain the Flamiltonian for a free electton in a magnetic field,... [Pg.1549]

Application of an oscillating magnetic field at the resonance frequency induces transitions in both directions between the two levels of the spin system. The rate of the induced transitions depends on the MW power which is proportional to the square of oi = (the amplitude of the oscillating magnetic field) (see equation (bl.15.7)) and also depends on the number of spins in each level. Since the probabilities of upward ( P) a)) and downward ( a) p)) transitions are equal, resonance absorption can only be detected when there is a population difference between the two spin levels. This is the case at thennal equilibrium where there is a slight excess of spins in the energetically lower p)-state. The relative population of the two-level system in thennal equilibrium is given by the Boltzmaim distribution... [Pg.1551]

MW frequency of 10 Hz. There are various considerations that influence the choice of the radiation frequency. Higher frequencies, which require higher magnetic fields, give inlierently greater sensitivity by virtue of a more favourable Boltzmaim factor (see equation (b 1.15.11)). However, several factors place limits on the frequency employed, so that frequencies in the MW region of the electromagnetic spectrum remain favoured. One limitation is the sample size at frequencies around 40 GHz the dimensions of a typical... [Pg.1558]


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See also in sourсe #XX -- [ Pg.38 ]




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