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Low Molar Mass Hydrocarbons

Conformation energies computed for this molecule in the neighbourhood of the trans and gauche minima for bond 2 indicate that the gauche minimum occurs at 112.5° rather than the expected 120° and has a value of 2215 J moC.  [Pg.8]

Similar calculations for the next member of the series, -pentane, give a potential surface, the contours being drawn in values of 1 kcal mol (4.18 kJ mol ) above the minimum conformation, the trans-trans [tt] conformation [Pg.8]

Potential energy curve obtained for z-butane for rotation about the 2,3 central bond of the molecule. [Pg.9]

The tg and g t minima are equivalent to those for w-butane. The g g and g g minima (not shown) occur in the vicinity of (p2 = (p3 = ll0°. Thus the gauche minima for two adjoining bonds in gauche conformations of the same sign are mutually displaced a few degrees from the values ( 112.5°) which would be assumed by each if both of its neighbours were trans. [Pg.9]

The trans minima for neighbouring bonds 1 and 4 are also perturbed a few degrees. These effects arising from subtle interactions between pairs of H atoms on third neighbour carbons are small. The calculated energy for the g g pair is 4932 kJ moP which is close to twice the value for one gauche bond alone. [Pg.9]


This explains the success of the Doolittle empirical equation for the viscosity of low molar mass hydrocarbon liquids ... [Pg.70]

Water and carbon dioxide are the most used solvents due to their low price and environmental friendliness. The critical temperature of water is 473 K and it is used for reactions under extreme conditions.Carbon dioxide, on the other hand, presents a very low critical temperature and it is adequate for reactions carried out under mild conditions, for example, selective hydrogenations. Unfortunately, it is well known that CO2 is not a good solvent for high molar mass organic compounds. Liquid carbon dioxide is miscible with alkanes with up to approximately 10 carbon atoms, while the range of miscibility increases for ethane up to 18 carbon atoms, and for propane up to 30 carbon atoms. Thus, the application of CO2 as reaction media is limited to low molar mass hydrocarbons if a homogenous operation is desired, while ethane and propane are a better option for higher molar mass hydrocarbons. [Pg.447]

Fig. 2 Mineralization of acetone extract of PE (EPITDPA ) after peroxidation (ACQ) compared with cellulose (CELL) and low molar mass hydrocarbon analogues of polyolefins. DOC is docosane (C22H46), SQUA is 2,6,10,15,-19,23-hexamethyl tetracosane, squalane and ACDOC is docosanoic acid (C22H44O2). Fig. 2 Mineralization of acetone extract of PE (EPITDPA ) after peroxidation (ACQ) compared with cellulose (CELL) and low molar mass hydrocarbon analogues of polyolefins. DOC is docosane (C22H46), SQUA is 2,6,10,15,-19,23-hexamethyl tetracosane, squalane and ACDOC is docosanoic acid (C22H44O2).
Alcohols with low molar masses are liquids, and alcohols have much lower vapor pressures than do hydrocarbons with approximately the same molar mass. For example, ethanol is a liquid at room temperature, but butane, which has a higher molar mass than ethanol, is a gas. The relatively low volatility of alcohols is a sign of the strength of hydrogen bonds. The ability of alcohols to form hydrogen bonds also accounts for the solubility in water of alcohols with low molar mass. [Pg.875]

The generic name hydrocarbon resins designates several families of low molar mass polymers (M from 600 to 104) obtained by polymerization of petroleum, coal tar, and turpentine distillates [80-82], In most cases, these products are obtained by cationic polymerization of mixtures either of aliphatic and/or aromatic mono and diolefins present in the more or less enriched Cs and C9 feedstreams, or of pure aromatic monomers generally of the styrene type. They are complex mixtures of polymers ranging from viscous liquids and tacky fluids to hard, brittle thermoplastics, and are used as additives in adhesives, printing inks, rubbers, coatings, etc. [80-82], They are obviously amorphous and are characterized by their softening point (0 to —150° C), determined by standardized methods (i.e.,... [Pg.703]

The carbonyl oxygen atom allows molecules of aldehydes to form strong hydrogen bonds with water molecules. As a result, low molar mass aldehydes show appreciable solubilities in water. As the molar mass increases, polarity decreases because of the effect of the hydrocarbon groups, hence the solubility in water also decreases. [Pg.67]

PAHs may be synthesized from saturated hydrocarbons under oxygen-deficient conditions. Hydrocarbons with very low molecular masses, including even methane, may act as precursors for the polycyclic aromatic compounds. The process of PAH formation from low molar mass HCs is called pyrosynthesis. This happens at temperatures exceeding 500 C at which C - H and C - C bonds are broken to form free... [Pg.65]

Although liquid crystals were discovered in 1888 [369], chemical concepts are only now being developed for converting the type of mesophase exhibited by a given chemical structure. Compounds which normally form only nematic mesophases can be forced to order into smectic layers by incorporating immiscible fluorocarbon units into their hydrocarbon chemical structure. Comparison of the data in Tables 7, 20 and 21 demonstrate that smectic layering is induced not only in low molar mass liquid crystals, but... [Pg.197]

Hydroxylic solvents, such as water or low-molar-mass alcohols, are often used to purify amides such as the acetanilides produced in this experiment. Briefly explain why these are used in preference to hydrocarbon solvents like petroleum ether. [Pg.740]

The most important physical effect of peroxidation in hydrocarbon polymers is to reduce the molar mass of the polymer leading to deterioration in mechanical properties. Peroxidation, whether abiotically or biologically initiated, leads to the formation of hydrophilic chemical species such as carboxylic acids and alcohols particularly in the surface layers of the polymer. This enables microorganisms to colonise the polymer surface and utilise the low molar mass oxygenated species as nutrients in the absence of other sources of carbon. ... [Pg.11]

Arehart SV, Pugh C (1997) Induction of smectic layering in nematic liquid crystals using immiscible components. 1. laterally attached side-chain liquid crystalline poly(norbomene)s and their low molar mass analogs with hydrocarbon/fluorocarbon substituents. J Am Chem Soc 119 3027-3037... [Pg.408]

Chiellini et al. [58] extracted thermally peroxidised polyethylene with acetone and measured the rate of mineralization of the solvent free extracts in forest soil. This is compared with cellulose and a number of low molar mass control hydrocarbons in Fig. 2. Surprisingly, the peroxidation products were converted to carbon dioxide and water more rapidly than cellulose. The extracted polyethylene degraded at a similar rate to the pure hydrocarbons and it is evident from this work that the rate controlling process in the overall sequence of degradation reactions is the initial peroxidation of the polymer. It has been demonstrated [19] that the exposure of peroxidised PE to an abiotic water-leaching environment did not remove the peroxidation products from the polymer, whereas bioassimilation began immediately (see Fig. 2)... [Pg.42]

An amine is a derivative of ammonia, NHa, in which one or more of the hydrogen atoms have been replaced by a hydrocarbon group (e.g., CH3, C2H5). Amines can be classified according to the number (1, 2, or 3) of hydrocarbon groups bonded to nitrogen (Table B, page 429). Most amines of low molar mass are volatile with distinctly unpleasant odors. For example, (CH3)3N is a gas at room temperature (bp = 3°C) with an odor somewhere between those of ammonia and spoiled fish. [Pg.428]

The authors concluded from this premise that every pound of plastic that has been produced, if it has not been burned, is still with us . This reasoning ignores the fact that abiotic as well as biotic processes are involved in the bioassimilation of all polymers, natural as well as synthetic. Thus the hydrophobic hydrocarbon polymers, cfr-polyisoprene (cfr-Pl) and cfr-polybutadiene (cfr-PB) begin to biodegrade only after exposure to the environment, when peroxidation leads to low molar mass products that support microbial growth. The relevance of this fact to polyolefin bidegradation will be discussed further in Section 12.4. [Pg.316]

Direct comparisons between hydrocarbon and siloxane main chains are few for lyotropic side chain polymer liquid crystals. Pietschmann et al. have recently synthesised polymers of 1,3-diols which differ in the nature of the polymer backbone. DSC and optical polarizing microscopy were used to construct the phase diagrams. These were compared with the phase diagrams obtained for the analogous low-molar-mass compounds. The structures of the polyacrylate (I) and polymethacrylate (II) based materials are shown below ... [Pg.262]


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