Layered double hydroxides application

Keywords Layered double hydroxides Application Intercalation Calcination... 

Shan, D., Cosnier, S., Mousty, C. HRP wiring by redox active layered double hydroxides application to the mediated H202 detection. Anal. Lett. 36(5), 909-922 (2003). doi 10.1081/ AL-120019252... 

Evans, D.G. and Duan X. (2006) Preparation of layered double hydroxides and their application as additives, polymers, as precursors to magnetic materials and in biology and... 

Kloprogge JT (ed)(2005) The Application of Vibrational Spectroscopy to Clay Minerals and Layered Double Hydroxides. Clay Minerals Society, Aimora Kloprogge JT, Frost RL (1999) J Solid State Chem 146 506... 

Abstract This chapter is intended to provide a state-of-the-art review of nanocomposite materials prepared by the assembly of layered double hydroxides (LDH) and polymers, including their synthesis and characterization, and point out their potential applications. 

The selective intercalation of guests into solid hosts offers the potential for application in catalysis and separation science. An excellent case in point is zeolites, which exhibit shape and size selective inclusion properties and are used for an enormous variety of processes [44,45]. Additionally, a munber of layered materials have been reported to possess selective intercalation properties, including layered metal phosphonates [46,47], montmorUlonite [48], magnesium aluminum oxide [49], and layered double hydroxides [50-59]. 

Iu search for efficieut aud greeuer processes over the past few years various heterogeneous catalysts such as titanium incorporated mesoporous molecular sieves [45,46], Schiff-base complexes supported on zeolite [47] and Zn(II)-Al(III) layered double hydroxide (LDH) [48], oxomolybdenum(VI) complexes supported on MCM-41 and MCM-48 [49], polyoxometallate supported materials [50], Co and Mn-AlPO s [51] etc. have been developed and studied for the catalytic epoxidatiou of a-pinene. Many of these processes suffer from drawbacks and limited applicability due to the poor conversion and also the selectivities. Sacrificial aldehydes are often used as an oxygen acceptor in such processes to achieve reasonable yield and selectivities but, this procedure leads to an increase in the E-factors and decrease in the atom economy [51]. 

Li F, Duan X (2005) Applications of Layered Double Hydroxides 119 193-223 Liebau F, see Santamarfa-Perez D (2005) 118 79-135... 

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Newman, S. P. and Jones, W. (1998). Synthesis, characterization and applications of layered double hydroxides containing organic guests. New J. Chem. 22, 105. 

Khan, A.L, and O Hare, D. 2002. Intercalation chemistry of layered double hydroxides Recent developments and applications. Journal of Materials Chemistry 12, 3191-3198. 

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