Lamin formation

Aramid paper laminates can be formed by calendering the opposing surfaces of the aramid paper at different temperatures prior to laminate formation [45]. Laminates made from aramid paper laminates are useful in electrical transformers, wherein the laminate serves as a dielectric insulation material. 

The Amadori compounds can react further with a second sugar molecule, resulting in glycosy-lamine formation and subsequent conversion to di-D-ketosylamino acids ( diketose amino acids ) by an Amadori rearrangement ... 

Hagiwara, T., 1994. Response of 2 MHz resistivity devices in thinly laminated formations (anisotropic resistivity and EM log interpretation). In Presented at SPE 69th Annual Technical Conference, pp. 667-675. Paper 28426. 

Direct irradiation of [60]fuUerene 47 in the presence of trimethylamine is reported to yield the adducts 47a and 47b as primary and secondary products (Scheme 29). Only small amounts of these adducts are isolated from complex product mixtures. Formation of 47a is proposed to occur via an electron transfer, proton transfer, radical coupling mechanism similar to that for addition of stilbene and trialky-lamines. Formation of 47b is found to require oxidation of 47a by singlet fuUerene. Direct irradiation of 47 with dimethylamine in the presence of air is reported to result in the formation of the tetra(amino)fullerene epoxide 47c (Scheme 29). Isolated yields as high as 98% are reported for the reaction of N-methylpiperazine. More hindered secondary amines such as EtjNH and primary amines fail to undergo this extraordinary reaction. 

Lafarie-Frenot, M.C. and Henaff-Gardin, C., Formation and Growth of 90° Ply Fatigue Cracks in Carbon/Epoxy Laminates , Composites Science and Technology Vol. 40, p. 307-324, 1991... 

If desired, the alcohol may be identified as the 3 5-dinitrobenzoate (Section 111,27) it is then best to repeat the experiment on a larger scale and to replace the dilute hydrochloric acid by dilute sulphuric acid. It must, however, be pointed out that the reaction is not always so simple as indicated in the above equation. Olefine formation and rearrangement of the alcohol sometimes occur thus n-prop3 lamine yields n-propyl alcohol, isopropyl alcohol and propylene. 

This polymerization is carried out in the two stages indicated above precisely because of the insolubility and infusibility of the final product. The first-stage polyamide, structure [IX], is prepared in polar solvents and at relatively low temperatures, say, 70°C or less. The intermediate is then introduced to the intended application-for example, a coating or lamination-then the second-stage cyclization is carried out at temperatures in the range 150-300°C. Note the formation of five-membered rings in the formation of the polyimide, structure [X], and also that the proportion of acid to amine groups is 2 1 for reaction (5.II). 

In the cuspation—dilation thermoforming process developed in AustraHa, sheet formation is promoted by expanding blades extending into aU areas and distributing the material uniformly throughout the mold. This process is claimed to deHver uniform distribution of high barrier components of sheet coextmsions and laminations. The process also permits almost vertical side waUs to cups (2). 

Plastic laminated sheets produced in 1913 led to the formation of the Formica Products Company and the commercial introduction, in 1931, of decorative laminates consisting of a urea—formaldehyde surface on an unrefined (kraft) paper core impregnated with phenoHc resin and compressed and heated between poHshed steel platens (8,10). The decorative surface laminates are usually about 1.6 mm thick and bonded to wood (a natural composite), plywood (another laminate), or particle board (a particulate composite). Since 1937, the surface layer of most decorative laminates has been fabricated with melamine—formaldehyde, which can be prepared with mineral fiUers, thus offering improved heat and moisture resistance and allowing a wide range of decorative effects (10,11). 

A comment on the properties of the base employed in reactions that involve the formation of the Vilsmeier-Haack adduct is in order, because several derivatives of cellulose are obtained by this route. Preparation of Cell-Tos has been attempted in LiCl/DMAc, by reacting the polymer with TosCl/base. Whereas the desired product was obtained by employing triethy-lamine, use of pyridine (Py) resulted in the formation of chlorodeoxycellu-lose. In order to explain these results, the following reaction pathways have been suggested [147] ... 

Lower-density E-plastomers have found alternate use in cast film processes to make elastic film laminates with good breathability which contain laminates of liquid impermeable extensible polymeric films with extensible-thermoplastic-polymer-fiber nonwovens and nonwoven webs of polyethylene-elastomer fibers as the intermediate layers. The development relates to a breathable film including an E-plastomer and filler that contributes to pore formation after fabrication and distension of the film. The method and extent of distension is designed to produce a breathable film by stretching the film to form micropores by separation of the film of the E-plastomer from the particulate solids. This film is useful for manufacture of absorbent personal-care articles, such as disposable diapers and sanitary napkins and medical garments. In detail, these constructions comprise a liquid impermeable extensible film comprising polyolefins. The outer layer contains extensible-thermoplastic-polymer-fiber nonwovens, and an elastic intermediate layer contains nonwoven webs of fiber E-plastomers. The intermediate layer is bonded to the film layer and the outer... 

One of the important aspects of the development of P-plastomers was the expectation that these materials were amenable to plastics processing such as fiber and film formation and yet would yield soft elastic fabrication. This combination was hitherto unknown [24]. The formation of nonwoven fabrics including spun-bond and melt-blown nonwoven fabrics as well as their laminated forms has been documented. Similarly, cast film operation to form elastic monolithic films or composite structures which are not only amenable to these processes, but also to a variety of postfabrication processes have been described. 

Curing of Polyimlde Resin. Thermoset processing involves a large number of simultaneous and interacting phenomena, notably transient and coupled heat and mass transfer. This makes an empirical approach to process optimization difficult. For instance, it is often difficult to ascertain the time at which pressure should be applied to consolidate the laminate. If the pressure is applied too early, the low resin viscosity will lead to excessive bleed and flash. But if the pressure is applied too late, the diluent vapor pressure will be too high or the resin molecular mobility too low to prevent void formation. This example will outline the utility of our finite element code in providing an analytical model for these cure processes. 

Euran Furan resins are thermosetting polymers derived from furfuryl alcohol and Furfural. The cure must be carefully controlled to avoid the formation of blisters and delaminations. To obtain optimum strength and corrosion resistance, furan composites must undergo a postcure schedule at carefully selected temperatures depending upon the laminate thickness. Equipment made with furan resins exhibits excellent resistance to solvents and combinations of acids and solvents. These resins are not for use in strong oxidizing environments. 

The Onnagawa Formation conformably overlies the Nishikurosawa Formation and is composed of siliceous shale and shale. The rocks are characterized by organic-rich laminated diatomaceous deposits, siliceous microfossils, and fish bones, while foraminiferal fossil is poor in amounts. The total thickness is about 3(X) m. The age of base of the Onnagawa Formation is estimated to be 12.9 Ma based on diatoms (Koizumi and Matoba, 1989). The age of the top of the Formation is 5.8 Ma. 

Imai, H., Tatara, S., Furuichi, K. and Oaki, Y. (2003) Formation of calcium phosphate having a hierarchically laminated architecture through periodic precipitation in organic gel. Chemical Communications, 1952—1953. 

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