Kumada

Nickel (II) Catalyzed Cross-Coupling with Grignard Reagents (Kumada Reaction) Pure AppJ. Chem. 1980, 52, 669 Bull Chern. Soc.Jpn. 1976, 49, 1958... [Pg.113]

KUMADA NEGISHI Cross coupling Stsreospecific alkenyl aluminum-alkenyl halide cross coupling catalyzed by Pd or Ni... [Pg.222]

JAN972 M. Kitahara, K. Ishii, Y. Kumada, T. Shiraishi, T. Furuta, T. Miwa,... [Pg.165]

M17 El. Fujimiya, S. Nakashima, T. Kumada, Y. Nakamura, El. Miyata,... [Pg.268]

In 1971, a short communication was published [54] by Kumada and co-workers reporting the formation of di- and polysilanes from dihydrosilanes by the action of a platinum complex. Also the Wilkinson catalyst (Ph3P)3RhCl promotes hydrosilation. If no alkenes are present, formation of chain silanes occurs. A thorough analysis of the product distribution shows a high preference for polymers (without a catalyst, disproportionation reactions of the silanes prevail). Cross experiments indicate the formation of a silylene complex as intermediate and in solution, free silylenes could also be trapped by Et3SiH [55, 56],... [Pg.30]

Yamamoto K, Okinoshima H, Kumada M (1971) J Organomet Chem 27 C 31 and references therein... [Pg.42]