Grignard reagents Kumada cross-coupling

Nickel (II) Catalyzed Cross-Coupling with Grignard Reagents (Kumada Reaction) Pure AppJ. Chem. 1980, 52, 669 Bull Chern. Soc.Jpn. 1976, 49, 1958... 

CROSS-COUPLING OF ARYLCHLORIDES WITH ARYL GRIGNARD REAGENTS (KUMADA REACTION)... 

The Kumada cross-coupling reaction (also occasionally known as the Kharasch cross-coupling reaction) is a nickel- or palladium-catalyzed cross-coupling reaction of a Grignard reagent with an organic halide, triflate, etc. 

Huang, J. Nolan, S. P. Efficient cross-coupling of aryl chlorides with aryl Grignard reagents (Kumada reaction) mediated by a Pd/imidazolium chloride system./. Am. 

Pd- or Ni-catalyzed Kumada cross-coupling Cross-coupling of alkenyl- or aryl halides and Grignard reagents or organolithium species. 258... 

Huang, J., Nolan, S. P. Efficient Cross-Coupling of Aryl Chlorides with Aryl Grignard Reagents (Kumada Reaction) Mediated by a Palladium/lmidazolium Chloride System. J. Am. Chem. Soc. 1999, 121,9889-9890. 

A few palladium-catalyzed Kumada cross-couplings of heteroaryl chlorides have been reported [101]. Knochel has recently determined that certain 2-chloropyridine derivatives react with functionalized aryl Grignard reagents under mild conditions (Equation 2.61) [102]. 

Cross-couplings between organotin (Stille type), Grignard reagent (Kumada type), and aryl halide have been carried out using palladium over silica support. ... 

The synthesis of a 3-alkylthiophene mcMiomer can be achieved in several different ways. One rather simple way involves Kumada cross-coupling of 3-bromothiophene (9) with an alkyl Grignard reagent, as seen in Scheme 4 [52]. 

Nickel bisphosphine complexes are used as catalysts in cross-coupfing of aromatic and olefinic halides with Grignard reagents. Kumada and co-workers [69] reported a cross-coupling reaction... 

Early preparations of polythiophene employed both electrochemical and chemical methods [1,21-23]. Chemical preparations via oxidative coupling of thiophene or Kumada cross-coupling of Grignard reagents... 

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