Kumada-Corriu-Tamao reaction

The reaction of aryl electrophiles with organomagnesium compounds is known as Kumada or Kumada-Tamao-Corriu reaction. The most common leaving groups in the electrophile are halogen atoms and, among them, chlorine is the most wanted due to the good availability and the low price of aryl or heteroaryl chlorides. Unfortunately, the oxidative addition of a metal center to an aryl chloride is a difficult reaction and many efforts have been made to overcome existing limitations. [Pg.550]

Cadiot-Chodkiewicz reaction, 11, 19 Hiyama reaction, 11, 23 Kumada-Tamao-Corriu reaction, 11, 20 Migita-Kosugi-Stille reaction, 11, 12 Negishi coupling, 11, 27 overview, 11, 1-37 Suzuki-Miyaura reaction, 11, 2 terminal alkyne reactions, 11, 15 Cu-mediated reactions acetylenes, 10, 551 dienes, 10, 552... [Pg.72]

Cross-coupling reactions 5-alkenylboron boron compounds, 9, 208 with alkenylpalladium(II) complexes, 8, 280 5-alkylboron boron, 9, 206 in alkyne C-H activations, 10, 157 5-alkynylboron compounds, 9, 212 5-allylboron compounds, 9, 212 allystannanes, 3, 840 for aryl and alkenyl ethers via copper catalysts, 10, 650 via palladium catalysts, 10, 654 5-arylboron boron compounds, 9, 208 with bis(alkoxide)titanium alkyne complexes, 4, 276 carbonyls and imines, 11, 66 in catalytic C-F activation, 1, 737, 1, 748 for C-C bond formation Cadiot-Chodkiewicz reaction, 11, 19 Hiyama reaction, 11, 23 Kumada-Tamao-Corriu reaction, 11, 20 via Migita-Kosugi-Stille reaction, 11, 12 Negishi coupling, 11, 27 overview, 11, 1-37 via Suzuki-Miyaura reaction, 11, 2 terminal alkyne reactions, 11, 15 for C-H activation, 10, 116-117 for C-N bonds via amination, 10, 706 diborons, 9, 167... [Pg.87]

Iron-platinum carbonyl clusters, characteristics, 8, 415 Iron reagents, in Kumada-Tamao-Corriu reaction, 11, 21 Iron-rhodium clusters, as heterogeneous catalyst precursors,... [Pg.131]

Kumada-Tamao-Corriu reaction Fe-based systems, 11, 21 Ni-based systems, 11, 20 Pd-based systems, 11, 22 reagent systems, 11, 23... [Pg.132]

These reactions are Moritani-Fujiwara reactions, Heck reactions, Mizoroki-Heck reactions, Kumada-Tamao-Corriu reactions, Murahashi reactions, Eto-Hagihara reactions, Negishi reactions, Migita-Kosugi-Stille reactions, Suznki-Miyanra reactions, and Hiyama reactions. [Pg.159]

Unsaturated hydrocarbon halides Kumada-Tamao-Corriu reaction... [Pg.160]

Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...