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Ketones salts

The salts of some enamines crystallize as hydrates. In such cases it is possible that they are derived from either the tautomeric carbinolamine or the amino ketone forms. Amino ketone salts (93) ( = 5, 11) can serve as examples. The proton resonance spectra of 93 show that these salts exist in the open-chain forms in trifluoroacetic acid solution, rather than in the ring-closed forms (94, n = 5, 11). The spectrum of the 6-methylamino-l-phenylhexanone cation shows a multiplet at about 2.15 ppm for phenyl, a triplet for the N-methyl centered at 7.0 ppm and overlapped by signals for the methylene protons at about 8.2 ppm. The spectrum of 93 ( = 11) was similar. These assignments were confirmed by determination of the spectrum in deuterium oxide. Here the N-methyl group of 93 showed a sharp singlet at about 7.4 ppm since the splitting in —NDjMe was much reduced from that of the undeuterated compound. [Pg.275]

Entry Aldehyde or ketone Salt, method0 Oxaspiropentane0 Rearrangement method 1 CycSobutanone Yield" Ref. [Pg.18]

Pyridines from a-pyridinium methyl ketone salts and a,P-unsaturated ketones. [Pg.343]

The same kind of addition can be carried out on the ethynylphosphonium salt 26, generated in situ from the 1,2-vinylenebisphosphonium salt 25, and, depending on the experimental conditions, the vinylphosphonium salt produced can eventually undergo a second addition of YH to produce the / -acetalized or-thioacetalized salt. The same type of /Mieterosubstituted vinylphosphonium salt can also undergo an acidic hydrolysis that leads to the ketonic salt itself335 (reaction 74). [Pg.85]

KrOhnke annulation involves the condensation reaction of an a-pyridinium methyl ketone salt such as phenacylpyridinium bromide 191 to an enones such as benzalacetophenone 193 to afford 2,4,6-triphenylpyridine 194 in 90% yield. Krdhnke found that glacial acetic acid and ammonium acetate were the ideal conditions to promote the desired Michael addition. [Pg.435]

Michael addition, q.v., of oc-pyridinium methyl ketone salts to a,p-unsaturated ketones, generating the 1,5-dicarbonyl compounds which undergo ammonium acetate-promoted ring closure, to yield substituted pyridines ... [Pg.186]

Monocyclic amino-ketone salts can be converted via their bicyclic iminium salts to give bicyclic enamines (Scheme 2). The reaction proceeds well to give... [Pg.357]

Girard s reagents Quaternary ammonium salts of the type Me3NCH2CONHNH2 X which form water-soluble compounds with aldehydes and ketones, and are therefore separable from other neutral compounds the aldehyde or ketone may be subsequently regenerated after separation. [Pg.190]

CH2 CH C CH. Colourless gas with a sweet odour b.p. 5°C. Manufactured by the controlled low-temperature telomerization of ethyne in the presence of an aqueous solution of CuCI and NH Cl. Reduced by hydrogen to butadiene and, finally, butane. Reacts with water in the presence of HgSO to give methyl vinyl ketone. Forms salts. Forms 2-chloro-butadiene (chloroprene) with hydrochloric acid and certain metallic chlorides. [Pg.266]

NH2-C0-NH NH2,CH5N30. Colourless crystalline substance m.p. 96" C. Prepared by the electrolytic reduction of nitrourea in 20% sulphuric acid at 10 "C. Forms crystalline salts with acids. Reacts with aldehydes and ketones to give semicarbazones. Used for the isolation and identification of aldehydes and ketones. [Pg.355]

Since hydroxylamine is usually available only in the form of its salts, e.g., the hydrochloride or sulphate, the aqueous solution of these salts is treated with sodium acetate or hydroxide to liberate the base before treatment with the aldehyde or ketone. Most oximes are weakly amphoteric in character, and may dissolve in aqueous sodium hydroxide as the sodium salt, from which they can be liberated by the addition of a weak acid, e.g., acetic acid. [Pg.93]

Phenylhydrazine on exposure to light slowly darkens and eventually becomes deep red in colour salts of the base share this property but to a lesser degree, the sulphate and acetate (of the common salts) being most stable to light. Phenylhydrazine is largely used in organic chemistry to characterise aldehydes and ketones as their phenyl-hydrazones (pp. 342, 345), and carbohydrates as their osazones (pp. 136-140). It is readily reduced thus in the process of osazone formation some of the phenylhydrazine is reduced to aniline and ammonia. On the... [Pg.199]

Aldehydes and ketones may frequently be identified by their semicarbazones, obtained by direct condensation with semicarbazide (or amino-urea), NH,NHCONH a compound which is a monacidic base and usually available as its monohydrochloride, NHjCONHNH, HCl. Semicarbazones are particularly useful for identification of con jounds (such as acetophenone) of which the oxime is too soluble to be readily isolated and the phenylhydrazone is unstable moreover, the high nitrogen content of semicarbazones enables very small quantities to be accurately analysed and so identified. The general conditions for the formation of semicarbazones are very similar to those for oximes and phenylhydrazones (pp. 93, 229) the free base must of course be liberated from its salts by the addition of sodium acetate. [Pg.258]

By pyrolysis of dibasic acids or their salts to yield cyclic ketones. The slow distillation of adipic acid with about. 5 per cent, of baryta affords cyclo-pentanone in good yield ... [Pg.336]

Cool the mixture and decant the solution from the sodium bromide wash the salt with two 20 ml. portions of absolute alcohol and add the washings to the main solution. Distil off the alcohol, which contains the slight excess of n-propyl bromide used in the condensation, through a short fractionating column from a water bath. The residue A) of crude ethyl n-propylacetoacetate may be used directly in the preparation of methyl n-butyl ketone. If the fairly pure ester is required, distil the crude product under diminished pressure and collect the fraction boihng at 109-113727 mm. (183 g.) (R). [Pg.481]

Separate the ketone layer from the water, and redistil the lattCT rmtil about one third of the material has passed over. Remove the ketone after salting out any dissolved ketone with potassium carbonate (5). Wash the combined ketone fractions four times with one third the volume of 35-40 per cent, calcium chloride solution in order to remove the alcohol. Dry over 15 g. of anhydrous calcium chloride it is best to shake in a separatory funnel with 1-2 g. of the anhydrous calcium chloride, remove the saturated solution of calcium chloride as formed, and then allow to stand over 10 g. of calcium chloride in a dry flask. Filter and distil. Collect the methyl n-butyl ketone at 126-128°. The yield is 71 g. [Pg.482]

The condensation of aldehydes and ketones with succinic esters in the presence of sodium ethoxide is known as the Stobbe condensation. The reaction with sodium ethoxide is comparatively slow and a httlo reduction of the ketonic compound to the carbinol usually occurs a shorter reaction time and a better yield is generally obtained with the more powerful condensing agent potassium ieri.-butoxide or with sodium hydride. Thus benzophenone condenses with diethyl succinate in the presence of potassium [Pg.919]

When an alkyl aryl ketone is heated with yellow ammonium polysulphide solution at an elevated temperature, an aryl substituted aliphatic acid amide is foimed the product actually isolated is the amide of the ci-aryl carboxylic acid together with a smaller amount of the corresponding ammonium salt of the oarboxylio acid. Thus acetophenone affords phenylacetamide (50 per cent.) and ammonium phenylacetate (13 per cent.) ... [Pg.923]

Some di-p-tolyl ketone is produced as a by-product, presumably by Interaction of the lithium salt of the carboxylic acid with the aryl lithium ... [Pg.930]


See other pages where Ketones salts is mentioned: [Pg.397]    [Pg.784]    [Pg.902]    [Pg.1548]    [Pg.145]    [Pg.397]    [Pg.784]    [Pg.902]    [Pg.1548]    [Pg.145]    [Pg.19]    [Pg.141]    [Pg.163]    [Pg.208]    [Pg.226]    [Pg.231]    [Pg.231]    [Pg.315]    [Pg.259]    [Pg.142]    [Pg.172]    [Pg.339]    [Pg.341]    [Pg.731]    [Pg.735]    [Pg.865]    [Pg.877]    [Pg.911]   
See also in sourсe #XX -- [ Pg.23 ]




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