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It effects

It is a powerful antagonist of histamine, antagonizing its effect on smooth muscle of the bronchioles, bladder and partially the intestines and preventing the dilation of capillaries. Promethazine is used in the treatment of allergic reactions. [Pg.328]

C7H9N402- M.p. 337 C, an alkaloid obtained from cacao seeds or prepared synthetically. Constitutionally it is similar to caffeine, and is also a weak base. It is usually administered as the sodium compound combined with either sodium ethanoate or sodium salicylate, and is employed almost entirely as a diuretic. Physiologically theobromine resembles caffeine, but its effect on the central nervous system is less, while its action on the kidneys, is more pronounced. [Pg.392]

If sulfur is a contaminant, its content can be measured, but it may suffice to characterize its effects by the copper strip corrosion test, or by the doctor test". [Pg.274]

The user inspectorate must fulfil the same technical criteria as the notified body. In addition, it must be organisationally identifiable and demonstrate its impartiality. It must not engage in any activities that might conflict with its independence of judgement and integrity. Given that the authorisation of user inspectorates to carry out conformity assessment is an innovation for technical harmonisation at Union level, the Commission shall monitor the application of this measure and evaluate its effects three years after the coming into force of the directive. [Pg.943]

The surface forces apparatus (Section VI-3C) has revealed many features of surfactant adsorption and its effect on the forces between adsorbent surfaces [180,181]. A recent review of this work has been assembled by Parker [182]. [Pg.416]

We define the effect of a synnnetry operation on a wavefiinction in two different ways depending on whether the synnnetry operation concerned uses a moving or fixed reference frame (see [4]). Either we define its effect iismg the equation... [Pg.154]

The Hamiltonian considered above, which connmites with E, involves the electromagnetic forces between the nuclei and electrons. However, there is another force between particles, the weak interaction force, that is not invariant to inversion. The weak charged current mteraction force is responsible for the beta decay of nuclei, and the related weak neutral current interaction force has an effect in atomic and molecular systems. If we include this force between the nuclei and electrons in the molecular Hamiltonian (as we should because of electroweak unification) then the Hamiltonian will not conuuiite with , and states of opposite parity will be mixed. However, the effect of the weak neutral current interaction force is mcredibly small (and it is a very short range force), although its effect has been detected in extremely precise experiments on atoms (see, for... [Pg.170]

Once the partition function is evaluated, the contributions of the internal motion to thennodynamics can be evaluated. depends only on T, and has no effect on the pressure. Its effect on the heat capacity can be... [Pg.407]

Kajimoto O 1999 Soivation in supercriticai fluids its effects on energy transfer and chemicai reactions Chem. Rev. 99 355-89... [Pg.863]

Fig. 6.20 A switching function that applies over a narrow range near the cutoff and its effect on the Lennard-Janes potential. Fig. 6.20 A switching function that applies over a narrow range near the cutoff and its effect on the Lennard-Janes potential.
Alternatively, authors have repeatedly invoked the internal pressure of water as an explanation of the rate enhancements of Diels-Alder reactions in this solvent ". They were probably inspired by the well known large effects of the external pressure " on rates of cycloadditions. However, the internal pressure of water is very low and offers no valid explanation for its effect on the Diels-Alder reaction. The internal pressure is defined as the energy required to bring about an infinitesimal change in the volume of the solvents at constant temperature pi = (r)E / Due to the open and... [Pg.20]

Nitration in aqueous solutions of nitric acid Added water retards nitration in concentrated nitric acid without disturbing the kinetic order of the reaction. The rate of nitration of nitrobenzene was depressed sixfold by the addition of 5 % of water, (c. 3 2 mol 1 ), but because of the complexity of the equilibria involving water, which exist in these media, no simple relationship could be found between the concentration of water and its effect on the rate. [Pg.9]

The most crucial observation concerning the effects of added species is that nitrate ion anticatalyses nitration without changing the kinetic form of the reaction. This shows that nitrate does not exert its effect by consuming a proportion of the nitronium ion, for, as outlined above, this would tend to bring about a kinetically first-order reaction. Nitrate ions must be affecting the concentration of a precursor of the nitronium... [Pg.42]

In contrast to its effect upon the general mechanism of nitration by the nitronium ion, nitrous acid catalyses the nitration of phenol, aniline, and related compounds. Some of these compounds are oxidised under the conditions of reaction and the consequent formation of more nitrous acids leads to autocatalysis. [Pg.57]

The regioselectivity of substitution like the rate is strongly affected by the sub stituent In the following several sections we will examine the relationship between the structure of the substituent and its effect on rate and regioselectivity of electrophilic aro matic substitution... [Pg.489]

Evaluating Indeterminate Error Although it is impossible to eliminate indeterminate error, its effect can be minimized if the sources and relative magnitudes of the indeterminate error are known. Indeterminate errors may be estimated by an appropriate measure of spread. Typically, a standard deviation is used, although in some cases estimated values are used. The contribution from analytical instruments and equipment are easily measured or estimated. Indeterminate errors introduced by the analyst, such as inconsistencies in the treatment of individual samples, are more difficult to estimate. [Pg.63]

Brown and Lin reported a quantitative method for methanol based on its effect on the visible spectrum of methylene blue. In the absence of methanol, the visible spectrum for methylene blue shows two prominent absorption bands centered at approximately 610 nm and 660 nm, corresponding to the monomer and dimer, respectively. In the presence of methanol, the intensity of the dimer s absorption band decreases, and that of the monomer increases. For concentrations of methanol between 0 and 30% v/v, the ratio of the absorbance at 663 nm, Asss, to that at 610 nm, Asio, is a linear function of the amount of methanol. Using the following standardization data, determine the %v/v methanol in a sample for which Agio is 0.75 and Ag63 is 1.07. [Pg.452]

When ligand is present we must account for its effect on the concentration of O. Solving equation 11.42 for [O] c=o and substituting into the Nernst equation gives... [Pg.529]

I which, for an average recovery of 98.1% gives a relative standard deviation of approximately 0.7%. If the acid s concentration is controlled such that its effect approaches that for factors B, C, and F, then the relative standard deviation becomes 0.18, or approximately 0.2%. [Pg.687]

The initiators which are used in addition polymerizations are sometimes called catalysts, although strictly speaking this is a misnomer. A true catalyst is recoverable at the end of the reaction, chemically unchanged. Tliis is not true of the initiator molecules in addition polymerizations. Monomer and polymer are the initial and final states of the polymerization process, and these govern the thermodynamics of the reaction the nature and concentration of the intermediates in the process, on the other hand, determine the rate. This makes initiator and catalyst synonyms for the same material The former term stresses the effect of the reagent on the intermediate, and the latter its effect on the rate. The term catalyst is particularly common in the language of ionic polymerizations, but this terminology should not obscure the importance of the initiation step in the overall polymerization mechanism. [Pg.349]

P. Benhaine and co-workers, "Investigation on Gun Propellant Breakup and its Effect on Interior BaUistics," in Proceedings of 4th International Symposium on Ballistics, Oct. 1989. [Pg.26]

Although molecular diffusion itself is very slow, its effect is nearly always enhanced by turbulent eddies and convection currents. These provide almost perfect mixing in the bulk of each Hquid phase, but the effect is damped out in the vicinity of the interface. Thus the concentration profiles at each... [Pg.62]


See other pages where It effects is mentioned: [Pg.63]    [Pg.97]    [Pg.550]    [Pg.121]    [Pg.487]    [Pg.622]    [Pg.33]    [Pg.155]    [Pg.171]    [Pg.2308]    [Pg.215]    [Pg.73]    [Pg.346]    [Pg.721]    [Pg.9]    [Pg.500]    [Pg.537]    [Pg.1074]    [Pg.1083]    [Pg.389]    [Pg.668]    [Pg.686]    [Pg.49]    [Pg.98]    [Pg.284]    [Pg.292]    [Pg.324]    [Pg.120]   
See also in sourсe #XX -- [ Pg.180 ]




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Renner-Teller effect IT electronic states

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The effect of surface cracking and its repair

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