Ionic Liquid Based Polymer Electrolytes

Tiruye, G. A., D. Munoz-Torrero, J. Pahna, M. Anderson, and R. Marcilla. 2015. Allsolid state supercapacitors operating at 3.5 V by using ionic liquid based polymer electrolytes. Journal of Power Sources 279 472—480. [Pg.248]

Kim J-K, Marie A, Ahn J-H et al (2012) Preparation and application of TEMPO-based di-radical organic electrode with ionic liquid-based polymer electrolyte. RSC Adv 2 (27) 10394-10399... [Pg.667]

Lin B, Qiu L, Lu 1, Yan F (2010) Cross-linked alkahne ionic liquid-based polymer electrolytes for alkatine fuel ceU applications. Chem Mater 22(24) 6718-6725. doi 10.1021/ cml02957g... [Pg.312]

Tamilarasan, R, and S. Ramaprabhu. 2014. Stretchable supercapacitors based on highly stretchable ionic liquid incorporated polymer electrolyte. Materials Chemistry and Physics 148 48-56. [Pg.249]

Pandey GP, Hashmi SA, Kumar Y (2010) Performance studies of activated charcoal based electrical double layer capacitors with ionic liquid gel polymer electrolytes. Energy Fuels 24(12) 6644-6652. doi 10.1021/efl010447... [Pg.314]

The second approach involving the use of ionic liquids in polymer electrolyte-based DSSC consists of the use of ionic polymers. " The ionic liquid-type polymer may have the desirable properties (similar to that of pure ionic liquids) and be employed in the fabrication of DSSC with high efficiency, without the problems of evaporation or leakage of the electrolyte during long-term operation. [Pg.416]

Sellam, and S. A. Hashmi. 2013. High rate performance of flexible pseudocapacitors fabricated using ionic-liquid-based proton conducting polymer electrolyte with poly(3, 4-ethylenedioxythiophene) poly(styrene sulfonate) and its hydrous ruthenium oxide composite electrodes. ACS Applied Materials Interfaces 5 3875-3883. [Pg.248]

Liew, C. W., S. Ramesh, and A. K. Arof. 2014. Good prospect of ionic liquid based-polyfvinyl alcohol) polymer electrolytes for supercapacitors with excellent electrical, electrochemical and thermal properties. International Journal of Hydrogen Energy 39 2953-2963. [Pg.249]

Pandey, G. P., and S. A. Hashmi. 2013. Solid-state supercapacitors with ionic liquid based gel polymer electrolyte Effect of lithium salt addition. Journal of Power Sources 243 211-218. [Pg.249]

Egashira, M. Todo, H. Yoshimoto, N. Morita, M., Lithium ion conduction in ionic liquid-based gel polymer electrolyte, J. Power Sources 2008,178,729-735. [Pg.162]

An assessment of the relative diffusion rates of ionic and molecular species in the PAN-based electrolyte may be made from the diffusion coefficients calculated for ferrocene from cyclic voltammograms. Some data are presented in Table 3.8. The ratio of diffusion coefficients of ferrocene in the PAN-based polymer electrolyte and PC/LiC104 liquid electrolyte at room temperature is the same as that obtained for the conductivity of LiC104 in these electrolytic media. It may be noted here that the ferro-cene/ferrocenium couple has been shown [36] to be useful for the overcharge protection of secondary Li batteries. [Pg.100]

Shin J-H, Henderson WA, Passerini S (2005) PEO-based polymer electrolytes with ionic liquids and their use in lithium metal-polymer electrolyte batteries. J Electrochem Soc 152(5) A978-A983. doi 10.1149/l.1890701... [Pg.215]

Fujiwara N, Asaka K, Nishimura Y et al (2000) Preparation of gold — solid polymer electrolyte composites as electric stimuli-responsive materials. Chem Mater 12(6) 1750-1754 Fukushima T, Asaka K, Kosaka A et al (2005) Fully plastic actuator through layer-by-layer casting with ionic-liquid-based bucky gel. Angew Chem hit Ed 44 2410-2413 Gao R, Wang D, Heflin JR et al (2012) Imidazolium sulfonate-containing pentablock copolymer-ionic liquid membranes for electroactive actuators. J Mater Chem 22 13473-13476 Gogotsi Y, Nikitin A, Ye H et al (2003) Nanoporous carbide-derived carbon with tunable pore size. Nat Mater 2(9) 591-594... [Pg.168]

Appetecchi, G. B. Kim, G.-T. Montanino, M. Alessandrini, F. Passerini, S. (2008). Solvent-free, PYR14TFSI ionic liquids-based ternary polymer electrolyte systems. II. Battery tests. ECS Transactions, 11, 29, (2008, Rechargeable Lithium and Lithium Ion Batteries), 119-129... [Pg.71]

A gel electrolyte is a polymer gel that confines a liquid electrolyte. Gel electrolytes have better ionic conductivity than polymer electrolytes. Wang et al. have studied poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) gel electrolyte with plasticizers such as EC-DMC, and PC-EC-DEC for Li-S batteries at room temperature. The ionic conductivity is improved significantly to about 1.2 X 10 Scm, which is much higher than that of PEO-based polymer electrolyte. High discharge capacity and utilization of sulfur are obtained with PAN-S [70, 71] and C-S [46, 69] composite electrodes. However, much lower utilization of sulfur is obtained when PVDF [134] or PVDF-HFP [119] are combined with TEGDME as a plasticizer. When TEGDME combines with EC as the plasticizer for microporous PVDE-HEP gel electrolytes, a better performance is observed in Hthium-sulfur batteries [31]. [Pg.833]

The transfer of Li+ ions happens mainly in the amorphous region of the PEO-based polymer electrolyte, and PEO is easily crystallized. The solubility of lithium salt in the amorphous phase is low and the number of carriers is small. Compared to liquid electrolyte at or below room temperature, its ionic conductivity is usually in the order of 10 S/cm. This limits the application of PEO-based polymer electrolytes. [Pg.366]

Kim, J.K., Ahn, J.H., Jacobsson, P. 2014. Influence of temperature on ionic liquid-based gel polymer electrolyte prepared by electrospun fibrous membrane. Electrochim. Acta 116 321-325. [Pg.441]

Pandey GP, Kumar Y, Hashmi SA (2011) Ionic liquid incorporated PEO based polymer electrolyte for electrical double layer capacitors a comparative study with lithium and magnesium systems. Solid State Ion 190(l) 93-98... [Pg.276]

Pandey GP, Hashmi SA (2009) Experimental investigations of an ionic-liquid-based, magnesium ion conducting, polymer gel electrolyte. JPower Sources 187(2) 627-634. doi 10.1016/j. jpowsour.2008.10.112... [Pg.309]

Liao Y, Sun C, Hu S, Li W (2013) Anti-thennal shrinkage nanopeuticles/polymer and ionic liquid based gel polymer electrolyte for hthium ion battery. Electrochim Acta 89 461 68. doi 10.1016/j.electacta.2012.11.095... [Pg.311]

Liew C-W, Ramesh S, Arof AK (2014) A novel approach on ionic liquid-based poly(vinyl alcohol) proton conductive polymer electrolytes for fuel cell appUcations. Int J Hydrog Energy 39(6) 2917-2928. doi 10.1016/j.ijhydene.2013.07.092... [Pg.312]

Singh PK, Rim K-W, Park N-G, Rhee H-W (2008) Mesoporous nanocrystalline TiOj electrode with ionic liquid-based solid polymer electrolyte for dye-sensitized solar cell application. Synth Met 158(14) 590-593. doi 10.1016/j.synthmet.2008.04.003... [Pg.313]

Sellam HSA (2013) High rate performance of flexible pseudocapacitors fabricated using ionic-liquid-based proton conducting polymer electrolyte with poly(3,... [Pg.314]

The ionic conductivity of polymer electrolytes is typically 100 to 1000 times less than exhibited by a liquid- or ceramic-based electrolyte. Although higher conductivities are preferable, and indeed a great deal of effort has gone into improving the bulk conductivity of polymer electrolytes over the years, 100-fold or 1000-fold increases are not essential, as a thin film electrochemical cell configuration can largely compensate for the lower values. [Pg.4]

Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...