Internal mixing-compression

Figure 6.40 Tensile stress-strain curves of composite materials prepared using an internal mixing-compression molding method, (a) Pure polypropylene, (b) 10% whisker content. 

In another time and place, a lube oil tank experienced a dramatic failure of the wall-to-floor seam of an oil tank. A vertical lubricating oil storage tank, 19 ft. (6.1 m) in diameter and 24 ft. (7.4 m) high, failed catastrophically when it was accidentally overpressured with compressed air injected into the tank. A stream of compressed air injected below the liquid level provided internal mixing within the tank. There were no injuries and no lire [4]. 

Two-fluid nozzles, also known as pneumatic nozzles, use a compressed gas to atomize the liquid feed. There are different designs of nozzles on the market. The two major groups of two-fluid nozzles are known as an external mixing nozzle and an internal mixing nozzle. 

Urethanes are processed as mbber-like elastomers, cast systems, or thermoplastic elastomers. The elastomer form is mixed and processed on conventional mbber mills and internal mixers, and can be compression, transfer, or injection molded. The Hquid prepolymers are cast using automatic metered casting machines, and the thermoplastic peUets are processed like aU thermoplastic materials on traditional plastic equipment. The unique property of the urethanes is ultrahigh abrasion resistance in moderately high Shore A (75—95) durometers. In addition, tear, tensUe, and resistance to many oUs is very high. The main deficiencies of the urethanes are their resistance to heat over 100°C and that shear and sliding abrasion tend to make the polymers soft and gummy. 

The success of the compaction operation depends pardy on the effective utilization and transmission of appHed forces and pardy on the physical properties and condition of the mixture being compressed. Friction at the die surface opposes the transmission of the appHed pressure in this region, results in unequal distribution of forces within the compact, and hence leads to density and strength maldistribution within the agglomerate (70). Lubricants, both external ones appHed to the mold surfaces and internal ones mixed with the powder, are often used to reduce undesirable friction effects (71). For strong compacts, external lubricants are preferable as they do not interfere with the optimum cohesion of clean particulate surfaces. Binder materials maybe used to improve strength and also to act as lubricants. 

Sidestream compressors are used in refrigeration processes where, for economy, the refrigerant is flashed off at different pressure levels. Ideally, separate compressors could be used to successively compress the gas back up to the condensing pressure level. The pressure ratio for each stage is low enough to enable this to be done with only one or two impellers in each section. Because of this, compressors can be made with all sections in one casing so that mixing of the streams takes place intern.ll I v. 

Haimovitch, Y., E. Gartenberg, A. S. Roberts, Jr., and G. B. Northam. 1997. Effects of internal nozzle geometry on compression-ramp mixing in supersonic flow. AIAA J. 35(4) 663-70. 

Processing variables can affect to a very great extent the results obtained on the rubber product or test piece and, in fact, a great number of physical tests are carried out in order to detect the result of these variables, for example state of cure and dispersion. In a great many cases, tests are made on the factory prepared mix or the final product as it is received but, where the experiment involves the laboratory preparation of compounds and their moulding, it is sensible to have standard procedures to help reduce as far a possible sources of variability. Such procedures are provided by ISO 2393 which covers both mills and internal mixers of the Banbury or Intermix type, and also procedures for compression moulding. 

Catalyst-poisoning studies have concentrated on the potential poisons introduced with fuel, particularly on lead, which has been added intentionally to improve the combustion characteristics at the high compression ratios employed in modem internal combustion engines prior to the introduction of exhaust purification catalysts. The lead is usually introduced as motor mix which contains tetraethyllead in a mixture with organic halides, chlorides or bromides. These halides transport the lead in the form of volatile halides out of the engine and into the exhaust, and are hence termed lead scavengers. Thus the potential catalyst-poison elements associated with the additive mixture are Pb, Br, and Cl. 

Another way to classify fermenters is based on how the fermenter contents are mixed by compressed air,by a mechanical internal moving part, or by external liquid pumping. Representative fermenters in each category are listed in Table 6.2 and the advantages and disadvantages of three basic fermenter types are listed in Table 6.3. 

The sample to be analyzed, say C60 fullerene, is mixed with an appropriate amount of KBr in an agate mortar and then transferred into a press and compressed at 4,000 Kg into a pellet with a diameter of 1.2 cm and a thickness of 0.2 cm. The pellet was mounted into the sample holder of the Specac variable temperature cell and inserted into the cell. The cell was then evacuated with the aid of a pump to a vacuum of 0.1 torr and then heated gradually at 120°C in order to permit the humidity absorbed on the internal surfaces of the cell and in the KBr pellet to evaporate. The sample was then cooled to the desired temperature to record the infrared spectrum. In order to go below room temperature, use was made of liquid nitrogen, added cautiously and in small amount in the cavity present inside the cell. Such cavity is connected with the sample holder and permits to cool the sample to the desired temperature. The temperature of the sample was monitored with adequate thermocouples. The lowest temperature reached with this apparatus was -180°C (93K) while the highest temperature was +250°C. Heating is provided by the Joule effect and an external thermal control unit. 

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