Inorganic compounds solubility product constant

The appendices contain the thermodynamic data, the solubility product constants that are relevant to CBPC formation or their durability, and formulae of minerals that were discussed in the text. The thermodynamic data of phosphates is difhcult to find in the common literature. Some excellent sources such as Phosphate Minerals by Nriagu and Moore and Inorganic Phosphate Materials by Kanazawa are out of print. The most commonly used data books such as CRC Handbook of Physics and Chemistry do not contain data on most phosphate compounds. For this reason, these appendices are provided to facilitate the discussion in the text and also for the benefit of those who wish to pursue further research in CBPCs. 

The solubility of sparingly soluble compounds that do not appear in this table may be calculated from the data in the table Solubility Product Constants . Solubility of inorganic gases may be found in the table Solubility of Selected Gases in Water Compounds are listed alphabetically by chemical formula in the most commonly used form (e.g., NaCl, NH NO, etc.). 

SOLUBILITY PRODUCT CONSTANTS OF SOME INORGANIC COMPOUNDS AT 25°C... 

Solubility Product Constants for Some Inorganic Compounds at 25°C... 

APPENDIX H SOLUBILITY PRODUCT CONSTANTS FOR SOME INORGANIC COMPOUNDS AT 25 C... 

Solubility of Carbon Dioxide in Water at Various Temperatures and Pressures Aqueous Solubility and Henry s Law Constants of Organic Compounds Aqueous Solubility of Inorganic Compounds at Various Temperatures Solubility Product Constants... 

Appendix 1 presents numerous reference tables containing most important data on the solubility of inorganic compounds in water, the density, dissociation constants, solubility products, ionization potentials of various atoms, etc., as well as thermochemical constants because many laws of inorganic chemistry cannot be explained without these quantities. 

Many density-dependent properties of H2O, such as viscosity, polarity (dielectric constant s changes from 74 to 2), heat capacity at constant pressure (which is infinite at the critical point), ion product and solvent power can be tuned for specific requirements by setting the correct temperature and pressure, and they show significant changes near the critical point (Figure 25.2). Several studies have demonstrated that the transition from sub- to supercritical conditions also affects the elementary steps in reaction mechanisms, and radical intermediates are favoured over ionic species. Another consequence is that subcritical water shows potential for acid catalysis. Reactions can be run either under non-polar/aprotic or polar/pH controlled conditions (water can take part in these reactions). Consequently, non-polar compounds like aromatics become soluble whereas inorganic salts precipitate. Therefore, the properties of water as a solvent are tunable over much wider parameter ranges than for most other compounds. 

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