Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Infrared continued reflection

Various optical detection methods have been used to measure pH in vivo. Fluorescence ratio imaging microscopy using an inverted microscope was used to determine intracellular pH in tumor cells [5], NMR spectroscopy was used to continuously monitor temperature-induced pH changes in fish to study the role of intracellular pH in the maintenance of protein function [27], Additionally, NMR spectroscopy was used to map in-vivo extracellular pH in rat brain gliomas [3], Electron spin resonance (ESR), which is operated at a lower resonance, has been adapted for in-vivo pH measurements because it provides a sufficient RF penetration for deep body organs [28], The non-destructive determination of tissue pH using near-infrared diffuse reflectance spectroscopy (NIRS) has been employed for pH measurements in the muscle during... [Pg.286]

A prerequisite for the development indicated above to occur, is a parallel development in instrumentation to facilitate both physical and chemical characterization. TEM and SPM based methods will continue to play a central role in this development, since they possess the required nanometer (and subnanometer) spatial resolution. Optical spectroscopy using reflection adsorption infrared spectroscopy (RAIRS), polarization modulation infrared adsorption reflection spectroscopy (PM-IRRAS), second harmonic generation (SFIG), sum frequency generation (SFG), various in situ X-ray absorption (XAFS) and X-ray diffraction spectroscopies (XRD), and maybe also surface enhanced Raman scattering (SERS), etc., will play an important role when characterizing adsorbates on catalyst surfaces under reaction conditions. Few other methods fulfill the requirements of being able to operate over a wide pressure gap (to several atmospheres) and to be nondestructive. [Pg.335]

Internal reflection spectroscopy of solids Mid-infrared internal reflection accessories were developed initially largely for studying the surface layer characteristics of a continuous flat solid sample, e.g., a polymer film although they may also be used as convenient methods of sample identification, when a surface layer spectrum may be taken as indicative of a sample s bulk characteristics. The sample surface is brought and held under low pressure into optical contact with the clean surface of an internal reflection element. Other common traditional uses have included the direct examination of fibers, foams, and malleable (soft) powders. It has, however, become common practice nowadays, with the sensitivity now available with FT-IR spectroscopy, to use single (or low-number) internal reflection accessories to conveniently and easily record a mid-infrared fingerprint... [Pg.2241]

When a beam of monochromatic radiation is passed through the windows of an infrared cell some reflection occurs on the window surfaces and interference takes place between radiation passing from the internal surface of the first window and that reflected back from the internal surface of the second window. This interference is at a maximum when 2d = (n + 1 /2)k, where d is the distance in yum between the inner surfaces of the two cell windows, X is the wavelength in m, and n is any integral number. If the wavelength k of the monochromatic radiation is varied continuously an interference pattern consisting of a series of waves (Fig. 19.7) is obtained. [Pg.750]

A fiber-optic device has been described that can monitor chlorinated hydrocarbons in water (Gobel et al. 1994). The sensor is based on the diffusion of chlorinated hydrocarbons into a polymeric layer surrounding a silver halide optical fiber through which is passed broad-band mid-infrared radiation. The chlorinated compounds concentrated in the polymer absorb some of the radiation that escapes the liber (evanescent wave) this technique is a variant of attenuated total reflection (ATR) spectroscopy. A LOD for chloroform was stated to be 5 mg/L (5 ppm). This sensor does not have a high degree of selectivity for chloroform over other chlorinated aliphatic hydrocarbons, but appears to be useful for continuous monitoring purposes. [Pg.233]

The details in the CO response continue to be the subject of many discussions and a full explanation will need further studies. These can include spectroscopy studies such as diffuse reflectance transform infrared spectroscopy (DRIFT), which can be performed under realistic conditions [43,44], and theoretical modeling [45]. However it seems likely that not only hydrogen gives rise to charged or polarized complexes on the insulator surface. Equation (2.3) may now be written as... [Pg.34]

Solvent-elimination approaches include evaporative spray deposition onto infrared-transparent surfaces (141) or reflective surfaces and powders (142, 143). Other approaches include partial evaporation of the mobile phase before spray deposition (144, 145), and continuous liquid-liquid extraction systems that transfer solutes from LC mobile phases to solvents possessing an infrared window (146). Spray systems include both pneumatic and ultrasonic nozzles (147). [Pg.739]

Eventually, rapid methods based on techniques such as near-infrared reflectance spectroscopy (NIRS) are expected to replace chemical methods for routine feed analysis, but bioavailability is expected to continue to be measured in animal studies. [Pg.50]

There are several major areas of interfacial phenomena to which infrared spectroscopy has been applied that are not treated extensively in this volume. Most of these areas have established bodies of literature of their own. In many of these areas, the replacement of dispersive spectrometers by FT instruments has resulted in continued improvement in sensitivity, and in the interpretation of phenomena at the molecular level. Among these areas are the characterization of polymer surfaces with ATR (127-129) and diffuse reflectance (130) sampling techniques transmission IR studies of the surfaces of powdered samples with adsorbed gases (131-136) alumina(137.138). silica (139). and catalyst (140) surfaces diffuse reflectance studies of organo- modified mineral and glass fiber surfaces (141-143) metal overlayer enhanced ATR (144) and spectroelectrochemistry (145-149). [Pg.18]

The most commonly used technique for obtaining a spectrum is the attenuated total reflectance (ATR) method in the multiple internal reflectance (MIR) mode. In this method, the infrared beam is passed into a special crystal of a selenide (KRS-5). The angle of incidence is such that the beam will bounce along the crystal. A sample of the polyurethane is placed hard up against the crystal. The infrared just penetrates into the material before it continues down the crystal. A number of internal bounces are obtained along the crystal. Up to 25 reflectances are obtained from a 2 mm crystal. Figure 9.8 illustrates the infrared path in an ATR cell. [Pg.190]

These are GC-IR (5), LC-IR (6), and diffuse reflectance (7). On-the-fly GC-IR systems are commercially available, and lower detection limits are being continually reported. While GC-IR may not replace GC/MS in residue and metabolism work, it can provide valuable data in these areas. On-the-fly LC-IR systems have been developed and are also commercially available. The major problem in these systems is the strong infrared absorbence of many common LC solvents. However, with proper selection of solvents and the development of LC conditions specifically designed for the LC-IR experiment, these problems may be overcome. Recent reports on diffuse reflectance measurements by FTIR indicate the technique may provide a method of examining formulated material or TLC spots with no sample preparation. While this technique is still in the development stage, it may become quite significant in the future. [Pg.320]

AIN buffer layer on (0001) sapphire. Composition was determined by help of X-ray diffraction. A continuous increase of the mode energy with x was observed. An AlxGai.xN/GaN/sapphire heterostructure grown with the AIN buffer layer technique was studied in infrared reflection and Raman spectroscopy by Wetzel et al [2] (FIGURE 2). From an X-ray analysis of the c-axis an AlN-ftaction of x = 0.15 was derived. Recently, however, it was shown that AIN layers in heterostructures with GaN are coherently strained up to a thickness of at least 350 nm. This leads to misinterpretation of the AIN fraction [8], Including the deformation of the unit cell in the pseudomorphic structure above, a value 50% smaller is concluded (x = 0.08). In backscattering off the c-plane the Ai(LO) mode was determined at 752 cm 1 (square with cross symbol) in excellent agreement with the infrared reflection data [2],... [Pg.144]


See other pages where Infrared continued reflection is mentioned: [Pg.186]    [Pg.149]    [Pg.111]    [Pg.288]    [Pg.201]    [Pg.532]    [Pg.387]    [Pg.95]    [Pg.504]    [Pg.1008]    [Pg.1011]    [Pg.511]    [Pg.308]    [Pg.253]    [Pg.87]    [Pg.648]    [Pg.532]    [Pg.384]    [Pg.74]    [Pg.201]    [Pg.203]    [Pg.37]    [Pg.48]    [Pg.26]    [Pg.457]    [Pg.94]    [Pg.423]    [Pg.445]    [Pg.316]    [Pg.100]    [Pg.254]    [Pg.33]    [Pg.84]    [Pg.278]    [Pg.545]    [Pg.16]    [Pg.814]   
See also in sourсe #XX -- [ Pg.192 ]




SEARCH



Infrared (continued

Infrared reflective

© 2024 chempedia.info