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Indirect values

The largest contribution to the uncertainty of the indirect mass ratio in (12.34) is supplied by the unknown theoretical contributions to hyperfine splitting. This sets a clear task for the theory to reduce the contribution of the theoretical uncertainty in the error bars in (12.34) to the level below two other contributions to the error bars. It is sufficient to this end to calculate all contributions to HFS which are larger than 10 Hz. This would lead to further reduction of the uncertainty of the indirect value of the muon-electron mass ratio. There is thus a real incentive for improvement of the theory of HFS to account for all corrections to HFS of order 10 Hz, created by the recent experimental and theoretical achievements. [Pg.254]

For rapid analysis during the production process atomic absorption is mainly of indirect value because, due to the sequential character of the technique, it cannot be used for complete steel or slag analysis in a two to three minute period. The analytical requirements for the testing of rapid continuous production processes are fulfilled by the techniques of emission and X-ray spectrometry. These techniques are characterised by great speed, high precision and simultaneous multi-element analysis. Accuracy must, however, be constantly checked with a variety of special calibration samples. This requires the determination of the true concentrations of the calibration samples with chemical methods of solution analysis, whose precision is often only equal to or, when compared with X-ray spectrometry, frequently poorer. Chemical analysis is, however, the basis of all comparisons, and must be repeated frequently for the determination of the true concentrations. Atomic absorption, with its relatively good precision, has greatly simplified the analytical control of numerous elements. [Pg.212]

The adopted spectroscopic IP(HD) receives strong support from a value calculated indirectly from experimental values (1.) of Dq (HD) and IP(H) combined with the theoretical value (5) of Dq (HD ) this indirect value differs by only 0.3 cm. Furthermore, IP(HD) can be predicted (6) approximately from that of Hg (or Dg) using differences in zero-point energies (1 ) of the diatomic molecules and their ions. Predicted values of IP(HD) deviate from the observed value by -16 cm" (based on... [Pg.996]

Additional data may be found in the paper by Soundy and Williams, who obtained indirect values for the rate of the charge transfer reaction during their study of the atomic ion-electron recombination process. Their analysis does not allow for compound formation, of particular... [Pg.218]

Here v,/27t is the resonance frequency in a held of 1 T along the x-axis, including the true nuclear term. An NMR measurement of this frequency can therefore be used to derive an indirect value for the Van Vieck paramagnetic moment, since... [Pg.379]

Acid precipitation and ozone levels, if uncontrolled, will almost certainly cause as yet unknown ecological damage in the future. The scale and timing of this damage is quite impossible to predict at present. It is quite possible that the cost in present value terms of the measurable future damage would be small relative to control costs. However, it is evident that society does place an indirect value on its terrestrial and aquatic ecosystems and decision-makers and politicians will need to address the question of how large is this indirect value in making decisions about S02/N05 controls. [Pg.142]

The reported rate constants of these reactions, however, used to have large uncertainties since they were indirect values assuming the above reaction mechanism for CH2OO. Recently, Welz et al. (2012) and Stone et al. (2014) reported the following values based on the direct measurement of CH2OO as SO2 3.9 x 10 ", 3.4x... [Pg.210]

The stated challenges require an analytical connection of the operational changes caused by the implementation of the SCI and an adequate business metric, such as the economic value added (EVA). In general, SCIs have a financial affect by influencing costs, revenues and capital commitment (Christopher Ryals, 1999 3f D Avanzo et al, 2003 43 Lambert Burduroglu, 2000 13 Pohlen Coleman, 2005 45f). In this context, the distinction between direct and indirect value drivers is important... [Pg.3]

Ellram Liu (2002), Hofinann Locker (2009) and Pohlen Coleman (2005) discuss this link in the context of supply chain performance management on a conc tual basis. They distinguish between direct and indirect value drivers, where their central value driver for revenues is logistics customer service. This is additionally confirmed by enqpirical quantitative studies, for instance, those of Ozmcnt Chard (1986), Tracey (1998) and Yeung (2008). [Pg.25]

Here, r is positive and there is thus an increased vapor pressure. In the case of water, P/ is about 1.001 if r is 10" cm, 1.011 if r is 10" cm, and 1.114 if r is 10 cm or 100 A. The effect has been verified experimentally for several liquids [20], down to radii of the order of 0.1 m, and indirect measurements have verified the Kelvin equation for R values down to about 30 A [19]. The phenomenon provides a ready explanation for the ability of vapors to supersaturate. The formation of a new liquid phase begins with small clusters that may grow or aggregate into droplets. In the absence of dust or other foreign surfaces, there will be an activation energy for the formation of these small clusters corresponding to the increased free energy due to the curvature of the surface (see Section IX-2). [Pg.54]

The enthalpy, entropy and free energy changes for an isothennal reaction near 0 K caimot be measured directly because of the impossibility of carrying out the reaction reversibly in a reasonable time. One can, however, by a suitable combination of measured values, calculate them indirectly. In particular, if the value of... [Pg.369]

As a final point, it should again be emphasized that many of the quantities that are measured experimentally, such as relaxation rates, coherences and time-dependent spectral features, are complementary to the thennal rate constant. Their infomiation content in temis of the underlying microscopic interactions may only be indirectly related to the value of the rate constant. A better theoretical link is clearly needed between experimentally measured properties and the connnon set of microscopic interactions, if any, that also affect the more traditional solution phase chemical kinetics. [Pg.891]

In the fir.st iteration proces.s, the class values of the atoms of the structure. show information already known (the degree of the nodes). Hence Morgan takes the neighboring atoms into account. He considers the environment of an atom by summing class values of all directly adjacent atoms. This process results in a new class value called the extended connectivity (EC) value of the atom. The new EC value expresses indirectly the neighborhood of the adjacent atoms in a second sphere (Figure 2-43). [Pg.61]

The characteristic of a relational database model is the organization of data in different tables that have relationships with each other. A table is a two-dimensional consti uction of rows and columns. All the entries in one column have an equivalent meaning (c.g., name, molecular weight, etc. and represent a particular attribute of the objects (records) of the table (file) (Figure 5-9). The sequence of rows and columns in the tabic is irrelevant. Different tables (e.g., different objects with different attributes) in the same database can be related through at least one common attribute. Thus, it is possible to relate objects within tables indirectly by using a key. The range of values of an attribute is called the domain, which is defined by constraints. Schemas define and store the metadata of the database and the tables. [Pg.235]

Since they all necessitate a knowledge of the value of r, and of both r and either directly or indirectly, all as a function of p p°, these data are given in tabular form for reference (Table 3.2). If required, intermediate values of t may be obtained to sufficient accuracy by graphical interpolation, and the corresponding values of r can be calculated with the Kelvin formula. The values of r refer to the most commonly used model, the cylindrical pore, so that r " = r + t. The values of t are derived from the standard nitrogen isotherm for hydroxylated silica and though the values do differ... [Pg.135]

Spices and herbs can play an important indirect role in good nutrition. They are not high in nutrient values, but they help to increase the appeal and satisfaction of foods that are highly nutritious. Spices do contain fat, protein and carbohydrates, electrolytic minerals, iron and B vitamins, and others, but even the highest calorie spice, poppy seeds, contains only two to three calories per serving in normal use (12). [Pg.27]

Other methods attempt to probe the stmcture of the foam indirectly, without directly imaging it. Eor example, since the Hquid portion of the foam typically contains electrolytes, it conducts electrical current, and much work has been done on relating the electrical conductivity of a foam to its Hquid content, both experimentally (15) and theoretically (16). The value of the conductivity depends in a very complex fashion on not only the Hquid content and its distribution between films and borders, but the geometrical stmcture of the bubble packing arrangement. Thus electrical measurements offer only a rather cmde probe of the gas Hquid ratio, a quantity that can be accurately estimated from the foam s mass density. [Pg.429]

Semiconductors can be divided into two groups direct and indirect band gap materials. In direct semiconductors the minimum energy in the conduction band and the maximum in the valence band occur for the same value of the electron momentum. This is not the case in indirect materials. The difference has profound consequences for the transitions of electrons across the band gap in which light is emitted, the radiative transitions, of interest here. [Pg.127]

The double titration method, which involves the use of ben2ylchloride, 1,2-dibromoethane, or aUyl bromide, determines carbon-bound lithium indirectly (101,102). One sample of the //-butyUithium is hydroly2ed directly, and the resulting alkalinity is determined. A second sample is treated with ben2ylchloride and is then hydroly2ed and titrated with acid. The second value (free base) is subtracted from the first (total base) to give a measure of the actual carbon-bound lithium present (active base). [Pg.228]

In addition, many grades of paper and paperboard are used in direct or indirect contact with foods. Thus, many mills only use paper chemicals that have been cleared for use by the U.S. Pood and Dmg Administration (PDA) (3), so that it is not necessary to segregate machine broke (off-grade paper and edge clippings that are reclaimed for their fiber value) and white water. Most of the chemicals discussed in this article are approved by the PDA for use in paper and paperboard that are intended for appHcations in food processing and packaging. However, there are various restrictions on both the specific functional uses and amounts of paper chemical additives which can be used, so the PDA status should be confirmed by the suppHer before use. [Pg.15]


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See also in sourсe #XX -- [ Pg.36 ]




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