Homogeneous Impedance

Polyethylene ignites readily and melts and drips as it bums, leaving little or no residual char. The incorporation of flame retardants into polyethylene is made difficult by the crystallinity of the polymer, which impedes homogeneous distribution of the flame retardant and reduces its effectiveness. 

The results found for the coating controlled parts allow to consider during the testing the exploitation of the information provided by the measured variation impedance for the processed products by the coating thickness determination and low frequency homogeneity and to evaluate the high frequency coating nature. 

Vortex formation leads to a considerable drop in mixing efficiency and should be suppressed as much as possible in practical applications to increase the homogenizing effects of mixers. The preferable method of vortex suppression is to install vertical baffles at the walls of the mixing tank. These impede rotational flow without interfering with the radial or longitudinal flow. Figure 11 illustrates such a system. 

Catalysts are so important in chemical industry that combinatorial-type approaches will certainly be utilized as tools in the identification and optimization of both heterogeneous and homogeneous catalysts. These are, in many cases, high value-added, commercially important materials. In any research activity it makes sense to remove any choke points that impede progress. However, many engineering considerations are important in producing commercial catalytic processes thus, combinatorial-type approaches are unlikely to be a panacea. Still, a variety of unanticipated discoveries may result from various efforts that are under way. 

Methylation in both ortho-positions on the aniline ring appears to impede hydrolysis of the amide bond. Thus, 2,4,6-trimethylacetanilide (4.105) was not hydrolyzed by rat liver homogenates, perhaps due to steric hindrance by the 2- and 6-Me groups [71]. Similarly, the amide bond of the hypocholes-terolemic agent 2,2-dimelhyl-A-(2,4,6-trimethoxypheiiyl )dodccanamidc... 

Figure 25. Adler s ID macrohomogeneous model for the impedance response of a porous mixed conducting electrode. Oxygen reduction is viewed as a homogeneous conversion of electronic to ionic current within the porous electrode matrix, occurring primarily within a distance A from the electrode/electrolyte interface (utilization region). (Adapted with permission from ref 28. Copyright 1998 Elsevier.)...

Effect of Sample Dilution. To determine the effect of sample dilution on impedance measurements, shrimp samples were stored at >2(y C or for 21 d. Frozen samples were used to mimic fr h shrimp while refrigerated samples were used to represent spoilage over time. Duplicate SO-g samples were removed from storage every 7 d and used for impedance analysis. Each sample was removed from the bags, boiled for 5 min, cooled to room temperature, then transferred to a tared blender jar and diluted either 1 1 or 1 10 with sterile deionized, demineralized water. Samples were homogenized for 2 min on high. Controls consisted of water alone. 

The fat globules of milk reduce the conductivity by occupying volume and by impeding the mobility of ions. Thus the conductivity of whole milk is less than that of skim milk by about 10%, and that of cream varies with the fat content (Gerber 1927 Muller 1931 Prentice 1962). Homogenization of milk does not measurably influence conductivity (Prentice 1962). The conductivity of whey and ultrafiltrate is slightly greater than that of skim milk (Schulz 1956 Schulz and Sydow 1957). A possible relationship between the electrical conductivity and physical stability of evaporated milk and concentrated infant milk products has been reported (Hansson 1957). Samples of poor physical stability tended to have relatively low conductivity values compared to those of the more stable products. 

Both Knudsen and molecular diffusion can be described adequately for homogeneous media. However, a porous mass of solid usually contains pores of non-uniform cross-section which pursue a very tortuous path through the particle and which may intersect with many other pores. Thus the flux predicted by an equation for normal bulk diffusion (or for Knudsen diffusion) should be multiplied by a geometric factor which takes into account the tortuosity and the fact that the flow will be impeded by that fraction of the total pellet volume which is solid. It is therefore expedient to define an effective diffusivity De in such a way that the flux of material may be thought of as flowing through an equivalent homogeneous medium. We may then write ... 

---