Sediment hydrogenous

Sediments formed by the abiogenic precipitation of solutes from seawater are termed hydrogenous. Unequivocal examples of hydrogenous sediments are ones formed from the evaporation of seawater. The minerals deposited are collectively called evaporites and are the subject of Chapter 17. Others form with the assistance, to varying degrees, of marine microbes. For example, bacteria seem to play a role in the formation of Fe-Mn nodules and crusts. Some hydrogenous minerals, such as barite, celestite, glauconite, and francolite, are produced from the precipitation of elements... 

In the South Pacific, the CCD is deep enough to permit the preservation of calcareous oozes except in the center of the basin, which as a result is covered by abyssal clays. The relatively rapid supply of hydrogenous sediments prevents the accumulation of calcareous oozes on the East Pacific Rise. In the North Pacific, abyssal clays dominate as this is the location where the CCD is shallowest. Aeolian transport is the source of the clay minerals that make up these deposits. 

Hydrogenic Sediment component(s) of inorganic origin formed within the lake. 

Anhydrous ammonia is normally analy2ed for moisture, oil, and residue. The ammonia is first evaporated from the sample and the residue tested (86). In most instances, the amount of oil and sediment ia the samples are insignificant and the entire residue may be assumed to be water. For more accurate moisture determinations, the ammonia can be dissociated into nitrogen and hydrogen and the dewpoint of the dissociated gas obtained. This procedure works well where the concentration of water is in the ppm range. Where the amount of water is in the range of a few hundredths of a percent, acetic acid and methanol can be added to the residue and a Karl Fischer titration performed to an electrometricaHy detected end point (89—92). 

Table 12-4 is a summary of liquid fuel speeifieations set by manufaeturers for effieient maehine operations. The water and sediment limit is set at 1% by maximum volume to prevent fouling of the fuel system and obstruetion of the fuel filters. Viseosity is limited to 20 eentistokes at the fuel nozzles to prevent elogging of the fuel lines. Also, it is advisable that the pour point be 20 °F (11 °C) below the minimum ambient temperature. Failure to meet this speeifieation ean be eorreeted by heating the fuel lines. Carbon residue should be less than 1% by weight based on 100% of the sample. The hydrogen eontent is related to the smoking tendeney of a fuel. Lower... 

Ribosomes, the supramolecular assemblies where protein synthesis occurs, are about 65% RNA of the ribosomal RNA type. Ribosomal RNA (rRNA) molecules fold into characteristic secondary structures as a consequence of intramolecular hydrogen bond interactions (marginal figure). The different species of rRNA are generally referred to according to their sedimentation coefficients (see the Appendix to Chapter 5), which are a rough measure of their relative size (Table 11.2 and Figure 11.25). 

Dissimilatory sulfate reducers such as Desul-fovibrio derive their energy from the anaerobic oxidation of organic compounds such as lactic acid and acetic acid. Sulfate is reduced and large amounts of hydrogen sulfide are generated in this process. The black sediments of aquatic habitats that smell of sulfide are due to the activities of these bacteria. The black coloration is caused by the formation of metal sulfides, primarily iron sulfide. These bacteria are especially important in marine habitats because of the high concentrations of sulfate that exists there. 

Koyama, T. (1963). Gaseous metabolism in lake sediments and paddy soils and the production of atmospheric methane and hydrogen, /. Geophys. Res. 68, 3971-3973. 

Aerobic degradation of hydrocarbons requires access to electron acceptors, generally oxygen in natnral sitnations, added hydrogen peroxide in terrestrial systems, or nitrate or snlfate nnder anaerobic conditions that prevail at deeper levels of the soil or sediment. 

The viscosity of water also changes with temperature. It decreases with an increase in temperature because of the reduction in the number of hydrogen bonds binding the molecules together. The viscosity of water has an influence on the movement of solutes in water and on the sedimentation rate of suspended solids. 

---