Hydrazinium perchlorates, thermal

NICKEL CHLORIDE (7718-54-9) NiClj Violent reaction with chlorine nitrate. Mixtures with potassium produces an impact-sensitive explosive. Contact with strong acids or acid fumes produces highly toxic and corrosive HCl gas. Forms heat- or shock-sensitive explosives with ammonium nitrate. Increases sensitivity to heat, impact, or friction of hydrazinium perchlorate. Incompatible with gold, lithium, sodium, sulfur. Thermal decomposition emits toxic chloride fumes. 

ACETATO MERCURIOSO (Spanish) (21908-53-2) A strong oxidizer. Violent reaction with reducing agents, acetyl nitrate, diboron tetrafluoride, disulfur dichloride, combustible materials, fuels, hydrazine hydrate, hydrogen peroxide, hydrogen trisulfide, hypophospho-rous acid, methanethiol, phospham. sodium-potassium alloy, sulfur, sulfur trioxide. Incompatible with alcohols, alkali metals, ammonium nitrate, diboron tetrafluoride, hydrazinium nitrate, hydrogen sulfide, nitroalkanes, rubidium acetylide, selenium oxychloride. Forms heat-, friction-, or shock-sensitive explosives with anilinium perchlorate, chlorine, phosphorus,. sulfur, magnesium, potassium, sodium-potassium alloy. May increase the explosive or thermal sensitivity of nitromethane, nitroethane, 1-nitropropane and other lower nitroalkanes, silver azide, hydrazinium perchlorate. Slowly decomposes on exposure to air. 

CADMIUM FUME (1306-19-0) Forms explosive mixture with aluminum, ammonium perchlorate, magnesium in the presence of heat, chlorine trifluoride. Explodes or ignites on contact with hydrazinium nitrate, hydrogen peroxide (90%), hydrogen sulfide, hydrogen trisulfide, lithium. Can increase the thermal and explosive sensitivity of nitroalkanes, hydrazinium perchlorate. May react with phosphorus, sulfur, sulfur dioxide, sulfur trioxide, selenium, zinc. 

Tappan BC, Brill TB (2003) Thermal decomposition of energetic materials 85 Cryogels of nanoscale hydrazinium perchlorate in resorcinol-formaldehyde. Propellants Explosives and Pyrotechnics 28(2) 72-76. Li J, Brill TB (2005) Nanostructured energetic composites of CL-20 and binders by sol-gel methods. Propellants Explosives and Pyrotechnics 31(1) 61-69. 

The thermal properties of hydrazinium perchlorate salts are discussed in Section 2.4.5.3 along with other perchlorate hydrazine salts. 

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