Human activities, mercury release

As noted earlier, diverse forms of organomercury are released into the environment as a consequence of human activity. Methyl mercury presents a particular case. As a product of the chemical industry, it may be released directly into the environment, or it may be synthesized in the environment from inorganic mercury which, in turn, is released into the environment as a consequence of both natural processes (e.g., weathering of minerals) and human activity (mining, factory effluents, etc.). 

Organoarsenic compounds have been of importance in human toxicology but have not as yet received much attention in regard to environmental effects. Like methyl mercury compounds, they are both synthesized in the environment from inorganic forms and released into the environment as a consequence of human activity (Environmental Health Criteria 18). They can cause neurotoxicity. 

Pollutant An agent, often released by human activity, that is adversely affecting the environment DDT, PCBs, mercury, lead, etc. 

Mercury is a toxic substance that, through human and natural activities, cycles through the atmosphere, hydrosphere, and ecosphere affecting the health of both humans and wildlife. It enters the environment naturally through erosion, fire, and volcanic processes, as well as a result of human industrial practices. The human activities such as combustion, smelting, and mining have elevated global mercury levels to approximately three times those found before industrialization. Once released, mercury persists in the environment where it circulates between air, water, sediments, and biota in various forms. Mercury is present everywhere in the environment. The level of Hg in air varies from 0.5 ng/m3 to 10 ig/m3. 

Approximately 80% of the mercury released from human activities is elemental mercury released to the air, primarily from fossil fuel combustion, mining, and smelting, and from solid waste incineration. About 15% of the total is released to the soil from fertilizers, fungicides, and municipal solid waste (for example, from waste that contains discarded batteries, electrical switches, or thermometers). An additional 5% is released from industrial wastewater to water in the environment. 

Human activities have resulted in the release of a wide variety of both inorganic and organic forms of mercury. The electrical industry, chloro-alkali industry, and the burning of fossil fuels (coal, petroleum, etc.) release elemental mercury into the atmosphere. Metallic mercury has also been released directly to fresh water by chloro-alkali plants, and both phenylmer-cuiy and methylmercury compounds have been released into fresh and sea water -phenylmercury by the wood paper-pulp industry, particularly in Sweden, and methyl-mercury by chemical manufacturers in Japan. Important mercury compounds which also may be released into the environment include mercury(II) oxide, mercury(II) sulfide (cinnabar), mercury chlorides, mer-cury(II) bromide, mercury(II) iodine, mer-cury(II) cyanide, mercury(II) thiocyanate, mercury(II) acetate, mercury nitrates, mercury sulfates, mercury(II) amidochloride monoalkyl- and monoarylmercury(II) halides, borates and nitrates dialkylmercury compounds like dimethylmercury, alkoxyal-kylmercury compounds or diphenylmercury (Simon and Wiihl-Couturier 2002) (for quantities involved, see Section 17.4). 

One of the most hazardous heavy metal emitted to the atmosphere due to its toxicity is mercury. It is released to environment naturally and through human activities in three forms such as elemental (Hg ), oxidized (Hg ) and particulate (HgP). The examples of natural emission source are emission from ocean and volcanic eruptions, whereas, fuels used for energy production and raw materials used in industrial processes are anthropogenic source of mercury (Pacyna et al. 2006, Pirrone et al. 2010). The latest data revealed that the global pool of mercury mainly results from anthropogenic emissions... 

Cadmium (Cd) anode cells are at present manufactured based on nickel-cadmium, silver-cadmium, and mercury-cadmium couples. Thus wastewater streams from cadmium-based battery industries carry toxic metals cadmium, nickel, silver, and mercury, of which Cd is regarded the most hazardous. It is estimated that globally, manufacturing activities add about 3-10 times more Cd to the atmosphere than from natural resources such as forest fire and volcanic emissions. As a matter of fact, some studies have shown that NiCd batteries contribute almost 80% of cadmium to the environment,4,23 while the atmosphere is contaminated when cadmium is smelted and released as vapor into the atmosphere4 Consequently, terrestrial, aquatic, and atmospheric environments become contaminated with cadmium and remain reservoirs for human cadmium poisoning. 

One area that requires additional study is the use of elemental mercury by members of specific religious or ethnic groups in their ceremonies, rituals, and practices so an assessment of the magnitude of these activities can be made. In addition, information on how mercury is used in these ceremonies and rituals, as well as the methods of mercury disposal used, would be helpful in assessing the potential pathways for human exposure and environmental releases. 

Many researchers have attempted to determine mercury levels in the blood, urine, tissues, and hair of humans and animals. Most methods have used atomic absorption spectrometry (AAS), atomic fluorescence spectrometry (AFS), or neutron activation analysis (NAA). In addition, methods based on mass spectrometry (MS), spectrophotometry, and anodic stripping voltametry (ASV) have also been tested. Of the available methods, cold vapor (CV) AAS is the most widely used. In most methods, mercury in the sample is reduced to the elemental state. Some methods require predigestion of the sample prior to reduction. At all phases of sample preparation and analysis, the possibility of contamination from mercury found naturally in the environment must be considered. Rigorous standards to prevent mercury contamination must be followed. Table 6-1 presents details of selected methods used to determine mercury in biological samples. Methods have been developed for the analysis of mercury in breath samples. These are based on AAS with either flameless (NIOSH 1994) or cold vapor release of the sample to the detection chamber (Rathje et al. 1974). Flameless AAS is the NIOSH-recommended method of determining levels of mercury in expired air (NIOSH 1994). No other current methods for analyzing breath were located. 

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