Hofmeister

Note Some of Grahame s values for and included in this table. For a common cation, the sequence of anions in order of increasing adsorption is similar to that of the Hofmeister series in coagulation studies, and it is evident that specific adsorption properties are involved. [Pg.199]

Cacace M G, Landau E M and Ramsden J J 1997 The Hofmeister series salt and solvent effects on interfacial phenomena Q. Rev. Biophys. 30 241-78... [Pg.2847]

S ts can be used to precipitate proteins by salting out effects. The effectiveness of various salts is determined by the Hofmeister series, with anions being effective in the order citrate > PO4" > SO4" > CH3COO > Cl > NO3 , and cations according to NH4 > > Na ... [Pg.2059]

Hofmeister has recorded the presence of a liquid toxic alkaloid, temuline, C HjjONj, in L. temulentum. ... [Pg.750]

H. Hofmeister, R. Wiechert, K. Annen, H. Laurent and H. Steinbeck, German Often. 2,546,062 Chem. Abstr. 87, 168265k (1977). [Pg.107]

The order of cations and anions regarding these structure breaking and making properties is related to their position in the lyotropic or Hofmeister series, such as... [Pg.5]

Heterogeneous rate constants, 12, 113 Hofmeister sequence, 153 Hybridization, 183, 185 Hydrodynamic boundary layer, 10 Hydrodynamic modulation, 113 Hydrodynamic voltammetry, 90 Hydrodynamic voltammogram, 88 Hydrogen evolution, 117 Hydrogen overvoltage, 110, 117 Hydrogen peroxide, 123, 176... [Pg.207]

Kunz H., Hofmeister A., Glaser B. Stereoselective Syntheses Using Carbohydrates as Carriers of Chiral Information in Polysaccharides 1998 539, Ed. Severian D., Pb. Dekker N.Y. [Pg.308]

Protein conformation is also markedly affected by the concentration and type of ionic species present. In solution, individual salt effects can be either stabilizing or denaturing [26,27], These effects correspond to the Hofmeister lyotropic series ... [Pg.702]

We have examined a number of different salts and have shown that the transition temperature can almost be altered at will (12), in many cases in line with the Hofmeister or lyotropic series (13-15J, a relationship found for many other aqueous systems such as hydrocarbon solubility and protein stability. [Pg.168]

Kan C, Cai W, Li C, Zhang L, Hofmeister H (2003) Ultrasonic synthesis and optical properties of Au/Pd bimetallic nanoparticles in ethylene glycol. J Phys D Appl Phys 36 1609-1614... [Pg.168]

Clarke RJ, Liipfert C (1999) Influence of anions and cations on the dipole potential of phosphatidylcholine vesicles a basis for the Hofmeister effect. Biophys J 76 2614-2624... [Pg.344]

While ionophore-free membranes based on classical ion exchangers are still in use for the determination of lipophilic ions, such sensors often suffer from insufficient selectivity, as it is governed solely by the lipophilicity pattern of ions, also known for anions as the Hofmeister sequence. This pattern for cations is Cs+ > Ag+ >K+ > NH > Na+ > Li+ > Ca2+ > Mg2+ and for anions CIOT > SCN- > I > Sal- > N03- > Br > N02- > Cl- > OAc- HC03- > SO - > HPO4. While the ion exchanger fixes the concentration of hydrophilic analyte ions in the membrane on the basis of the electroneutrality condition within the membrane, the second key membrane component is the ionophore that selectively binds to the analyte ions. The selectivity of... [Pg.102]

Hoffmann J, Bohlmann R, Heinrich N, Hofmeister H, Kroll J, Kunzer H, Lichtner RB, Nishino Y, Parczyk K, Sauer G, et al. (2004) Characterization of new estrogen receptor destabilizing compounds effects on estrogen-sensitive and tamoxifen-resistant breast cancer. J Natl Cancer Inst 96 210-218... [Pg.166]

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