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Hexanedioll

Trimethylene dibromide (Section 111,35) is easily prepared from commercial trimethj lene glycol, whilst hexamethylene dibromide (1 O dibromohexane) is obtained by the red P - Br reaction upon the glycol 1 6-hexanediol is prepared by the reduction of diethyl adipate (sodium and alcohol lithium aluminium hydride or copper-chromium oxide and hydrogen under pressure). Penta-methylene dibromide (1 5-dibromopentane) is readily produced by the red P-Brj method from the commercially available 1 5 pentanediol or tetra-hydropyran (Section 111,37). Pentamethylene dibromide is also formed by the action of phosphorus pentabromide upon benzoyl piperidine (I) (from benzoyl chloride and piperidine) ... [Pg.489]

Diethyl adipate EtOOC(CH2)4COOEt —> 1 -.G-hexanediol H0CH2(CHj)4CH20H... [Pg.878]

To illustrate how aldol condensation may be coupled to functional group modifi cation consider the synthesis of 2 ethyl 1 3 hexanediol a compound used as an insect repellent This 1 3 diol is prepared by reduction of the aldol addition product of butanal... [Pg.773]

Batzer has reported the following data for a fractionated polyester made from sebacic acid and 1,6-hexanediol ... [Pg.68]

Reduction. Hydrogenation of dimethyl adipate over Raney-promoted copper chromite at 200°C and 10 MPa produces 1,6-hexanediol [629-11-8], an important chemical intermediate (32). Promoted cobalt catalysts (33) and nickel catalysts (34) are examples of other patented processes for this reaction. An eadier process, which is no longer in use, for the manufacture of the 1,6-hexanediamine from adipic acid involved hydrogenation of the acid (as its ester) to the diol, followed by ammonolysis to the diamine (35). [Pg.240]

Hexanedione [110-13-4] (acetonylacetone) is one of the most widely used 1,4-diketones. It is a colorless high boiling Hquid prepared by the hydrolysis of 2,5-dimethylfuran (332,333), by oxidation of 2,5-hexanediol (334) or 5-hexen-l-one (335), and from allylacetone (336). Its main use is in solvent systems and as a raw material for chemical synthesis. It is reportedly not highly toxic (336). [Pg.499]

Polyols. Analogous to the use of linear a,C0-dibasic acids, such as adipic and sebacic, polyols with long, flexible chains between hydroxyl groups, such as 1,4-butanediol [110-63-4] 1,6-hexanediol [629-11-8J, and diethylene glycol [111-46-6] may also be used to impart greater flexibiUty ia the resia. [Pg.34]

Polyester and polyether diols are used with MDI in the manufacture of thermoplastic polyurethane elastomers (TPU). The polyester diols are obtained from adipic acid and diols, such as ethylene glycol, 1,4-butanediol, or 1,6-hexanediol. The preferred molecular weights are 1,000 to 2,000, and low acid numbers are essential to ensure optimal hydrolytic stabihty. Also, caprolactone-derived diols and polycarbonate diols are used. Polyether diols are... [Pg.350]

Polyurethane engineering thermoplastics are also manufactured from MDI and short-chain glycols (49). These polymers were introduced by Upjohn/Dow under the trade name Isoplast. The glycols used are 1,6-hexanediol and cyclohexanedimethanol. 1,4-Butanediol is too volatile at the high processing temperatures used in the reaction extmsion process. Blends of engineering thermoplastics with TPU are also finding uses in many appHcations... [Pg.351]

Another method that appears to have commercial potential is the ozonolysis of cyclooctene. Ozonolysis is carried out using a short chain carboxyHc acid, preferably propanoic acid, as solvent. The resultant mixture is thermally decomposed in the presence of oxygen at about 100°C to give suberic acid in about 60—78% yield (38—40). Carboxylation of 1,6-hexanediol using nickel carbonyl as catalyst is reported to give suberic acid in 90% yield (41). [Pg.62]

There are several laboratory methods useful for the preparation of suberic acid. One starting material is 1,6-hexanediol which can be converted to the dibromide with HBr. Reaction of the dibromide with NaCN gives the dinitrile which can be hydrolyzed to suberic acid. The overall yield is 76% (42). Another laboratory method is the condensation of 1,3-cyclohexanedione with ethyl bromoacetate foUowed by reductive cleavage to give suberic acid in 50% yield (43). [Pg.62]

Lipase-catalyzed intermolecular condensation of diacids with diols results in a mixture of macrocycUc lactones and liuear oligomers. Interestingly, the reaction temperature has a strong effect on the product distribution. The condensation of a,(D-diacids with a,(D-dialcohols catalyzed by Candida glindracea or Pseudomonas sp. Upases leads to macrocycUc lactones at temperatures between 55 and 75°C (91), but at lower temperatures (<45°C) the formation of oligomeric esters predorninates. Optically active trimers and pentamers can be produced at room temperature by PPL or Chromobacterium viscosum Upase-catalyzed condensation of bis (2,2,2-trichloroethyl) (+)-3-meth5ladipate and 1,6-hexanediol (92). [Pg.341]

Plasticizers can be classified according to their chemical nature. The most important classes of plasticizers used in rubber adhesives are phthalates, polymeric plasticizers, and esters. The group phthalate plasticizers constitutes the biggest and most widely used plasticizers. The linear alkyl phthalates impart improved low-temperature performance and have reduced volatility. Most of the polymeric plasticizers are saturated polyesters obtained by reaction of a diol with a dicarboxylic acid. The most common diols are propanediol, 1,3- and 1,4-butanediol, and 1,6-hexanediol. Adipic, phthalic and sebacic acids are common carboxylic acids used in the manufacture of polymeric plasticizers. Some poly-hydroxybutyrates are used in rubber adhesive formulations. Both the molecular weight and the chemical nature determine the performance of the polymeric plasticizers. Increasing the molecular weight reduces the volatility of the plasticizer but reduces the plasticizing efficiency and low-temperature properties. Typical esters used as plasticizers are n-butyl acetate and cellulose acetobutyrate. [Pg.626]


See other pages where Hexanedioll is mentioned: [Pg.338]    [Pg.271]    [Pg.283]    [Pg.284]    [Pg.448]    [Pg.873]    [Pg.879]    [Pg.773]    [Pg.476]    [Pg.502]    [Pg.560]    [Pg.598]    [Pg.324]    [Pg.382]    [Pg.382]    [Pg.476]    [Pg.476]    [Pg.304]    [Pg.459]    [Pg.243]    [Pg.243]    [Pg.278]    [Pg.428]    [Pg.428]    [Pg.114]    [Pg.114]    [Pg.122]    [Pg.344]    [Pg.40]    [Pg.257]    [Pg.374]    [Pg.90]    [Pg.1014]    [Pg.773]    [Pg.18]   
See also in sourсe #XX -- [ Pg.6 , Pg.246 , Pg.352 , Pg.454 , Pg.456 ]




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1 : 6-Hexanediol

1 : 6-Hexanediol

1,2-Hexanediol diacetate

1,2-Hexanediol oxidative cleavage

1,6-Hexanediol diacrylate

1,6-Hexanediol diacrylate properties

1,6-Hexanediol, diisocyanate

1,6-hexanediol nitrate

1,6-hexanediol, polycondensation with

1.4- Diols 2,5-dimethyl-2,5-hexanediol

2,5-dimethyl-2,5-hexanediol

2-Ethyl-l,3-hexanediol

3-Methyl-1,6-hexanediol

Ethyl hexanediol

Furan, 2,5-dimethyltetrahydrosynthesis via 2,5-hexanediol

Hexamethylene Glycol *1, 6-Hexanediol

Hexanediol and derivs

Hexanediol chloride

Hexanediol, 2,5-dimethylnickel acetate

Hexanediol, 2,5-dimethylnickel acetate cyclic ketone reduction

Polymerization 1,6-hexanediol diacrylate

Thiacyclodec-4-ene S-oxide via l,6-dibromo-3,4-hexanediol

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