1,6-hexanediol nitrate

Dimethylolhexanediol or Bis(hydroxymethyl) hexanediol and Derivatives 2,5 DimethyloUl, 6-hexanediol, [Pg.248]

Dinitro-2,5-dimethylol-l, 1-hexanediol tetra-nitrate 5 D1354-D1355... 

Cyclic Ketone Alcohols or Cycloolkanones, They are prepd by condensation of the corresponding cyclic ketones with formaldehyde in the presence of alkali. They are converted by reduction into cyclic alcohols. Friederich (Ref 1) found that cyclic ketone alcohols (such as tetramethylol-cyclopentanone, tetramethylolcyclohexanone octamethylolcyclohexanedione) and cyclic alcohols (such as tetramethylolcyclopentanol, tertramethylolcyclohexanol, octamethylolcyclo-hexanediol) on nitration yield expl products. 

Tetrakis (Difluoroamino)-3/4-Hexanediol Dinitrate. C6H8F8N606 mw 412 20 N= 20.39% OB to C02 —38.82% yel vise oil bp, decompn at 155°. Sol in chlf. Prepn is by nitration of 1,2,4,6-tetrakis (difluoroamino)-3,4-hexanediol in chlf with mixed acid (50/50) at below 25°. After 6 hrs of stirring the mixt is poured over ice and the chlf layer evapd leaving the prod. The inventor claims the compd is useful as an expl and rocket propint Ref R.A. Smiley, 1,2,5,6-Tetrakis (Difluoro-amino)-3,4-HexanedioI Dinitrate Rocket Propellant and Explosive , USP 3331867 (1967) CA 67,75036(1967)... 

Dinitro-2,5-dimethyIol-l, 1-hexanediol Tetranitrate 2,5-Bis(hydroxymethyI)-2,5-dinitro-1,6-hexanediol Tetranitrote or 1,4 Dinitro-1,1,4,4 tetramethylolbutane Tetra-nitrate (called by Blatt, Ref 3)... 

We can also classify the systems based on the states of the reactants and products. Monofunctional monomers such as benzyl acrylate are liquids and produce liquid polymers, and we call these Tiquid/liquid systems. Figure 1 shows a schematic of the changes in properties across a liquid/liquid front. Multifunctional monomers such as 1, 6 hexanediol diacrylate (HDDA) are liquid but produce a thermoset, solid product, and these we call liquid/solid systems. Finally, solid monomers such as acrylamide (8,25) and transition metal nitrate complexes of acrylamide (26-28) can be polymerized frontally in solid/solid systems. 

There are many other unitary operations which are used by organic chemistry plants to manufacture synthetic solvents. These include alkoxylation (ethylene glycol), halogenation (1,1,1-trichloethane), catalytic cracking (hexane), pyrolysis (acetone and xylene), hydrodealkylation (xylene), nitration (nitrobenzene), hydrogenation (n-butanol, 1,6-hexanediol), oxidation (1,6-hexanediol), esterification (1,6-hexanediol), and many more. 

Dodecyl acrylate microspheres, crosslinked with hexanediol diacrylate, were prepared by emulsion polymerisation and characterised by scanning electron microscopy, particle size measurement, and differential scanning calorimetry. The microspheres were doped with 9-(diethylamino)-5-(octadecanoylimino)-5H-benzo(alpha)phenoxazine (ETH 5294), a chromoionophore whose fluorescence emission spectrum is sensitive to pH. These microspheres adsorb anions selectively according to their lipophilicity, and therefore can be used as anion-selective optical sensors. The responses of the microspheres to chloride, nitrate and perchlorate ions were reported. 27 refs. 

Tetraoctylammonium nitrate (TOAN) triooctyl phosphonate (TOP) aliphatic urethane diacrylate Ebecryl 270 and hexanediol diacrylate (HDDA) 2-2 -dimethoxyl phenylace-tophenone (Irgacure 651) -62.6 2.3 X 10- 6x 10- 1 X 10- cr = -2.o 116... 

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