Heating roasting

Test how chromium nitride reacts with water and with an alkali solution in the cold and with heating. Roast part of the nitride in a porcelain crucible on the flame of a burner. Identify the product. 

Dextrins are produced by dry heating (roasting) starch in the presence of an acid catalyst. They are produced in a range of viscosity and color specifications. Dextrins are primarily used as adhesives in paper conversion, such as laminating and envelope production. A low-viscosity dextrin is used in Europe as a total chlorine free (TCF) coating binder for application on TCF paper. 

PAHs are ubiquitous. They are present in the atmosphere as components of a variety of dusts, soots, tars, oils, engine exhaust gases in water in many commonly consumed foodstuffs, particularly those that are heated, roasted, or broiled... 

Pyrometallurgy, which involves the use of heat (roasting, smelting, etc.) for processing... 

The common ores of zinc are zinc blende, ZnS, and calamine, ZnC03. The metal is extracted (a) by roasting blende with air or by heating... 

It occurs chiefly as cinnabar, the red sulphide HgS, from which it is readily extracted either by roasting (to give the metal and sulphur dioxide) or by heating with calcium oxide the metal distils off and can be purified by vacuum distillation. 

The iodides of the alkaU metals and those of the heavier alkaline earths are resistant to oxygen on heating, but most others can be roasted to oxide in air and oxygen. The vapors of the most volatile iodides, such as those of aluminum and titanium(II) actually bum in air. The iodides resemble the sulfides in this respect, with the important difference that the iodine is volatilized, not as an oxide, but as the free element, which can be recovered as such. Chlorine and bromine readily displace iodine from the iodides, converting them to the corresponding chlorides and bromides. 

Germany, Bitterfeld 1920 two-stage rotary kilns heated internally using intermediate grinding of roast oxidation completed within 3—4 h cylindrical monopolar ceUs, 4 m volume undivided con-centric Ni anodes, rod-shaped Fe cathodes unfiltered electrolyte batch operation KMnO crystallizes in ceU electrolysis energy consumption about 700 kWh/1 4,000 27,113... 

Secondary. Scrap material, industrial and municipal wastes, and sludges containing mercury are treated in much the same manner as ores to recover mercury. Scrap products are first broken down to Hberate metallic mercury or its compounds. Heating in retorts vaporizes the mercury, which upon cooling condenses to high purity mercury metal. Industrial and municipal sludges and wastes may be treated chemically before roasting. 

Pyrometallurgy. Metallurgy involved in winning and refining metals where heat is used, as in roasting and smelting. PyrometaHurgy is the oldest extractive process and is probably the most important. 

Roast. The heating of soflds, frequently to promote a reaction with a gaseous constituent in the furnace atmosphere. 

HydrometaHurgical Processes. The hydrometaHurgical treatments of oxide ores involve leaching with ammonia or with sulfuric acid. In the ammoniacal leaching process, the nickel oxide component of the ore first is reduced selectively. Then the ore is leached with ammonia which removes the nickel into solution, from which it is precipitated as nickel carbonate by heating. A nickel oxide product used in making steel is produced by roasting the carbonate. 

The sodium tungstate solution is filtered from the resulting slurry. Similarly, in the alkaH roasting process, the concentrate, either scheeHte or wolframite, is heated with sodium carbonate in a rotary kiln at 800°C and then leached using hot water to remove the sodium tungstate. Wolframite ores are also decomposed by reaction with a sodium hydroxide solution at 100°C. 

Zinc does not react with nitrogen, even at elevated temperatures but zinc nitride, Zn N2, forms with ammonia at red heat. Zinc sulfide, the most common form of zinc in nature, is not reduced direcdy in commercial practice because of reactions of the zinc vapor during condensation. Rather, the sulfide is burned (roasted) to the oxide plus sulfur dioxide before reduction. However, zinc can be reduced to the metal at ca 1300°C with carbon or iron. 

The zinc sulfide in the concentrate is always converted to oxide by roasting. An exception is the direct leach process described below. The principal overall roasting reaction is strongly exothermic and provides excess heat which is recovered. 

Multiple-hearth roasting offers ease of operation, abiUty to handle a wide variety of ores or blends, and Httle downtime. On the other hand, these furnaces are no longer being built because of their high capital and labor costs, relatively low sulfur dioxide off-gas, need for added fuel, and marginal opportunity for waste-heat recovery. 

---