HDPEs

Ffigh-density polyethylene (HDPE) Thermoplastic elastomers... 

HDPE [OLEFIN POLYMERS - POLYETHYLENE - HIGH DENSITY POLYETHYLENE] (Vol 17)... 

Blends of PET and HDPE have been suggested to exploit the availabiUty of these clean recycled polymers. The blends could combine the inherent chemical resistance of HDPE with the processiag characteristics of PET. Siace the two polymers are mutually immiscible, about 5% compatihilizer must be added to the molten mixture (41). The properties of polymer blends containing 80—90% PET/20—10% HDPE have been reported (42). Use of 5—15% compatbiLizer produces polymers more suitable for extmsion blow mol ding than pure PET. 

The economics of recycling PET are more favorable than recycling HDPE. To iacrease the recycling of HDPE, the separation of bottles made of these two plastics could be omitted and a mixture processed. Coarse, light-colored powders of the two polymers have been prepared by an experimental soHd state shear extmsion pulverization process (55). The powder has been successfully injection molded without pelletization. 

Results obtained for two mixed plastics are summarized in Table 4. A balance exists between process temperature, plastics feed rate, and product yields (67). For example, lower temperatures increase wax formation due to incomplete depolymerization. Slower feed rates and increased residence times reduce wax formation and increase the yield of Hquids. The data summarized in Table 4 illustrate that the addition of PET to a HDPE PP PS mixture changes the performance of the Conrad process. Compared to the reference HDPE PP PS mixture, increased amounts of soHds ate formed. These are 95% terephthahc acid and 5% mono- and bis-hydroxyethyl esters. At higher temperatures, apparentiy enough water remains to promote decarboxylation. 

Price swings, particularly in the PET and HDPE markets have contributed to a retrenchment in the U.S. plastics recycling industry in 1995—1997... 

In 1994 in the U.S., recycled PET, HDPE, LDPE, and PS had a 16—46% cost advantage (4). This cost advantage largely disappeared by 1996. Bureau of Labor Statistics data indicate U.S. plastics prices in mid-1997 are seven percent below those of mid-1995 after being more than ten percent less in 1996... 

HDPE, high density polyethylene PP, polypropylene EVA, ethylene—vinyl alcohol SMC, sheet-molding compound ERP, fiber-reinforced plastic LDPE, low density polyethylene PE, polyethylene BMC, bulk mol ding compound TPE, thermoplastic elastomer. 

In the sheeting market, the low density polyethylenes are less important than the high density resins. The high density resins have excellent chemical resistance, stress-crack resistance, durabiUty, and low temperature properties which make them ideal for pond liners, waste treatment faciUties, and landfills. In thicker section, HMW-HDPE sheet makes good containers, trays, tmck-bed liners, disposable items, and concrete molds. The good durabiUty, abrasion resistance, and light weight are critical elements for its selection. 

There are three basic types of polyethylene foams of importance (/) extmded foams from low density polyethylene (LPDE) (2) foam products from high density polyethylene (HDPE) and (J) cross-linked polyethylene foams. Other polyolefin foams have an insignificant volume as compared to polyethylene foams and most of their uses are as resia extenders. 

Plastic materials represent less than 10% by weight of all packagiag materials. They have a value of over 7 biUion including composite flexible packagiag about half is for film and half for botties, jars, cups, tubs, and trays. The principal materials used are high density polyethylene (HDPE) for botties, low density polyethylene for film, polypropylene (PP) for film, and polyester for both botties and films. Plastic resias are manufactured by petrochemical companies, eg. Union Carbide and Mobil Chemical for low density polyethylene (LDPE), Solvay for high density polyethylene, Himont for polypropylene, and Shell and Eastman for polyester. 

Second, in the early 1950s, Hogan and Bank at Phillips Petroleum Company, discovered (3,4) that ethylene could be catalyticaHy polymerized into a sohd plastic under more moderate conditions at a pressure of 3—4 MPa (435—580 psi) and temperature of 70—100°C, with a catalyst containing chromium oxide supported on siUca (Phillips catalysts). PE resins prepared with these catalysts are linear, highly crystalline polymers of a much higher density of 0.960—0.970 g/cnr (as opposed to 0.920—0.930 g/cnf for LDPE). These resins, or HDPE, are currentiy produced on a large scale, (see Olefin polymers, HIGH DENSITY POLYETHYLENE). 

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