Clean gas

W. Strauss, "Particulate Collection by Liquid Sembbing," in Industrial Gas Cleaning 2nd ed., Pergamon Press, Oxford, 1975, Chapt. 9, pp. 367—408. 

The process is carried at moderate (slightly above atmospheric) pressures, but at very high temperatures that reach a maximum of 1900°C. Even though the reaction time is short (0.6—0.8 s) the high temperature prevents the occurrence of any condensable hydrocarbons, phenols, and/or tar in the product gas. The absence of Hquid simplifies the subsequent gas clean-up steps. 

The use of hot gas clean-up methods to remove the sulfur and particulates from the gasified fuel increases turbine performance by a few percentage points over the cold clean-up systems. Hot gas clean-up permits use of the sensible heat and enables retention of the carbon dioxide and water vapor in the... 

The latest installations incorporate a waste heat boiler in the off-gas cleaning system to recover sensible heat from the rotary kiln off-gas. There is sufficient sensible heat in the off-gas from the SL/RN process to generate 500 to 700 kWh/t of DRJ, depending on the type of reductant used. 

The dried charge is pneumatically fed to a burner mounted on the roof of the reaction shaft. Normally oxygen is used to get an autogenous smelt. The offgases analy2e around 70% SO2 and can be used for the manufacture of sulfuric acid after conventional gas cleaning. 

It is generally unacceptable to emit sulfur dioxide, thus the scmbber effluent must be treated for sulfur dioxide removal. If the plant aheady possesses faciUties for the production of sulfuric acid, this rather concentrated sulfur dioxide stream can be easily fed into the wet gas cleaning circuit and disposed of in the sulfuric acid plant. The quantity is so small that it does not put any additional burden on the sulfuric acid plant. Because no tellurium is carried over with the selenium dioxide during roasting, it is possible to produce a selenium product which can be purified to commercial grade (99.5-99.7%). 

In the gas cleaning sections of spent acid or metaUurgical sulfuric acid plants, the weak acid scmbbing circuit is typicaUy handled by plastic or glass fiber reinforced plastic (ERP) pipe. The contaminants in weak acid usuaUy vary too greatly to aUow use of an economical aUoy. 

The exhaust gases are generally discharged into dust and fume knockdown equipment to avoid contamination of the atmosphere. Gas-cleaning equipment includes cyclones, setthng chambers, scrubbing towers, and electrical precipitators. Heat-recoveiy devices are utilized both within and outside the lain. These result in an increase in lain capacity or a decrease in fuel consumption. Waste-heat boilers, grates, coil systems, and chains are used for this purpose. 

G-7. Stern, Air Follution, 3d ed., vols. 3-5, Academic, Orlando, FL, 1976-77. G-8. Strauss, Industtial Gas Cleaning, 2d ed., Pergamon, New York, 1975. G-9. Theodore and Biionicore, Air Follution Control Equipment Selection, Design, Operation and Maintenance, Prentice Hall, Englewood Cliffs, NJ, 1982. 

With good diy scrubbing sorbents, the controlling resistance for gas cleaning is external turbulent diffusion, which also depends on energy dissipated by viscous and by inertial mechanisms. It turns out to Be possible to correlate mass-transfer rate as a fimctiou of the fric tiou Factor. 

Optimized modern dry scrubbing systems for incinerator gas cleaning are much more effective (and expensive) than their counterparts used so far for utility boiler flue gas cleaning. Brinckman and Maresca [ASME Med. Waste Symp. (1992)] describe the use of dry hydrated lime or sodium bicarbonate injection followed by membrane filtration as preferred treatment technology for control of acid gas and particulate matter emissions from modular medical waste incinerators, which have especially high dioxin emissions. 

A development of interest to the chemical industiy is the tubular precipitator of reinforced-plastic construction (Wanner, Gas Cleaning Plant after T1O2 Rotary Kilns, technical bulletin, Lurgi Corp., Frankfurt, Germany, 1971). Tubes made of polyvinyl chloride plastic are reinforced on the outside with polyester-fiber glass. The use of modern economical materials of construction to replace high-maintenance materials such as lead has been long awaited for corrosive applications. 

Foaming is usually caused by contamination of glycol with salt, hydrocarbons, dust, mud, and corrosion inhibitors. Remove the source of contamination with effective gas cleaning ahead of the absorber, improved solids filtration, and carbon purification. 

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