Fusible

These additives must thus be capable of decomposing under heat action by liberating the species that react with the moving metal or metals by creating an interphase more fusible than the metal itself. 

Before this treatment, the cassiterite content of the ore is increased by removing impurities such as clay, by washing and by roasting which drives off oxides of arsenic and sulphur. The crude tin obtained is often contaminated with iron and other metals. It is, therefore, remelted on an inclined hearth the easily fusible tin melts away, leaving behind the less fusible impurities. The molten tin is finally stirred to bring it into intimate contact with air. Any remaining metal impurities are thereby oxidised to form a scum tin dross ) on the surface and this can be skimmed off Very pure tin can be obtained by zone refining. 

Place 50 g. of o-chloronitrobenzene and 75 g. of clean dry sand in a 250 ml. flask equipped with a mechanical stirrer. Heat the mixture in an oil or fusible metal bath to 215-225° and add, during 40 minutes, 50 g. of copper bronze or, better, of activated copper bronze (Section 11,50, 4) (1), Maintain the temperature at 215-225° for a further 90 minutes and stir continuously. Pour the hot mixture into a Pyrex beaker containing 125 g. of sand and stir until small lumps are formed if the reaction mixture is allowed to cool in the flask, it will set to a hard mass, which can only be removed by breaking the flask. Break up the small lumps by powdering in a mortar, and boil them for 10 minutes with two 400 ml. 

Place 150 g. of benzoic acid, 150 g. (139 ml.) of acetic anhydride and 0-2 ml. of syrupy phosphoric acid in a 500 ml. bolt-head flask. Fit the latter with a two-holed stopper carrying a dropping funnel and an efficient fractionating column (compare Fig. 7/7, 61, 1) it is advisable to lag the latter with asbestos cloth. Set up the flask in an oil bath or in a fusible metal bath. Distil the mixture very slowly and at such a rate that the temperature of the vapour at the head of the column does... 

As a general rule flasks and similar vessels should be heated in an air bath (compare Fig. II, 5, 3). A glycerol bath may be employed for temperatures up to 140° the glycerol is subsequently removed from the outside of the vessel by washing with water. Medicinal liquid paraffin may be used for temperatures up to about 220° hard hydrogenated cotton seed oil, Silicone fluids or fusible metal may be employed when higher temperatures are required. Small test-tubes and centrifuge tubes... 

Iron is hard, brittle, fairly fusible, and is used to produce other alloys, including steel. Wrought iron contains only a few tenths of a percent of carbon, is tough, malleable, less fusible, and has usually a "fibrous" structure. 

Alloys of tin are very important. Soft solder, type metal, fusible metal, pewter, bronze, bell metal. Babbitt metal. White metal, die casting alloy, and phosphor bronze are some of the... 

Chlorine is stored and transported as a Hquefied gas in cylinders of 45.4-kg or 68-kg capacity that are under pressure and equipped with fusible-plug rehef devices. Quantities in the range of 15 to 90 t are transported in tank cars having special angle valves on the manhole cover on top of the vessel. Tank barges of the open-hopper type having several cylindrical uninsulated pressure vessels are used for amounts ranging from 600 to 1200 t. Road tankers are used for capacities of 15 to 20 t. 

In addition to dyeabiHty, polyesters with a high percentage of comonomer to reduce the melting poiat have found use as fusible biader fibers ia nonwoven fabrics (32,34,35). Specially designed copolymers have also been evaluated for flame-retardant PET fibers (36,37). 

Coating Theory. This theory includes fire retardants which form an impervious skin on the fiber surface. This coating may be formed during normal chemical finishing, or subsequently when the fire retardant and substrate are heated. It excludes the air necessary for flame propagation and traps any tarry volatiles produced during pyrolysis of the substrate. Examples of this type of agent include the easily fusible salts such as carbonates or borates. 

Acetylene cylinders are fitted with safety devices to release the acetylene ia the event of fire. Cylinders manufactured ia the United States are equipped with safety devices which contain a fusible metal that melts at 100°C. In large cylinders the safety devices are ia the form of a replaceable, threaded steel plug with a core of fusible metal. Small cylinders (0.28 and 1.12 m 10 and 40 fT, respectively) may have the fusible metal ia passages ia the cylinder valve. 

The solder and ahoy market, including low melting or fusible ahoys, is a principal user of indium (see SoLDERS AND BRAZING ALLOYS). The addition of indium results in unique properties of solders such as improved corrosion and fatigue resistance, increased hardness, and compatibhity with gold substrates. To fachitate use in various appHcations, indium and its ahoys can be easily fabricated into wine, ribbon, foil, spheres, preforms, solder paste, and powder. 

Low Melting Alloys. Lead ahoys having large amounts of bismuth, tin, cadmium, and iadium that melt at relatively low (10—183°C) temperatures are known as fusible or low melting ahoys. The specifications of many of these ahoys are Hsted ia ASTM B774-87 (7). 

Developments. A variety of process modifications aimed at improving surface finish or weld line integrity have been described. They include gas assisted, co-injection, fusible core, multiple Hve feed, and push—pull injection mol ding (46,47). An important development includes computer-aided design (CAD) methods, wherein a proposed mold design is simulated by a computer and the melt flow through it is analy2ed (48). 

This scheme eliminates the process of converting bis(etherimide)s to bis(ether anhydride)s. When polyetherimides are fusible the polymerization is performed in the melt, allowing the monamine to distill off. It is advantageous if the amino groups of diamines are more basic or nucleophilic than the by-product monoamine. Bisimides derived from heteroaromatic amines such as 2-arninopyridine are readily exchanged by common aromatic diamines (68,69). High molecular weight polyetherimides have been synthesized from various N,lSf -bis(heteroaryl)bis(etherimide)s. 

Various melt-fusible polyimides whose T s range from 250 to 350°C are avadable as mol ding powders or pellets. LARC-TPI was developed by... 

Natural resins are generally described as solid or semisolid amorphous, fusible, organic substances that are formed in plant secretions. They are usually transparent or translucent yeUow-to-brown colored, and are soluble in organic solvents but not in water. The principal uses for natural resins are in varnishes, printing inks, adhesives, paper size, and polymer compositions. The term natural resins includes tree and plant exudates, fossil resins, mined resins, and shellac. They often have been altered from their original state during isolation and processing. For some appHcations, the resins have been chemically modified to increase their industrial utiUty. 

Iron Precipitation. Rich sulfide ore or Hquated antimony sulfide (cmde antimony) is reduced to metal by iron precipitation. This process, consisting essentially of heating molten antimony sulfide ia cmcibles with slightly more than the theoretical amount of fine iron scrap, depends on the abihty of iron to displace antimony from molten antimony sulfide. Sodium sulfate and carbon are added to produce sodium sulfide, or salt is added to form a light fusible matte with iron sulfide and to faciHtate separation of the metal. Because the metal so formed contains considerable iron and some sulfur, a second fusion with some Hquated antimony sulfide and salt foHows for purification. 

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