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Heterocyclic fused

Hydrazino groups are also converted into H-compounds with mercury(II) oxide (74CR(C)-(278)427) in other reactions they have given hydrazones, or have been converted into pyrazoles and fused heterocyclic rings (77JAP(K)7785194), e.g. (72) -> (73). [Pg.211]

In summary, all estimates of resonance energies indicate a decrease in aromaticity in the sequence benzene > thiophene > pyrrole > furan. Similar sequences are also found for the benzo[6] and dibenzo analogues. A somewhat different sequence is found for the benzo[c] fused heterocycles with isoindole > benzo[c]thiophene > benzo[c]furan. As would be anticipated, the resonance energies for the benzo[c] heterocycles are substantially lower than those for their benzo[6] isomers. [Pg.28]

The five-membered ring heterocycles possess Diels-Alder reactivity of varying degree. This is most pronounced in the case of furan and benzo[c] fused heterocycles such as isoindole. In this capacity they are functioning as heterocyclic analogues of cyclopentadiene, and high Diels-Alder reactivity can be correlated with low aromaticity. [Pg.41]

Benzo[Z)]furans and indoles do not take part in Diels-Alder reactions but 2-vinyl-benzo[Z)]furan and 2- and 3-vinylindoles give adducts involving the exocyclic double bond. In contrast, the benzo[c]-fused heterocycles function as highly reactive dienes in [4 + 2] cycloaddition reactions. Thus benzo[c]furan, isoindole (benzo[c]pyrrole) and benzo[c]thiophene all yield Diels-Alder adducts (137) with maleic anhydride. Adducts of this type are used to characterize these unstable molecules and in a similar way benzo[c]selenophene, which polymerizes on attempted isolation, was characterized by formation of an adduct with tetracyanoethylene (76JA867). [Pg.67]

Pyrazoles can be prepared by ring opening reactions of fused systems already containing the pyrazole nucleus. Thus several [5.5], [5.6] and [5.7] fused heterocycles have been opened to substituted pyrazoles, usually in basic medium. In general, the method has little preparative interest since another pyrazole derivative has usually been used to build the ring-fused system. However, due to the unexpected structures obtained, two publications are worthy of notice. 6//-Cyclopropa[5a,6a]pyrazolo[l,5-a]pyrimidine (638) was readily obtained from the corresponding pyrazolopyrimidine by the action of diazomethane at room temperature (Scheme 59) (81H(15)265). When (638) was treated with potassium hydroxide, the pyrazole (640) was formed, probably via the diazepine (639). [Pg.285]

Diazepines alkylation, 7, 617 electrophilic reactions, 7, 615 with fused heterocyclic rings... [Pg.596]

Aromatic macrocycles, flat hydrophobic molecules composed of fused, heterocyclic rings, such as ethidium bromide, acridine orange, and actinomycin D... [Pg.370]

G. Amino Group as Part, of a Fused Heterocyclic Ring. . . 426... [Pg.340]

Structure of tropones, tropolones, and tropylium salts with fused heterocyclic rings 95AHC(64)81. [Pg.205]

Chemistry of C-nucleosides of fused heterocyclic bases 98AHC(70)163. [Pg.262]

Physostigmine (36) is actually a complex fused heterocycle iMther than a simple derivative of aniline. The drug is men-... [Pg.111]


See other pages where Heterocyclic fused is mentioned: [Pg.9]    [Pg.30]    [Pg.41]    [Pg.107]    [Pg.167]    [Pg.263]    [Pg.267]    [Pg.132]    [Pg.161]    [Pg.172]    [Pg.92]    [Pg.271]    [Pg.530]    [Pg.4]    [Pg.5]    [Pg.508]    [Pg.423]    [Pg.424]    [Pg.426]    [Pg.428]    [Pg.430]    [Pg.432]    [Pg.225]    [Pg.226]    [Pg.227]    [Pg.228]   
See also in sourсe #XX -- [ Pg.57 ]




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1.2.4- Triazines fused to heterocycles with 6-and 7-membered

1.2.4- Triazines fused to two heterocyclic rings

Acridines, heterocycle-fused

Benzene-fused five-membered heterocycles

Benzene-fused heterocycles containing tellurium, selenium and sulphur

Benzo-fused five-membered heterocycles

Benzo-fused five-membered heterocycles aromaticity

Benzo-fused heterocycles

Benzo-fused heterocycles, reduction

Benzo-fused heterocycles, synthesis

Benzo-fused heterocyclic cations

Bicyclic Fused Heterocycles

Compounds containing Three or Four Fused Heterocyclic Rings (5,5,5), (5,5,6), (5,5,7), (5,6,7), and

Condensed 1,2,4-triazines: I. Fused heterocycles with three-, four-, and

Condensed 1,2,4-triazines: I. Fused heterocycles with three-, four-, and fivemembered rings

FIVE-MEMBERED HETEROCYCLES FUSED TO A BENZENE RING

Ferrocenes Containing a Heterocyclic Ring Fused to the Ferrocene

Fischer, G., Tropones, Tropolones, and Tropylium Salts with Fused Heterocyclic

Five-Membered Heterocycles Fused to Benzene

Five-Membered Heterocycles Fused to One Benzene Ring

Five-Membered Heterocyclic Rings and Their Fused Derivatives

Five-membered heterocycles fused with

Fused Five-Membered Heterocycles

Fused Heterocycles containing One Oxygen or Sulphur Atom

Fused Heterocyclic Compounds

Fused Heterocyclic Rings

Fused heterocycles sharing at least one heteroatom

Fused heterocycles systems

Fused heterocycles, synthesis

Fused heterocyclic systems

Fused nitrogen heterocycles

Fused quinoline heterocycles

Fused to a Second Heterocyclic Ring

Fused to heterocycles with 6-and

Fused to heterocycles with 6-and 7-membered rings

Fused to other Nitrogen-containing Heterocycles

Fused to two heterocyclic rings

Fused-Ring Five-Membered Heterocycles Indoles and Purines

Fused-Ring Heterocyclic Compounds

Fused-ring five-membered heterocycles

Fused-ring heterocycle

HETEROCYCLES FUSED TO TWO AROMATIC RINGS

Heteroaromatic compounds fused heterocycles

Heterocycle-fused -catalyzed synthesis

Heterocycles fused

Heterocycles fused

Heterocycles fused to a benzene ring

Heterocyclic Ring-Fused 1,2-Thiazines

Heterocyclic aromatic compounds fused

Heterocyclic fused TCNQ acceptors

Heterocyclic fused spirocyclic

Lithiation benzo fused heterocycles

Medicinal interest fused heterocycles

Medium ring size heterocycles fused with

Microwave irradiation fused heterocycles

Naming fused heterocycles

Nomenclature fused heterocyclic compounds

Numbering peripheral, fused heterocycles

Other Fused Heterocyclic Compounds

Other Seven-Membered Heterocycles Fused to a Benzene Ring

Oxidative cleavage of fused heterocyclic ring systems

Palladium Catalysis in the Synthesis of Benzo-Fused Heterocycles

Polycyclic fused nitrogen heterocycles

Purines Fused with Five-Membered Heterocycles

Pyrimidines heterocyclic fused

SEVEN-MEMBERED HETEROCYCLIC RINGS FUSED TO BENZENE

Selenophens Fused to Six-membered Heterocyclic Aromatic Rings

Six-Membered Heterocycles Fused to One Benzene Ring

Spiro-fused heterocycles

Spiro-fused heterocycles, formation

Steroids Having Fused Heterocyclic Rings

Stille reactions fused heterocycles

Synthesis of Fused Heterocycles

Synthesis of Quinoxalines from Various Fused Nitrogen-Containing Heterocycles Without a Pyrazine Fragment

Trivial names fused heterocycles

Tropolones with fused heterocyclic rings

Tropolones with fused heterocyclic rings structure, reactivity, and application

Tropolones with fused heterocyclic rings synthesis

Tropones with fused heterocyclic rings

Tropones with fused heterocyclic rings structure, reactivity, and application

Tropones with fused heterocyclic rings synthesis

Tropylium salts with fused heterocyclic rings

Tropylium salts with fused heterocyclic rings synthesis

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