Functional embedding

Special dibenzoxazepinones 86, obtained through the general method described in Fig. 16 and containing, as a third additional functionality, a triple bond, have been further cyclized via a palladium-catalysed hydroamination reaction (Fig. 17) [68]. In this way complex polycyclic systems 87 have been assembled in three steps, taking advantage of the three additional functions embedded in the starting component the aryl fluoride, the phenol and the triple bond. 

The lifetimes T 9q) displayed in Fig. 9.5 were calculated for fixed Iq. In order to obtain a better impression where the firactal features of T are located in the 9o, lo plane, T 9o,lo) was calculated as a function of the two initial conditions 9o and Iq for e — 0.5 and p = 1. The result is shown in Fig. 9.6 in the form of a grey-scale plot. The darker the shades in Fig. 9.6 the longer lived the molecule. Again there are apparently unresolved regions in Fig. 9.6(a). A magnification of the framed detail of Fig. 9.6(a) is shown in Fig. 9.6(b). Again there are apparently unresolved structures in Fig. 9.6(b). As before in the one-dimensional case one will never be able to resolve the two-dimensional features in T 9q, Iq) as more and more structme appears on smaller and smaller scales. Thus, T 9q, Iq) is a fractal function embedded in the two-dimensional 9q — Iq) space. 

The aminal function embedded in hexahydropyrrolo[l,2- 7]imidazoles 646 (Scheme 155) renders them prone to equilibration and eliminations under basic conditions. For example 646 (E = CN, C02Me) undergoes epimerization 647 upon storage or exposure to basic alumina. In the case of chloronitrile 648, a 2,4-disubstituted pyrrole is readily formed under mild conditions <1998J(P1)2061>. 

Next to a representing function, embedded lead users report that they also lead opinions In their user community (Sportl, 2, 3, 6 Healthl LeisureS). This opinion leadership is strongly coupled to the embedded lead users use experience my informants report that they were only regarded as opinion leaders, if other users believed them to know more about the products or to be more advanced in use than themselves. 

The Teletest control circuitry is a typical embedded system which requires a microprocessor, memories and other peripherals such as Analogue-to-Digital Converter (ADC), Digital-to-Analogue Converters (DAC). An embedded system is a special-purpose computer system designed to perform one or more dedicated functions. Embedded systems can be optimized for special tasks to reduce the size and cost of the product, also to increase the reliability and enhance the performance of the system. 

Further, multitopic anion receptors 10-12 (Fig. 5), containing thiourea functionalities embedded into an oligosaccharide structure, were designed. The p-iylene bis(thiourea) was used as an aromatic framework to construct the binding site of proper geometry for dicarboiylates. 

Kliiner T, Govind N, Wang YA, Carter EA (2002) Periodic density functional embedding theory for complete active space self-consistent field and configuration interaction calculations ground and excited states. J Chem Phys 116 42... 

Calculations, functions, embedded simulations or processes must terminate so that further actions can be initiated. In case of correct data not being provided within the defined time-interval, the system could fail. 

Andriotis, A. N., Menon, M. (2001). Greens function embedding approach to quantum conductivity of single wall carbon nanotubes. Journal of Chemical Physics, 115, 2737. 

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