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Fragmenting pattern

Separation of families by merely increasing the resolution evidently can not be used when the two chemical families have the same molecular formula. This is particularly true for naphthenes and olefins of the formula, C H2 , which also happen to have very similar fragmentation patterns. Resolution of these two molecular types is one of the problems not yet solved by mass spectrometry, despite the efforts of numerous laboratories motivated by the refiner s major interest in being able to make the distinction. Olefins are in fact abundantly present in the products from conversion processes. [Pg.50]

It is well known that the electron-impact ionization mass spectrum contains both the parent and fragment ions. The observed fragmentation pattern can be usefiil in identifying the parent molecule. This ion fragmentation also occurs with mass spectrometric detection of reaction products and can cause problems with identification of the products. This problem can be exacerbated in the mass spectrometric detection of reaction products because diese internally excited molecules can have very different fragmentation patterns than themial molecules. The parent molecules associated with the various fragment ions can usually be sorted out by comparison of the angular distributions of the detected ions [8]. [Pg.2070]

The fragmentation patterns of 2-acetamido-5-nitrothia2oie (17) and 2-diraethylaminothiazole are reported to be characterized by the stabilization brought by the amino group to the thiazole ring (137). The proposed fragmentation scheme (Scheme 19) displays two major features,... [Pg.28]

The infrared spectra of a set of 2-thiazolylthioureas are reported in Ref. 486. The ultraviolet spectra of l-aryl-3-(2-thiazolyl)thioureas are characterized by two bands of approximate equal intensity around 282 and 332 nm (492). For l-alkyl-3-(2-thiazolyl)thioureas these bands are shifted to 255 and 291 nm, respectively (492). The shape of the spectrum is modified further when l.l -dialkyl-3-(2-thiazolyl)thioureas are considered (491). Fragmentation patterns of various 2-thiazolylthioureas have been investigated (100, 493), some of which are shown in Scheme 158. Paper and thin-layer chromatography provide an effective tool for the analysis of these heterocyclic thioureas (494. 495). [Pg.94]

Alkylidenehydrazinothiazoles (297) can be prepared either from 2-hydrazinothiazoles (549) or by direct heterocyclization (527). Their characteristic infrared bands have been reported (550). The main mass spectrometric peaks of (4-coumarinyl-2-thiazolyl)hydrazone (302) (Scheme 179) (134, 551) are situated at mle = 361. 244, 243, 118, 216, 202, 174, 117 the proposed interpretation of the fragmentation pattern should, however, be reconsidered. Scheme l80 summarizes some representative reactions of this class of compounds. [Pg.105]

Thiazole disulfides absorb at 235 and 258 nm (320-322) and characteristic infrared bands are reported in Ref. 320. The activities of 2-cyclo-hexyldithiomethylthiazoles as vulcanization accelerators have been correlated with their mass-spectral fragmentation patterns (322). [Pg.412]

The base peak in the mass spectrum of the LM free metal-ligand ion and the fragmentation patterns of this parent ion are of particuliar significance since they illustrate the effect of coordination upon the properties of the thiazole ligand. The free thiazole fragments upon electron impact by two major routes (Scheme 86 also cf. Section II. 6). [Pg.130]

The mass spectra of more substituted thiazoles, or those with larger alkyl groups are more complex and involve other fragmentation patterns (117, 118, 374). The molecular ion is still abundant but decreases with increasing substitution past the ethyl group. [Pg.348]

The spectra of alkylarylthiazoles generally possess fragmentation patterns similar to those previously mentioned for alkyl- and arylthiazoles. In this case, scission of the S-Cj and C3-C4 bonds of the thiazole ring can occur in ion fragments as well as in the molecular ion (124). [Pg.349]

The mass spectra of arylthiazoles with funcmonal substituents cm the benzene ring have also been studied (125, 126). They possess the fragmentation pattern of the aromatic derivative corresponding to the substituent together with that of the thiazole ring described previously (126). [Pg.349]

Although GGMS is the most widely used ana lytical method that combines a chromatographic sep aration with the identification power of mass spectrometry it is not the only one Chemists have coupled mass spectrometers to most of the mstru ments that are used to separate mixtures Perhaps the ultimate is mass spectrometry/mass spectrome try (MS/MS) m which one mass spectrometer gener ates and separates the molecular ions of the components of a mixture and a second mass spec trometer examines their fragmentation patterns ... [Pg.573]

Understanding how molecules fragment upon electron impact permits a mass spec trum to be analyzed m sufficient detail to deduce the structure of an unknown compound Thousands of compounds of known structure have been examined by mass spectrome try and the fragmentation patterns that characterize different classes are well docu mented As various groups are covered m subsequent chapters aspects of their fragmentation behavior under conditions of electron impact will be descnbed... [Pg.573]

As we have just seen interpreting the fragmentation patterns m a mass spectrum m terms of a molecule s structural units makes mass spectrometry much more than just a tool for determining molecular weights Nevertheless even the molecular weight can provide more information than you might think... [Pg.573]

Fragmentation pattern (Section 13 22) In mass spectrometry the ions produced by dissociation of the molecular ion... [Pg.1284]

Mass spectral fragmentation patterns of alkyl and phenyl hydantoins have been investigated by means of labeling techniques (28—30), and similar studies have also been carried out for thiohydantoins (31,32). In all cases, breakdown of the hydantoin ring occurs by a-ftssion at C-4 with concomitant loss of carbon monoxide and an isocyanate molecule. In the case of aryl derivatives, the ease of formation of Ar—NCO is related to the electronic properties of the aryl ring substituents (33). Mass spectrometry has been used for identification of the phenylthiohydantoin derivatives formed from amino acids during peptide sequence determination by the Edman method (34). [Pg.250]

The combined techniques of gas chromatography/mass spectrometry (gc/ms) are highly effective in identifying the composition of various gc peaks. The individual peaks enter a mass spectrometer in which they are analyzed for parent ion and fragmentation patterns, and the individual components of certain resoles are completely resolved. [Pg.300]

A simple fragmentation pattern is also characteristic for chloro-, methyl- and amino-pyridazines. Pyridazinone fragments by loss of carbon monoxide followed by loss of N2 (Scheme 2). [Pg.8]

A feature eommon to the pyrazine, quinoxaline and phenazine ring systems is their remarkable stability in the mass speetrometer and in all eases with the parent heterocyeles the moleeular ion is the base peak. In the ease of pyrazine, two major fragments are observed at mje 53 and 26, and these fragments are eonsistent with the fragmentation pattern shown in Seheme 1. [Pg.162]

For fV-methylpyrazoIe (99), the molecular ion of which is less intense than pyrazole (a common feature for methyl-substituted pyrazoles (67ZOR1540)), the fragmentation pattern involves the methyl group (Scheme 2). These results were established using H, C and N labelling studies. [Pg.202]

Electron impact mass spectrometry has been employed to study the fragmentation patterns of isoxazolylmethyl- and bis(isoxazolylmethyl)-isoxazoles and the results are in agreement with proposed pathways (79AC(R)8l). Electron impact studies of nitrostyryl isoxazole (6) show fragmentation in a variety of ways. The standard loss of NO2 from the molecular ion... [Pg.6]

The fragmentation pattern of isoxazoles on electron impact has been well studied. It has been used as an important tool for the structural assignment of isoxazoles obtained from the reaction of chromones with hydroxylamine 79MI41600, 77JOC1356). For example, the structures of the isoxazoles (387) and (388) were assigned on the basis of their fragmentation patterns. Ions at mje 121 (100%) and mje 93 (19.8%) were expected, and indeed observed, for the isoxazole (388), and an ion at mje 132 (39.5%>) was similarly predicted and observed for the isoxazole (387). [Pg.79]

The structures of the isoxazoles (393) were all consistent with their mass spectral fragmentation patterns. The reaction of hydroxylamine with 3-phenylchromone (394) gave exclusively 5-(o-hydroxyphenyl)isoxazole (395) (78ACH(97)69). [Pg.79]

The fragmentation patterns of relatively volatile derivatives of penicillins (e.g. benzyl-penicillin methyl ester) under electron impact (B-72MI51101) and chemical ionization (75MI51100) conditions have been described. For both techniques the primary fragmentation is that shown in Scheme 1. [Pg.302]

Nepeta (Lamiaceae) is a genus of perennial or annual herbs found in Asia, Europe and North Africa. About 250 species of Nepeta are reported of which, 67 species are present in Iran. Some species of this genus are important medicinal plants and their extracts have been used for medicinal purposes. Aerial parts of Nepeta sintenisii Bornm. was subjected to hydrodistillation and the chemical composition of isolated essential oil has been analyzed by GC/MS method for first time. Identification of components of the volatile oil was based on retention indices relative to n-alkanes and computer matching with the Wiley275.L library, as well as by comparison of the fragmentation patterns of the mass spectra with those reported in the literature. [Pg.232]

Figure 1 shows a positive static SIMS spectrum (obtained using a quadrupole) for polyethylene over the mass range 0—200 amu. The data are plotted as secondary ion intensity on a linear y-axis as a function of their chaige-to-mass ratios (amu). This spectrum can be compared to a similar analysis from polystyrene seen in Figure 2. One can note easily the differences in fragmentation patterns between the... Figure 1 shows a positive static SIMS spectrum (obtained using a quadrupole) for polyethylene over the mass range 0—200 amu. The data are plotted as secondary ion intensity on a linear y-axis as a function of their chaige-to-mass ratios (amu). This spectrum can be compared to a similar analysis from polystyrene seen in Figure 2. One can note easily the differences in fragmentation patterns between the...
A Brown and J. C. Vickerman. Surf. Interface Anal. 6,1, 1984. Describes interpretation of fragmentation patterns in static SIMS. [Pg.558]

Molecular orbital calculations indicate that cyclo C-18 carbyne should be relatively stable and experimental evidence for cyclocarbynes has been found [25], Fig. 3B. Diederich et al [25] synthesised a precursor of cyclo C-18 and showed by laser flash heating and time-of flight mass spectrometry that a series of retro Diels-Alder reactions occurred leading to cyclo C-18 as the predominant fragmentation pattern. Diederich has also presented a fascinating review of possible cyclic all-carbon molecules and other carbon-rich nanometre-sized carbon networks that may be susceptible to synthesis using organic chemical techniques [26]. [Pg.8]


See other pages where Fragmenting pattern is mentioned: [Pg.49]    [Pg.423]    [Pg.82]    [Pg.347]    [Pg.953]    [Pg.815]    [Pg.69]    [Pg.402]    [Pg.143]    [Pg.89]    [Pg.162]    [Pg.204]    [Pg.202]    [Pg.11]    [Pg.356]    [Pg.41]    [Pg.550]    [Pg.953]   
See also in sourсe #XX -- [ Pg.232 ]




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