Sulfatide fragmentation patterns

Hsu, P.-P., Bohrer, A. and Turk, J. (1998) Electrospray ionization tandem mass spectrometric analysis of sulfatide. Determination of fragmentation patterns and characterization of molecular species expressed in brain and in pancreatic islets. Biochim. Biophys. Acta 1392, 202-216. 

Sulfatide (3-sulfogalactosylceramide, ST) species can be readily ionized as deproto-nated species (i.e., [M-H] ) by ESI-MS in the negative-ion mode. The fragmentation pattern of deprotonated ST species after low-energy CID is well characterized [3,18] (Figure 8.3a) and contains the following features ... 

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