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Fourier transform control

The probes are assumed to be of contact type but are otherwise quite arbitrary. To model the probe the traction beneath it is prescribed and the resulting boundary value problem is first solved exactly by way of a double Fourier transform. To get managable expressions a far field approximation is then performed using the stationary phase method. As to not be too restrictive the probe is if necessary divided into elements which are each treated separately. Keeping the elements small enough the far field restriction becomes very week so that it is in fact enough if the separation between the probe and defect is one or two wavelengths. As each element can be controlled separately it is possible to have phased arrays and also point or line focussed probes. [Pg.157]

Pig. 4. Photo dissociation of ArHCl. Left hand side the number of force field evaluations per unit time. Right hand side the number of Fast-Fourier-transforms per unit time. Dotted line adaptive Verlet with the Chebyshev approximation for the quantum propagation. Dash-dotted line with the Lanczos iteration. Solid line stepsize controlling scheme based on PICKABACK. If the FFTs are the most expensive operations, PiCKABACK-like schemes are competitive, and the Lanczos iteration is significantly cheaper than the Chebyshev approximation. [Pg.408]

Chemical Gas Detection. Spectral identification of gases in industrial processing and atmospheric contamination is becoming an important tool for process control and monitoring of air quaUty. The present optical method uses the ftir (Fourier transform infrared) interference spectrometer having high resolution (<1 cm ) capabiUty and excellent sensitivity (few ppb) with the use of cooled MCT (mercury—cadmium—teUuride) (2) detectors. [Pg.295]

The same reversible appearance and disappearance of the Pt(lll)-(12xl2)-Na overlayer is shown in Figure 5.51, together with the corresponding two-dimensional Fourier-transform spectra and also in Fig. 5.52, which shows smaller areas of the sodium-free and sodium doped Pt(lll) surface. The reversible electrochemically controlled spillover/backspillover of sodium between the solid electrolyte and the Pt(lll) surface is clearly proven. [Pg.262]

Several commercial companies now offer process compatible NMR systems. These systems are either low resolution based on relaxation time measurements or high resolution Fourier Transform spectral measurements. The low resolution systems are manufactured by Process Control Technologies (www.pctnmr.com) and Progression, Inc. (www.progression-systems.com). Progression s systems... [Pg.482]

A modern spectrophotometer (UV/VIS, NIR, mid-IR) consists of a number of essential components source optical bench (mirror, filter, grating, Fourier transform, diode array, IRED, AOTF) sample holder detector (PDA, CCD) amplifier computer control. Important experimental parameters are the optical resolution (the minimum difference in wavelength that can be separated by the spectrometer) and the width of the light beam entering the spectrometer (the fixed entrance slit or fibre core). Modern echelle spectral analysers record simultaneously from UV to NIR. [Pg.301]

Radiofrequency spectroscopy (NMR) was introduced in 1946 [158,159]. The development of the NMR method over the last 30 years has been characterised by evolution in magnet design and cryotechnology, the introduction of computer-based operating systems and pulsed Fourier transform methods, which permit the performance of new types of experiment that control production, acquisition and processing of the experimental data. New pulse sequences, double-resonance techniques and gradient spectroscopy allow different experiments and have opened up the area of multidimensional NMR and NMRI. [Pg.323]

Another advantage of frequency response analysis is that one can identify the process transfer function with experimental data. With either a frequency response experiment or a pulse experiment with proper Fourier transform, one can construct the Bode plot using the open-loop transfer functions and use the plot as the basis for controller design.1... [Pg.146]

Spectra were obtained using a Digilab FTS-15E Fourier Transform Spectrophotometer. A NaCl crystal mounted in a heated cell (Model 018-5322 Foxboro/Analabs, N. Haven, Ct.) was placed in the infrared beam and the chamber allowed to purge for several minutes while the cell was brought to the desired temperature. The temperature of the cell was controlled using a DuPont 900 Differential Thermal Analyzer interfaced to the spectrometer cell. A chlorobenzene solution (ca. 10 by wt.) of the sample was then applied to the crystal using cotton tipped wood splint. [Pg.243]

Where is a convolution integral and FT is the Fourier transform. The phase-contrast imaging performance of an HRTEM is controlled by sin y, which contains the basic phase-contrast sinusoidal terms modified by an envelope... [Pg.205]

Figure 16 shows the experimental arrangement for the measurement of the surface pressure. The trough (200 mm long, 50 mm wide and 10 mm deep) was coated with Teflon. The subphase temperature was controlled within 0.1 C by means of a jacket connected to a thermostated water circulator, and the environmental air temperature was kept at 18 °C. The surface tension was measured with a Wilhelmy plate of platinum(24.5 x 10.0 x 0.15 mm). The surface pressure monitored by an electronic balance was successively stored in a micro- computer, and then Fourier transformed to a frequency domain. The surface area was changed successively in a sinusoidal manner, between 37.5 A2/molecule and 62.5 A2/molecule. We have chosen an unsaturated phospholipid(l,2-dioleoyl-3-sn-phosphatidyI-choline DOPC) as a curious sample to measure the dynamic surface tension with this novel instrument, as the unsaturated lipids play an important role in biomembranes and, moreover, such a "fluid" lipid was expected to exhibit marked dynamic, nonlinear characteristics. The spreading solution was 0.133 mM chloroform solution of DOPC. The chloroform was purified with three consecutive distillations. [Pg.243]

Always based on the use of IR spectrophotometry, a novel attenuated total reflection-Fourier-transform infrared (ATR-FTIR) sensor [42] was proposed for the on-line monitoring of a dechlorination process. Organohalogenated compounds such as trichloroethylene (TCE), tetrachloroethylene (PCE) and carbon tetrachloride (CT) were detected with a limit of a few milligrams per litre, after extraction on the ATR internal-reflection element coated with a hydro-phobic polymer. As for all IR techniques, partial least squares (PLS) calibration models are needed. As previously, this system is promising for bioprocess control and optimization. [Pg.261]

DRIFT spectra, acquiring, 24 111. See also Diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) Drilling, of hydrothermal wells, 12 525-527 Drilling fluid (drilling mud) companies, 9 2 Drilling fluid materials, 9 2, 9-25. See also Drilling fluids Drilling muds alkalinity control in, 9 19 barite, 9 9-10 calcite, 9 10... [Pg.289]

A computer carries out the Fourier transform calculations, performs various control functions and manipulates the data for display and interpretation. [Pg.35]

The infrared technique has been described in numerous publications and recent reviews were published by Davies and Giangiacomo (2000), Ismail et al. (1997) and Wetzel (1998). Very few applications have been described for analysis of additives in food products. One interesting application is for controlling vitamin concentrations in vitamin premixes used for fortification of food products by attenuated total reflectance (ATR) accessory with Fourier transform infrared (FTIR) (Wojciechowski et al., 1998). Four vitamins were analysed - Bi (thiamin), B2 (riboflavin), B6 (vitamin B6 compounds) and Niacin (nicotinic acid) - in about 10 minutes. The partial least squares technique was used for calibration of the equipment. The precision of measurements was in the range 4-8%, similar to those obtained for the four vitamins by the reference HPLC method. [Pg.130]

Carter RE Jr., Thomas MJ, Marotz GA, et al. 1992. Compound detection and concentration estimation by open-path Fourier transform infrared spectrometry and canisters under controlled field conditions. Environ Sci Technol 26(11 ) 2175-2181. [Pg.243]

The monotonic increase of immobilized material vith the number of deposition cycles in the LbL technique is vhat allo vs control over film thickness on the nanometric scale. Eilm growth in LbL has been very well characterized by several complementary experimental techniques such as UV-visible spectroscopy [66, 67], quartz crystal microbalance (QCM) [68-70], X-ray [63] and neutron reflectometry [3], Fourier transform infrared spectroscopy (ETIR) [71], ellipsometry [68-70], cyclic voltammetry (CV) [67, 72], electrochemical impedance spectroscopy (EIS) [73], -potential [74] and so on. The complement of these techniques can be appreciated, for example, in the integrated charge in cyclic voltammetry experiments or the redox capacitance in EIS for redox PEMs The charge or redox capacitance is not necessarily that expected for the complete oxidation/reduction of all the redox-active groups that can be estimated by other techniques because of the experimental timescale and charge-transport limitations. [Pg.64]


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See also in sourсe #XX -- [ Pg.232 ]




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