Flexible fibre material

Silver halide fibres (AgClxBri x) have the widest spectral range in the mid-IR, well into the fingerprint range. Due to their crystalline nature, they have a superior flexibility. Problematic is their tendency to decompose upon contact with UV radiation or base metals. Also sulphides will chemically destroy the fibre material. Other points against are the high intrinsic attenuation due to absorption by impurities or scattering at inclusions or micro-crystals and the non-availability of (applicable) core-clad fibres. 

Nature in its abundance offers us a lot of material that can be called fibrous fibres are found in plant leaves, fraits, seed covers and stalk. Fibres from these plants can be considered to be totally renewable and biodegradable. Bast fibres are soft, woody fibres obtained from stems of dicotyledonous plants (flowering plants with net-veined leaves). Such fibres, usually characterized by fineness and flexibility, are also known as soft fibres, distinguishing them from the coarser, less flexible fibres of the leaf, or hard , fibre group. This chapter will discuss bast fibres from flax, hemp, jute, ramie, kenaf and abaca. 

Bastiaansen, C.W.M. (1997) High-modulus and high-strength fibres based on flexible macromolecules, in Processing of Polymers, ed. Meijer, H.E.H. Materials Science and Technology, A Comprehensive Treatment, vol. 18, eds. Cahn, R.W., Haasen, P. and Kramer, E.J. (VCH, Weinheim) p. 551. 

Figure 12.30 Potential uses of polyphosphazenes (a) A thin film of a poly(aminophosphazene) sueh materials are of interest for biomedical applications, (b) Fibres of poly[bis(trifluoroethoxy)phosphazene] these fibres are water-repellant, resistant to hydrolysis or strong sunlight, and do not burn, (c) Cotton cloth treated with a poly(fluoroalkoxyphosphazene) showing the water repellaney eonferred by the phosphazene. (d) Polyphosphazene elastomers are now being manufaetured for use in fuel lines, gaskets, O-rings, shock absorbers, and carburettor eomponents they are impervious to oils and fuels, do not bum, and remain flexible at very low temperatures. Photographs by eourtesy of H. R. Allcock (Pennsylvania State University) and the Firestone Tire and Rubber Company.

Many other opportunities exist due to the enormous flexibility of the preparative method, and the ability to incorporate many different species. Very recently, a great deal of work has been published concerning methods of producing these materials with specific physical forms, such as spheres, discs and fibres. Such possibilities will pave the way to new application areas such as molecular wires, where the silica fibre acts as an insulator, and the inside of the pore is filled with a metal or indeed a conducting polymer, such that nanoscale wires and electronic devices can be fabricated. Initial work on the production of highly porous electrodes has already been successfully carried out, and the extension to uni-directional bundles of wires will no doubt soon follow. 

Often used nowadays in the sense of textile material, e.g., natural fibre, man-made fibre, but correctly it refers to the comparatively short thread (staple fibre) of natural textiles. A fibre is fine, flexible, and very long in relation to its thickness. 

The final main category of non-Newtonian behaviour is viscoelasticity. As the name implies, viscoelastic fluids exhibit a combination of ordinary liquid-like (viscous) and solid-like (elastic) behaviour. The most important viscoelastic fluids are molten polymers but other materials containing macromolecules or long flexible particles, such as fibre suspensions, are viscoelastic. An everyday example of purely viscous and viscoelastic behaviour can be seen with different types of soup. When a thin , watery soup is stirred in a bowl and the stirring then stopped, the soup continues to flow round the bowl and gradually comes to rest. This is an example of purely viscous behaviour. In contrast, with certain thick soups, on cessation of stirring the soup rapidly slows down and then recoils slightly. 

ISO 527-4 1997 Plastics - Determination of tensile properties - Part 4 Test conditions for isotropic and orthotropic fibre-reinforced plastic composites ISO 527-5 1997 Plastics - Determination of tensile properties - Part 5 Test conditions for unidirectional fibre-reinforced plastic composites ISO 1798 1997 Flexible cellular polymeric materials - Determination of tensile strength and elongation at break... 

Textile fibres like nylon and polyester are used to reinforce flexible materials such as soft PVC. 

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