Fission products natural reactors

The Natural Reactor. Some two biUion years ago, uranium had a much higher (ca 3%) fraction of U than that of modem times (0.7%). There is a difference in half-hves of the two principal uranium isotopes, U having a half-life of 7.08 x 10 yr and U 4.43 x 10 yr. A natural reactor existed, long before the dinosaurs were extinct and before humans appeared on the earth, in the African state of Gabon, near Oklo. Conditions were favorable for a neutron chain reaction involving only uranium and water. Evidence that this process continued intermittently over thousands of years is provided by concentration measurements of fission products and plutonium isotopes. Usehil information about retention or migration of radioactive wastes can be gleaned from studies of this natural reactor and its products (12). 

Computer sensitivity studies show that hole size strongly affects the fraction of fission products released from the containment. The failure location determines mitigation due to release into another building in which condensation and particulate removal occur. The quantity released depends on the time of containment fails relative to reactor vessel failure. If containment integrity is maintained for several hours after core melt, then natural and engineered mechanisms (e.g., deposition, condensation, and filtration) can significantly reduce the quantity and radioactivity of the aerosols released to the atmosphere. 

What convinces scientists that sustained fission once occurred at Oklo is the presence of characteristic fission products in the ore. Elements of mass numbers between 75 and 160 occur in the ore in larger amounts than elsewhere. Furthermore, mass analysis of the elements in Oklo ore shows that they are distributed in the characteristic pattern shown in Figure 22-12. This isotopic signature, which is not found in any other naturally occurring materials, is so characteristic that it has convinced most scientists that the ore deposits at Oklo once formed a huge nuclear reactor. 

High-energy radiation may be classified into photon and particulate radiation. Gamma radiation is utilized for fundamental studies and for low-dose rate irradiations with deep penetration. Radioactive isotopes, particularly cobalt-60, produced by neutron irradiation of naturally occurring cobalt-59 in a nuclear reactor, and caesium-137, which is a fission product of uranium-235, are the main sources of gamma radiation. X-radiation, of lower energy, is produced by electron bombardment of suitable metal targets with electron beams, or in a... 

In the year 2000, 15% of the world s electric power was produced by 433 nuclear power reactors 169 located in Europe, 120 in the United States, and 90 in the Far East. These reactors consumed 6,400 tons of fresh enriched uranium that was obtained through the production of 35,000 tons of pure natural uranium in 23 different nations the main purification step was solvent extraction. In the reactors, the nuclear transmutation process yielded fission products and actinides (about 1000 tons of Pu) equivalent to the amount of uranium consumed, and heat that powered steam-driven turbines to produce 2,400 TWh of electricity in 2000. 

The Oklo natural reactors in Gabon are the best natural analogues for assessing the geological behaviour of fission products and actinides (see also Gauthier-Lafaye et al. 2004). Elements that were compatible with the U ore structure were retained, whereas elements that... 

Maximum Release. The analytical model described above assumes that the liquid phase is completely stagnant. While this may be true in an ideal laboratory experiment where a small sample can be kept isothermal at a specified temperature, in large scale systems where non-isothermal conditions exist, both natural convection and molecular diffusion will contribute to mass transfer. This combined effect, which is often very difficult to assess quantitatively, will result in an increase in fission-product release rate. Therefore, in making reactor safety analyses, it is desirable to be able to estimate the maximum release under all possible conditions. 

We should not leave our discussion of nuclear reactors without mentioning the Oklo phenomenon. In 1972, French scientists analyzing uranium ore from the Oklo uranium mine in Gabon found ore that was depleted in 235U. Further investigation showed the presence of high abundances of certain Nd isotopes, which are formed as fission products. The relative isotopic abundances of these isotopes were very different from natural abundance patterns. The conclusion was that a natural uranium chain reaction had occurred 1.8 billion years ago. 

Tritium is present naturally in the atmosphere, but the amounts were increased greatly in the late 1950s and 1960s by production and testing of thermonuclear weapons. Tritium is also a fission product and activation product produced in power reactors. Releases occur from reactors and reprocessing plants. Its use will increase greatly if fusion power is developed. 

Analysis of the natural reactors at Oklo gives valuable information about the migration behaviour of fission products and actinides in the geosphere. Uranium and the lanthanides have been redistributed locally. Plutonium produced in the Oklo reactors did not move during its lifetime from the site of its formation 85-100% of the lanthanides, 75-90% of the Ru and 60-85% of the Tc were retained within the reactor zones. Small amounts of U, lanthanides, Ru and Tc moved with the water over distances of up to 20-50 m. 

When neutrons strike the nucleus of a large atom, they cause that nucleus to split apart into two roughly equal pieces known as fission products. In that process, additional neutrons and very large amounts of energy are also released. Only three isotopes are known to be fissionable, uranium-235, uranium-233, and plutonium-239. Of these, only the first, uranium-235, occurs naturally. Pluto-nium-239 is produced synthetically when nuclei of uranium-238 are struck by neutrons and transformed into plutonium. Since uranium-238 always occurs along with uranium-235 in a nuclear reactor, plutonium-239 is produced as a byproduct in all commercial reactors now in operation. As a result, it has become as important in the production of nuclear power as uranium-235. Uranium-233 can also be produced synthetically by the bombardment of thorium with neutrons. Thus far, however, this isotope has not been put to practical use in nuclear reactors. 

Deuterium is in very low concentration. Lithium has an atomic weight of 6.94 and the abundance of Li is around 7% in natural Li. The main reaction product of B is Li which does not generate but there are other, minor reactions that do. Except in boron steels, the activation of Li predominates. Another source of in fission reactors is the low yield, ternary fission of fuel (-130 x 10 atoms per fission product pair). In Magnox gas-cooled reactors, from ternary fission is mainly retained in the metallic uranium fuel and its cladding but some is released into the coolant circuits, where it may possibly diffuse into structures within the primary vessel. Tritium is a low energy /5 emitting radionuclide of low radio-toxicity and with a half life of 12.3 years. 

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