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Factor three-dimensional

These types of three-dimensional electrodes on microchips could also be used for a wider variety of biomethods, including electroporation, drug delivery, and electrostimulated cell culturing. Three-dimensional electrodes will also have applicability in laminar flow-based fuel cells and biofuel cells due to the increase in roughness factor. Three-dimensional electrode... [Pg.3331]

Iditional importance is that the vibrational modes are dependent upon the reciprocal e vector k. As with calculations of the electronic structure of periodic lattices these cal-ions are usually performed by selecting a suitable set of points from within the Brillouin. For periodic solids it is necessary to take this periodicity into account the effect on the id-derivative matrix is that each element x] needs to be multiplied by the phase factor k-r y). A phonon dispersion curve indicates how the phonon frequencies vary over tlie luin zone, an example being shown in Figure 5.37. The phonon density of states is ariation in the number of frequencies as a function of frequency. A purely transverse ition is one where the displacement of the atoms is perpendicular to the direction of on of the wave in a pmely longitudinal vibration tlie atomic displacements are in the ition of the wave motion. Such motions can be observed in simple systems (e.g. those contain just one or two atoms per unit cell) but for general three-dimensional lattices of the vibrations are a mixture of transverse and longitudinal motions, the exceptions... [Pg.312]

Example of a two-factor response surface displayed as (a) a pseudo-three-dimensional graph and (b) a contour plot. Contour lines are shown for intervals of 0.5 response units. [Pg.668]

Water-Holding Capacity (WHC). AU polysaccharides are hydrophilic and hydrogen bond to variable amounts of water. HydratabUity is a function of the three-dimensional stmcture of the polymer (11) and is kifluenced by other components ki the solvent. Fibrous polymers and porous fiber preparations also absorb water by entrapment. The more highly crystalline fiber components are more difficult to hydrate and have less tendency to sweU. Stmctural features and other factors, including grinding, that decrease crystallinity or alter stmcture, may iacrease hydratioa capacity and solubUity. [Pg.70]

Thus the promoting vibrations reduce the Franck-Condon factor itself, which is not reflected in the spin-boson model (5.55), (5.67). As an illustration, three-dimensional trajectories for various interrelations between symmetric (Ws) and antisymmetric (oja) vibration frequencies, and odo are shown in fig. 33. [Pg.91]

We know much more about factors that influence the stability of the native state, mainly from experiments using directed mutations in proteins of known three-dimensional structure. Such experiments have yielded... [Pg.90]

Eucaryotes have many more genes and a broader range of specific transcription factors than procaryotes and gene expression is regulated by using sets of these factors in a combinatorial way. Eucaryotes have found several different solutions to the problem of producing a three-dimensional scaffold that allows a protein to interact specifically with DNA. In the next chapter we shall discuss some of the solutions that have no counterpart in procaryotes. However, the procaryotic helix-turn-helix solution to this problem (see Chapter 8) is also exploited in eucaryotes, in homeodomain proteins and some other families of transcription factors. [Pg.159]

A comparative study on ylide stability as a function of the heteroatom type was carried out by Doering et al. [3,4]. They concluded that the phosphorus and sulfur ylides are the most stable ones. The participation of three-dimensional orbitals in the covalency determines the resonance stabilization of the phosphorus and sulfur ylides [5-8]. The nitrogen ylides are less stable from this point of view. The only stabilization factor involves electrostatic interactions between the two charges localized on adjacent nitrogen and carbon atoms [9]. [Pg.374]

Heat transfer in the furnace is mainly by radiation, from the incandescent particles in the flame and from hot radiating gases such as carbon dioxide and water vapor. The detailed theoretical prediction of overall radiation exchange is complicated by a number of factors such as carbon particle and dust distributions, and temperature variations in three-dimensional mixing. This is overcome by the use of simplified mathematical models or empirical relationships in various fields of application. [Pg.347]

The two isozymes are both homodimers, composed of approximately 600 amino acids and possess approximately 60% homology. The three-dimensional structures of COX-1 and COX-2 are very similar. Each one consists of three independent units an epidermal growth factor-like domain, a membrane-binding section and an enzymic domain. The catalytic sites and the residues immediately adjacent are identical but for two small but crucial variations that result in an increase in the volume of the COX-2-active site, enabling it to accept inhibitor-molecules larger than those that could be accommodated in the COX-1 molecule. [Pg.404]

These tensors are transversal in the four-dimensional sense in each index by virtue of the three-dimensional transversality of the tensors T. .in. The factor Vifel0- -kM is introduced so that the norm of T) will become... [Pg.574]

Figure 9.39. View factors for three-dimensional geometries 45... Figure 9.39. View factors for three-dimensional geometries 45...
Interconnect. Three-dimensional structures require interconnections between the various levels. This is achieved by small, high aspect-ratio holes that provide electrical contact. These holes include the contact fills which connect the semiconductor silicon area of the device to the first-level metal, and the via holes which connect the first level metal to the second and subsequent metal levels (see Fig. 13.1). The interconnect presents a major fabrication challenge since these high-aspect holes, which may be as small as 0.25 im across, must be completely filled with a diffusion barrier material (such as CVD titanium nitride) and a conductor metal such as CVD tungsten. The ability to fill the interconnects is a major factor in selecting a thin-film deposition process. [Pg.349]

The abrasion loss as log (abrasion) of log (energy) and log (speed) is best presented either in tabular form filling out the table of Figure 26.67 or as a three-dimensional graph [52] as shown in Figure 26.68. Notice that the abrasion between the mildest condition (upper left) and the most severe condition (lower right) differs by a factor of about 1000. More important for practical use is the relative rating of an experimental compound to a standard reference compound. [Pg.740]


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