Ethylene imines

Ethylene imine Hydrazine hydrate Hydrogen sulfide. Hydroxylamme salts Inorganic Hg. compounds lodates Iodides... 

The chapter is divided into three sections, devoted to the discussion of the synthesis of (1) oxiranes (epoxides), (2) aziridines (ethylene imines) and (3) thiiranes (episulfides). 

A related enamine alkylation is seen in the rearrangement of an ethylene imine vinylogous amide, which was heated with sodium iodide in diglyme. The presumed internal enamine alkylation constitutes a critical step in an oxocrinane synthesis (265). Use of an ethylene imine urethane for alkylation of an enamine and formation of the hexahydroindole system has also been reported (266). 

Perhydropyrido[l,2- ]pyrazin-l-one was prepared in the reaction of methyl pipecolinate and ethylene imine in boiling EtOH <19951JSP5461047>. Cyclocondensation of ethyl 2-amino-2-(2-pyridyl)acetate with DMAD, followed by treatment of reaction mixture with NaOMe, gave the 2-(l-methoxycarbonyl)-4-oxo-47/-pyrido[l,2- ]pyrazin-3-yl)acetate <1996JHC639>. 

Merdan T, Kunath K, Petersen H, Bakowsky U, Voigt KH, Kopecek J, Kissel T (2005) PEGylation of poly(ethylene imine) affects stability of complexes with plasmid DNA under in vivo conditions in a dose-dependent manner after intravenous injection into mice. Bioconjug Chem 16 785-792... 

Neu M, Germershaus O, Mao S, Voigt KH, Behe M, Kissel T (2007) Crosslinked nanocarriers based upon poly(ethylene imine) for systemic plasmid delivery in vitro characterization and in vivo studies in mice. J Control Release 118 370-380... 

Synonyms AI3-50324 Aminoethene Aminoethylene Azacyclopropane Azirane Aziridine BRN 0102380 CCRIS 296 Dihydroazirene Dihydro-l//-azirene Dihydro-l//-azirine Dihydro-azirine Dimethyleneimine Dimethylenimine El EINECS 205-793-9 ENT 50324 Ethylene-imine Ethylimine Montrek 6 NSC 124034 NSC 124035 NSC 124036 NSC 134422 NSC 196335 P-1000 PEI PEI-600 PEI-1400 PEI-1500 PEI-2750 Polymine P RCRA waste number P054 TL 337 Tydex 12 UN 1185. 

In a system devised to oxidize a dye, glucose oxidase and horseradish peroxidase were coassembled by layer-by-layer alternative adsorption to construct multienzyme films. The peroxidase was adsorbed to poly(styrene sulfonate) while glucose oxidase was adsorbed to poly(ethylene imine), allowing for sequential redox reactions to take place resulting in the subsequent oxidation of the textile dye DA67 [71]. 

Garpenter GP, Smyth HF Jr, Shaffer GB The acute toxicity of ethylene imine to small animals. J Ind Hyg Toxicol 30 2-6, 1948... 

A variety of methods for immobilizing polymerized liposomes have been reported. Multiple layers of vesicles were deposited on quartz slides by layer-by-layer assembly (Su 2005). The slides were first coated with a layer of poly(ethylene imine), a... 

In contrast, similar examination of the product obtained by template polymerization of acrylic acid on poly(ethylene imine), using electrophoresis, leads to the conclusion that in this case graft copolymer is absent. 

Paper chromatography was also used to separate the complex obtained by polymerization of acrylic acid in the presence of poly(ethylene imine). In this case, both the complex obtained by mixing of two polymers and the complex obtained in template polymerization gave two distinct spots. No trace was found of any graft copolymer. 

An addition graft copolymerization is the reaction of /9-propiolactone with cellulose, which has been extensively studied by Daul, Reinhardt, and Reid [138). In a similar reaction cellulose adds ethylene imine, as shown by work by Cooper, and Smith (139), and ethylene or propylene sulfide, as described by Champetier (140). Also the well known hydroxy-ethylation of cellulose by reaction with ethylene oxide belongs to this class of reactions. 

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