Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Ethylamine hydrogenation

Chloroethy I )-theophy II ine Qi-Methyl-)S ihenyl ethylamine Hydrogen chloride... [Pg.624]

Bromo-4 -benzyloxypropiophenone 2-(4-Methoxyphenyl)ethylamine Hydrogen bromide... [Pg.1361]

Aluminum chloride anhydrous Aniline Ethylamine Hydrogen Sodium carbonate Sulfur Trifluoromethane sulfonic acid petroleum refining additive Hexyloxypropylamine ... [Pg.5515]

Schatzmann, in 1891, tried to prepare 2-thiazolines by hydrogenation of thiazoles and by the action of sodium and ethanol on 2,4-dimethyl-thiazole, 2-methylthiazole, and 2-methyl-4-phenylthiazole (476). None of these substrates was reduced to thiazoline the second gave no reaction and the first underwent ring cleavage, leading to a mixture of n-propylmercaptan and ethylamine (Scheme 90). Three years later the same... [Pg.132]

Ethylamines. Mono-, di-, and triethylamines, produced by catalytic reaction of ethanol with ammonia (330), are a significant outlet for ethanol. The vapor-phase continuous process takes place at 1.38 MPa (13.6 atm) and 150—220°C over a nickel catalyst supported on alumina, siUca, or sihca—alumina. In this reductive amination under a hydrogen atmosphere, the ratio of the mono-, di-, and triethylamine product can be controlled by recycling the unwanted products. Other catalysts used include phosphoric acid and derivatives, copper and iron chlorides, sulfates, and oxides in the presence of acids or alkaline salts (331). Piperidine can be ethylated with ethanol in the presence of Raney nickel catalyst at 200°C and 10.3 MPa (102 atm), to give W-ethylpiperidine [766-09-6] (332). [Pg.415]

When diazomethane is slowly added to excess lactam, the anions formed can interact with unreacted lactam by means of hydrogen bonds to form ion pairs similar to those formed by acetic acid-tri-ethylamine mixtures in nonpolar solvents. The methyldiazonium ion is then involved in an ion association wdth the mono-anion of a dimeric lactam which is naturally less reactive than a free lactam anion. The velocity of the Sn2 reaction, Eq. (7), is thus decreased. However, the decomposition velocity of the methyldiazonium ion, Eq. (6a), is constant and, hence, the S l character of the reaction is increased which favors 0-methylation. It is possible that this effect is also involved in kinetic dependence investigations have shown that with higher saccharin concentrations more 0-methylsaccharin is formed. [Pg.267]

The starting material was produced by the reaction of furfural with ethylamine followed by hydrogenation to give N-ethyl-N-(2-tetrahydrofurfuryl)amine. Treatment of that material with hydrogen bromide in acetic acid gives N-ethyl-3i3iperidinol. [Pg.1246]

A molecule of ethylamine is made up of two carbon atoms, seven hydrogen atoms, and one nitrogen atom. [Pg.47]

Benz[l,2-e][l,3]oxazin[3,4-a]azepin-6-one (15) is cleaved rapidly in cold ethereal ethylamine to /V.A-diethyl-2-(2-hydroxyphcnyl)-l//-azepinc-1-carboxamide (90% mp 121 -122°C), whereas acidic hydrolysis yields the intramolecularly hydrogen bonded 2-(2-hydro-xyphenyl)-3//-azepine (16).156... [Pg.171]

To a mixture of vinyl bromide (40 mmol) and the catalyst dichloro-[(R)-Af,N-dimethyl-l-[(.S)-2-(diphenylphosphino)ferrocenyl]ethylamine]-palladium(n) (0.2 mmol) was added an ethereal solution of [a-(trimethyl-silyl)benzyl]magnesium bromide (0.6-1 m, 80 mmol) at —78 °C. The mixture was stirred at 30 °C for 4 days, and then cooled to 0 °C and hydrolysed with dilute aqueous HC1 (3 m). The organic layer was separated, and the aqueous layer was re-extracted with ether. The combined organic extracts were washed with saturated sodium hydrogen carbonate solution and water, and dried. Concentration and distillation gave the chiral allylsilane (79%, 66% ee), b.p. 55°C/0.4mmHg. [Pg.110]

Results. In the past two years we have undertaken a high pressure examination of the ion-molecule reactions occurring in a series of polar molecules—namely, methylamine, methanol, ethylamine, and ethanol (3). In all cases, the major secondary ion is the (parent +1) ion and in the first two cases, it is the only secondary ion. All hydrogenic primary ions undergo the general reaction,... [Pg.142]

The use of the triphenylphosphine-carbon tetrachloride adduct for dehydration reactions appears to be a very simple way of synthesizing nitriles from amides, carbodi-imides from ureas, and isocyanides from monosubstituted formamides. All of these reactions involve the simultaneous addition of triphenylphosphine, carbon tetrachloride, and tri-ethylamine to the compound to be dehydrated. The elimination of the elements of water is stepwise. An adduct, e.g. (46), is first formed, chloroform being eliminated, which decomposes to produce hydrogen chloride and the dehydrated product. [Pg.10]

An attractive alternative to these novel aminoalcohol type modifiers is the use of 1-(1-naphthyl)ethylamine (NEA, Fig. 5) and derivatives thereof as chiral modifiers [45-47]. Trace quantities of (R)- or (S)-l-(l-naphthyl)ethylamine induce up to 82% ee in the hydrogenation of ethyl pyruvate over Pt/alumina. Note that naphthylethylamine is only a precursor of the actual modifier, which is formed in situ by reductive alkylation of NEA with the reactant ethyl pyruvate. This transformation (Fig. 5), which proceeds via imine formation and subsequent reduction of the C=N bond, is highly diastereoselective (d.e. >95%). Reductive alkylation of NEA with different aldehydes or ketones provides easy access to a variety of related modifiers [47]. The enantioselection occurring with the modifiers derived from NEA could be rationalized with the same strategy of molecular modelling as demonstrated for the Pt-cinchona system. [Pg.58]

An anti addition of hydrogen atoms to the triple bond occurs when alkynes are reduced with lithium or sodium metal in ammonia or ethylamine at low temperatures. [Pg.310]


See other pages where Ethylamine hydrogenation is mentioned: [Pg.1246]    [Pg.619]    [Pg.624]    [Pg.1361]    [Pg.191]    [Pg.1246]    [Pg.619]    [Pg.624]    [Pg.1361]    [Pg.191]    [Pg.165]    [Pg.166]    [Pg.167]    [Pg.10]    [Pg.82]    [Pg.545]    [Pg.819]    [Pg.239]    [Pg.619]    [Pg.2]    [Pg.47]    [Pg.146]    [Pg.264]    [Pg.177]    [Pg.204]    [Pg.43]    [Pg.135]    [Pg.174]    [Pg.447]    [Pg.41]    [Pg.36]    [Pg.145]    [Pg.320]    [Pg.138]    [Pg.24]    [Pg.59]    [Pg.1352]    [Pg.8]    [Pg.24]    [Pg.152]   
See also in sourсe #XX -- [ Pg.444 , Pg.508 , Pg.595 ]




SEARCH



Ethylamines

© 2024 chempedia.info