Ethyl linalyl acetate

Dimethyl-3-(1-ethoxyethoxy)-1,6-octadiene. See Acetaldehyde ethyl linalyl acetal 1 -(1,1 -Dimethyl ethoxy-2-methylethoxy)-2-propanol. See Dipropylene glycol t-butyl ether 1 -(1,1 -Dimethylethoxy)-2-propanol. See Propylene glycol t-butyl ether Dimethylethoxysilane CAS 14857-34-2... 

Elicrisina. See Everlasting (Helichrysum italicum) extract Eliminox. See Catalase Elintaal. See Acetaldehyde ethyl linalyl acetal Elite 5100, Elite 5110, Elite 5200, Elite 5210, Elite 5220 Elite 5400, Elite 5600. See Polyethylene... 

Ethoxyethoxy)-3,7-dimethyl-1,6-octadiene. See Acetaldehyde ethyl linalyl acetal... 

Ethyl linalyl acetate. See Homolinalyl acetate Ethyl linoleate... 

Acetaldehyde ethyl linalyl acetal Butyl 2-decenoate Citral diethyl acetal Citronellyl butyrate Citronellyl isobutyrate Isodecyl methacrylate Rhodinyl butyrate Tetramethyl decynediol C14H26O4 Decyl succinate Dibutyl adipate Diethyl sebacate Diisobutyl adipate Glyceryl undecylenate Mono (2-ethylhexyl) adipate C14H26O6 Sorbitan caprylate... 

Terpinyl acetate in the absence of esters of high molecular weight, or ethyl esters of the fatty acids of coconut oil, is indicated by a difference to be observed in the apparent ester value by different times of saponification. This ester is far more resistant to the action of caustic alkali than is linalyl acetate, and requires two hours at least for complete saponification. Hence, if the oil shows a difference in the saponification value in thirty minutes and in two hours, which amounts to more than from 1 to 2, terpinyl acetate is almost certainly present. The following table shows the effect of this partial-saponrfication on the two esters and on adulterated oils —... 

Flowery Anisyl alcohol Benzyl acetate, phenylaceiate Cinnamic acid Cinnamyl acetate Citronellyl formate Crcsyl acetate Decanal Dimethyl benzyl carbinol Dimethyl benzyl carbinyl acetate Ethyl anthranilate Geranyl acetate Hydroxycitronellal dimethyl acetate Linalool Linalyl acetate Methyl benzoate Pcnethyl acetate 2-Phcnylpropionaldehyde 3-Phenylpropionaldehvde. 

Linalool Ethyl linalool Rosewood T etrahydrolinalool Dimetol Linalyl acetate... 

Ethyl acetate, which is a comparatively small molecule, has the typical fruity character associated with all the lower esters, and a more or less equal balance between the influence of the two structural units, derived from ethyl alcohol and acetic acid. Linalyl acetate and geranyl acetate, however, although retaining the typical character of an acetate have much less of the ester fruitiness and are more closely related to the corresponding alcohols, linalool, and geraniol. The dominance of the alcohol appears to be even greater in phenylethyl acetate and paracresyl acetate (a phenolic ester). 

Hexyl butanoate Butyl hexanoate Fenchyl acetate Menthyl acetate a-Terpinyl acetate Bornyl acetate Isobornyl acetate Linalyl acetate Citronellyl isobutyrate Phenethyl formate Anisyl formate Ethyl salicylate Pentyl salicylate isoamyl Salicylate hexyl Salicylate... 

Esters, such as ethyl acetate, linalyl acetate, ethyl phenyl acetate, and methyl dihydrojasmonate... 

Lime (Citrus aurantifolia) oil Linalyl acetate extruded components Ethylene/ethyl acrylate copolymer extruded goods... 

Lavender oil has been reported to contain more than 100 components, including linalool, linalyl acetate, lavandulyl acetate, terpinen-l-ol-4, 1,8-cineole, camphor, 3-phellandrene, terpinolene, a-thujene, n-hexanal, n-heptanal, methyl amyl ketone, ethyl amyl ketone, perillaldehyde, perillyl alcohol, r/-bomeol, a-terpineol, a-pinene, limonene, lactones (4-butanolide, dihydrocoumarin, 4-methyl-4-vinyl-4-butanolide, 5-pentyl-5-pentanolide, 4,4-dimethyl-2-buten-4-olide, etc.), sesquiterpenes (caryophyllene, cadinene, etc.), fatty acids (propionic acid, isobutyric acid, caproic acid, p-coumaric acid, etc.), and others (list and horhammer). " ... 

Main components include linalol, linalyl acetate (30-35%), camphene, pinene, traces of - camphor and ethyl-n-amyl-ketone. 

The acetates of most alcohols are also commercially available and have diverse uses. Because of their high solvent power, ethyl, isopropyl, butyl, isobutyl, amyl, and isoamyl acetates are used in ceUulose nitrate and other lacquer-type coatings (see Cellulose, esters). Butyl and hexyl acetates are exceUent solvents for polyurethane coating systems (see Coatings Urethane polymers). Ethyl, isobutyl, amyl, and isoamyl acetates are frequentiy used as components in flavoring (see Flavors and spices), and isopropyl, benzyl, octyl, geranyl, linalyl, and methyl acetates are important additives in perfumes (qv). 

Fntity Benzyl propionate Butyl acetate Cinnamyl anthranilate. formate Citronellyl acelate. butyrate, isobutyrate. propionate, Delta-decalactone Diethyl malunate Dimethylbenzyl carbinyl acetate Delta-dodecalactone Ethyl p-anlsate. benzoate, butyrate, heptanoate, hexanoate. maltol. nonanoate Isoamyl butyrate, hexanoate. isovalerate, cinnamate Linalyl isobutyrate. propionate Mallol Methyl benzoate, cinnamate 2-Methyl-undecanal, Nerohdol Octanol. Octyl formaie Phencthyl isobuiyrate. isovalerate gamma- Indecalactone. 

Honey Allyl phenoxyacetate, phenylaceiate Benzyl cinnamate Carvacryl acetate Cinnamyl butyrate p-Cresyl acetate p-Cresyl ethyl ether /rt-Cresyl phenylaceiate />-Cresyl phenylaceiate Cyclohexyl phenylacctate Ethyl phenoxyacetate. phenylaceiate Guaiol phenylaceiate Isobutyl phenylaceiate Linalyl butyrate Methyl phenylaceiate Phenethyl acetate, butyrate, phenylaceiate Phenylacetic acid Propyl phenylaceiate Santalyl phenylaceiate. 

Figure 5.4 GC-MS total ion current (TIC) chromatogram of a red Italian wine (Corvina) after HS- SPME automated aroma enrichment using a 1 cm CAR-PDMS-DVB fiber. 1. ethyl acetate, 2. ethanol, 3. isobutyl alcohol, 4. isoamyl acetate, 5. isoamyl alcohols, 6. ethyl hexanoate, 7. methyl heptanoate (I.S.), 8. linalyl ethylether, 9. 1-hexanol, 10. ethyl octanoate, 11. acetic acid, 12. geranyl ethylether, 13. linalool, 14. ethyl decanoate, 15. diethylsuccinate, 16. ethyl 9-decenoate, 17. 2-phenethyl acetate, 18. hexanoic acid, 19. 2-phenylethanol, 20. octanoic acid, 21. decanoic acid...

CIC The weak juicy flavour is based on geraniol, geranyl acetate and neryl acetate in combination with linalyl ethyl ether and myrcenyl ethyl ether. The cold pressed peel oil has a high terpene content. Its flavour is dominated by citral, gamma-terpinene and alpha-pinene. Citral is recognized as a very important contributor to the fresh lemon character, although it decomposes within a few weeks in acidic soft drinks. 

---