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Esters, carboxylic acid phenolic

In most scenarios, the interaction proceeds in steps, i.e., equilibrium solution represents the mixture of heteroassociates of different stoichiometry AB, ABj, AjB, etc. Systems formed by 0-, S-, N-, P-bases with various H-donors (e.g., amines-carboxylic acids, esters-carboxylic acids (phenols), dimethylsulfoxide-carboxylic acid) refer to this type of interaction. [Pg.507]

Proton donors alcohols, carboxylic acids, phenols, and chloroform Proton acceptors amines, ethers, sulfoxides, amides, esters, and alcohols... [Pg.554]

C-O O-H Alcohols, ethers, esters, carboxylic acids, anhydrides Alcohols, phenols 1300-1000 7.69-10.0 s... [Pg.304]

Typical analyses include the detection and determination of paraffins, aromatics, olefins, acetylenes, aldehydes, ketones, carboxylic acids, phenols, esters, ethers, amines, sulfur compounds, halides, and so on. From the IR spectrum, it is possible to distinguish one polymer from another or determine the composition of mixed polymers or identify the solvents in paints. Atmospheric pollutants can be identified while still in the atmosphere. Another interesting application is the examination of old paintings and artifacts. It is possible to identify the varnish used on the painting and the textile comprising the canvas, as well as the pigments in the paint. From this information. [Pg.287]

Carbohydrates and glycosides Aldehydes, ketones and related con unds Quinones Carboxylic acids Phenols and enols Esters, lactones and acid anhydrides of carboxylic acids Alcohols Ethers Hydrocarbons... [Pg.45]

Fischer esterification m which a phenol and a carboxylic acid condense m the pres ence of an acid catalyst is not used to prepare aryl esters... [Pg.1006]

Trimethylsilyl trichloroacetate, K2CO3, 18-crown-6, 100-150°, 1-2 h, 80-90% yield.This reagent silylates phenols, thiols, carboxylic acids, acetylenes, urethanes, and /3-keto esters, producing CO2 and chloroform as byproducts. [Pg.71]

The most common impurities are the corresponding acid and hydroxy compound (i.e. alcohol or phenol), and water. A liquid ester from a carboxylic acid is washed with 2N sodium carbonate or sodium hydroxide to remove acid material, then shaken with calcium chloride to remove ethyl or methyl alcohols (if it is a methyl or ethyl ester). It is dried with potassium carbonate or magnesium sulfate, and distilled. Fractional distillation then removes residual traces of hydroxy compounds. This method does not apply to esters of inorganic acids (e.g. dimethyl sulfate) which are more readily hydrolysed in aqueous solution when heat is generated in the neutralisation of the excess acid. In such cases, several fractional distillations, preferably under vacuum, are usually sufficient. [Pg.64]

Solid esters are easily crystallisable materials. It is important to note that esters of alcohols must be recrystallised either from non-hydroxylic solvents (e.g. toluene) or from the alcohol from which the ester is derived. Thus methyl esters should be crystallised from methanol or methanol/toluene, but not from ethanol, n-butanol or other alcohols, in order to avoid alcohol exchange and contamination of the ester with a second ester. Useful solvents for crystallisation are the corresponding alcohols or aqueous alcohols, toluene, toluene/petroleum ether, and chloroform (ethanol-free)/toluene. Esters of carboxylic acid derived from phenols... [Pg.64]

The respective amide was prepared from 7-substituted 5-oxo-2,3-dihydro-5//-pyrido[l,2,3-de]-l,4-benzoxazine-6-carboxylic acids via acid chlorides with different benzylamines (00M1P3). 6-Carboxamides were N-benzylated, and a side-chain phenolic hydroxy group was O-alkylated. 7-Aryl-5-oxo-2,3-dihydro-5//-pyrido[l, 2,3-r/e]-1,4-benzoxazine-6-carboxylic acid was obtained from the ethyl ester by alkalic hydrolysis. [Pg.277]

Phenolic esters (1) of aliphatic and aromatic carboxylic acids, when treated with a Lewis acid as catalyst, do undergo a rearrangement reaction to yield ortho- and para-acylphenols 2 and 4 respectively. This Fries rearrangement reaction is an important method for the synthesis of hydroxyaryl ketones. [Pg.126]

This procedure provides a convenient method for the esterification ol a wide variety of carboxylic acids. The reaction proceeds smoothly with sterically hindered acids6 and with acids which contain various functional groups. Esters are obtained in high purity using Kugelrohr distillation as the sole purification technique. In cases where traces of dichloromethane present no problems, the crude product is usually pure enough to be used directly in subsequent reactions. Methyl and ethyl ethers of phenols may also be prepared by this procedure (see Note 8). [Pg.62]

Phenolic compounds are weaker nucleophiles and better leaving groups than aliphatic alcohols. They do not yield polyesters when reacted with carboxylic acids or alkyl carboxy lates. The synthesis of polyesters from diphenols is, therefore, generally carried out through the high-temperature carboxylic acid-aryl acetate or phenyl ester-phenol interchange reactions with efficient removal of reaction by-product (Schemes 2.10 and 2.11, respectively). [Pg.62]


See other pages where Esters, carboxylic acid phenolic is mentioned: [Pg.227]    [Pg.484]    [Pg.91]    [Pg.242]    [Pg.260]    [Pg.543]    [Pg.654]    [Pg.183]    [Pg.4890]    [Pg.591]    [Pg.41]    [Pg.422]    [Pg.133]    [Pg.406]    [Pg.397]    [Pg.170]    [Pg.238]    [Pg.1031]    [Pg.663]    [Pg.76]    [Pg.322]    [Pg.61]    [Pg.64]    [Pg.126]   
See also in sourсe #XX -- [ Pg.603 , Pg.666 , Pg.794 , Pg.800 ]

See also in sourсe #XX -- [ Pg.603 , Pg.666 , Pg.794 , Pg.800 ]




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Acidic phenols

Phenol acidity

Phenol acids

Phenol carboxylation

Phenol carboxylic acids

Phenol esters

Phenolic acid esters

Phenolic acidity

Phenolic acids

Phenolic esters

Phenolics phenolic acids

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