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Energy level alignment

Fig. 1 Schematics of a typical metal-molecule-metal junction and energy level alignment... Fig. 1 Schematics of a typical metal-molecule-metal junction and energy level alignment...
Ishii H, Seki K (1997) Energy level alignment at organic/metal interfaces studied by UV photoemission breakdown of traditional assumption of a common vacuum level at the interface. Trans Electron Devices 44 1295-1301... [Pg.213]

H. Ishii, K. Sugiyama, E. Ito, and K. Seki, Energy level alignment and interfacial electronic structures at organic-metal and organic-organic interfaces, Adv. Mater., 11 605-625 (1999). [Pg.395]

Intensive effort has been devoted to the optimization of CCP structures for improved fluorescence output of CCP-based FRET assays. The inherent optoelectronic properties of CCPs make PET one of the most detrimental processes for FRET. Before considering the parameters in the Forster equation, it is of primary concern to reduce the probability of PET. As the competition between FRET and PET is mainly determined by the energy level alignment between donor and acceptor, it can be minimized by careful choice of CCP and C. A series of cationic poly(fluorene-co-phenylene) (PFP) derivatives (IBr, 9, 10 and 11, chemical structures in Scheme 8) was synthesized to fine-tune the donor/acceptor energy levels for improved FRET [70]. FI or Tex Red (TR) labeled ssDNAg (5 -ATC TTG ACT ATG TGG GTG CT-3 ) were chosen as the energy acceptor. The emission spectra of IBr, 9, 10 and 11 are similar in shape with emission maxima at 415, 410, 414 and 410 nm, respectively. The overlap between the emission of these polymers and the absorption of FI or TR is thus similar. Their electrochemical properties were determined by cyclic voltammetry experiments. The calculated HOMO and LUMO... [Pg.430]

Sohn, Y. and White, J.M. (2007) Phenyl isocyanide on Cu(lll) bonding and interfadal energy level alignment. J. Phys. Chem. C, 111, 7816-25. [Pg.555]

Figure 4.33. (a) Sketch of the basic construction of an OLED. (b) Schematic diagram showing the energy-level alignment for the OLED ITO/CuPc/NPB/Alqs/Mg. Adapted from Lee et al, 1999. [Pg.201]

Koch N, Elschner A, Johnson RE, Rabe JP (2005) Energy level alignment at interfaces with pentacene metals versus conducting polymers. Appl Surf Sci 244 593... [Pg.65]

Wang ZB, Helander MG, Greiner MT, Qiu J, Lu ZH (2009) Energy-level alignment and charge injection at metal/Cgo/organic interfaces. Appl Phys Lett 95 043302... [Pg.65]

Fehse K, Olthof S, Walzer K, Leo K, Johnson RL, Glowatzki H, Broker B, Koch N (2007) Energy level alignment of electrically doped hole transport layers with transparent and conductive indium tin oxide and polymer anodes. J Appl Phys 102 073719... [Pg.65]

Popinciuc M, Jonkman HT, van Wees BJ (2006) Energy level alignment symmetry at Co/pentacene/Co interfaces. J Appl Phys 100 093714... [Pg.300]

Zhan YQ, de Jong MP, Li EH, Dediu V, Fahlman M, Salaneck WR (2008) Energy level alignment and chemical interaction at Alqa/Co interfaces for organic spintronics devices. Phys Rev B 78 045208... [Pg.300]

Scheme 5.8 Energy level alignment of bulk heterojunction components (conjugated polymer and semiconductor nanocrystals) facilitating the dissociation of excitons and charge separation. Left panel Case describing excitons formed in the nanocrystal phase. Right panel case describing excitons formed in the polymer phase. Scheme 5.8 Energy level alignment of bulk heterojunction components (conjugated polymer and semiconductor nanocrystals) facilitating the dissociation of excitons and charge separation. Left panel Case describing excitons formed in the nanocrystal phase. Right panel case describing excitons formed in the polymer phase.
Fig. 1.11. Energy-level alignment between ZnO and (Zn,Mg)0 as determined by optical spectroscopy [100]. The energy-level alignment agrees with a recent indirect determination using photoelectron spectroscopy [105]. The difference of the band gaps is almost fully accomplished by a conduction band offset... Fig. 1.11. Energy-level alignment between ZnO and (Zn,Mg)0 as determined by optical spectroscopy [100]. The energy-level alignment agrees with a recent indirect determination using photoelectron spectroscopy [105]. The difference of the band gaps is almost fully accomplished by a conduction band offset...
Ohno TR, Chen Y, Harvey SE, Kroll GH, Weaver JH, Haufler RE, Smalley RE (1991) C60 Bonding and Energy-Level Alignment on Metal and Semiconductor Surfaces, Phys Rev B 44(24) 13747-13755... [Pg.560]

Greczynski G, Kugler T, Salaneck WR (2000) Energy level alignment in organic-based three-layer structures studied by photoelectron spectroscopy. J Appl Phys... [Pg.72]

Yokoyama T, Yoshimura D, Ito E, Ishii H, Ouchi Y, Seki K (2003) Energy level alignment at Alq3/LiF/Al interfaces studied by electron spectroscopies island growth of LiF and size-dependence of the electronic structures. Jpn J Appl Phys 42 3666... [Pg.73]

Koch N, Kahn A, Ghijsen J, Pireaux J-J, Schwartz J, Johnson RL, Elschner A (2003) Conjugated organic molecules on metal versus polymer electrodes demonstration of a key energy level alignment mechanism. Appl Phys Lett 82 70 Cahen D, Kahn A (2003) Electron energetics at surfaces and interfaces concepts and... [Pg.74]

Veenstra SC, Jonkman HT (2003) Energy-level alignment at metal-organic and organic-organic interfaces. J Polym Sci Polym Phys 41 2549... [Pg.74]

K. Yamashita, The Electronic-Structure and Energy-Level Alignment of Porphyrin/Metal Interfaces Studied by Ultraviolet Photoelectron- Spectroscopy, Appl. Phys. Lett. 67(13), 1899-1901 (1995). [Pg.229]

FIGURE 2.2.16 Actual energy level alignment in the Au-pentacene junction as determined by UV photoelectron spectroscopy. (Adapted from [45].)... [Pg.94]


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Energy Level Alignment at the Interface

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