Drinking water pesticides

U.S. EPA, Drinking Water Health Mdvisoy Pesticides, Lewis Pub., Chelsea, Mich., 1989. 

Drinking Water Health Advisories for Pesticides, Office of Drinking Water, U.S. Environmental Protection Agency, Lewis Pubhshets, Chelsea, Mich., 1989. Includes data used for evaluating 1-day, 10-day, and longer-term health advisories for 50 pesticides which have a potential for being found in drinking water, with specific references as sources of information. 

P. A. Fenner-Crisp, "Risk Assessment Methods for Pesticides in Food and Drinking Water," Office of Pesticide Programs, U.S. Environmental Protection Agency, presented at the Florida Pesticide Review Council Meeting, July 7, 1989. 

In 1980 the Drinking Water Directive was introduced, which specified a maximum limit of 0.1 /rgU for any pesticide in drinking water and 0.5 /rgU for total pesticides. Monitoring was needed for a wide range of pesticides in water and this became the impetus for developing new analytical techniques capable of detecting pesticides at very low levels. Consequently, analytical techniques improved and more pesticides were detected in watercourses and water supplies. 

Atrazine and simazine arose principally as a result of their use in amenity situations but, since their ban for non-agriciiltiiral purposes, concentrations are generally declining. Fiowever, atrazine and simazine still have some agricultural uses (atrazine on maize and simazine on a wide range of crops), so the risk of pollution still exists when these pesticides are applied in either groundwater or surface water drinking water supply catchments. 

Limited to residents in BRA s weatherization program Adopted OSHA standards Indoor air exposures considered in determining drinking water levels Restricts use and sales of pesticides which may cause indoor air pollution Bans on use of some potential indoor pollutants in consumer products Restricts smoking in specified indoor environments Restricts use of asl estos in VA buildings... 

Of major concern are the health and environmental impacts of the abundant chlorinated and brominated hydrocarbons (ref. 2). These materials have numerous industrial applications as pesticides, solvents, propellants, refrigerants, plastics, fire retardants and extinguishers, disinfectants for drinking water, pharmaceuticals and electronic chemicals. Many chemical manufacturers utilize chlorinated and brominated organics as intermediates. It is estimated, for instance, that almost 85 % of the pharmaceuticals produced in the world require chlorine at some stage of synthesis. 

Le Bel GL, Williams DT, Griffith G, et al. 1979. Isolation and concentration of organophosphorus pesticides from drinking water at the ng/L level, using macroreticular resin. J AOAC 62 241-249. 

With the acceptable concentrations of herbicides in drinking water being taken to very low levels by some regulatory authorities (e.g., the EC), there has been interest in very low levels of atrazine present in some samples of groundwater and in drinking water. This finding illustrates the point that mobility of pesticides becomes increasingly evident as sensitivity of analysis improves. 

Because of the great importance of drinking water for human health, quality standards for pesticides in water were developed at Community level based on the precautionary principle. Toxicological considerations were not taken into account to derive the general limit for pesticides. 

Crescenzi et al. developed a multi-residue method for pesticides including propanil in drinking water, river water and groundwater based on SPE and LC/MS detection. The recoveries of the pesticides by this method were >80%. Santos etal. developed an on-line SPE method followed by LC/PAD and LC/MS detection in a simultaneous method for anilides and two degradation products (4-chloro-2-methylphenol and 2,4-dichlorophenol) of acidic herbicides in estuarine water samples. To determine the major degradation product of propanil, 3,4-dichloroaniline, the positive ion mode is needed for atmospheric pressure chemical ionization mass spectrometry (APCI/MS) detection. The LOD of 3,4-dichloroaniline by APCI/MS was 0.1-0.02 ng mL for 50-mL water samples. 

M. Fielding, D. Barcelo, A. Helweg, S. Galassi, L. Torstenson, P. van Zoonen, R. Wolter, and G. Angeletti, in Pesticides in Ground and Drinking Water (Water Pollution Research Report 27), Commission of the European Communities, Bmssels, pp. 1-136 (1992). 

The emphasis that the FQPA placed on the assessment of pesticide residues in drinking water, for example, led to the collection and analysis of data on the effects of drinking water treatment processes on pesticide residues. These data were presented to the FIFRA Science Advisory Board to highlight the variability in the effects of treatment on different kinds of pesticides and the products formed and the variability of treatment processes employed at different locations and at different collection time intervals at an individual location. These complexities led to the current proposal... 

Preliminary Literature Review of the Impacts of Water Treatment on Pesticide Removal and Transformations in Drinking Water, in Progress Report on Estimating Pesticide Concentrations in Drinking Water and Assessing Water Treatment Effects on Pesticide Removal and Transformation a Consultation, Session VI. USEPA, Washington, DC (2000). Also available on the World Wide Web http //www.epa.gov/scipoly/sap 000/index.htm, accessed September 2002. 

ILSl, A Framework for Estimating Pesticide Concentrations in Drinking Water for Aggregate Exposure Assessments, Workshop Report 5/19/99. International Life Sciences Institute, Washington, DC (1999). 

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