Design temperature, pressure

The impact of materia) choice on style and configuration is secondary to design temperature, pressure, flow rates and required effectiveness. The material fabrication factors and material properties will drive thickness and weight. 

The following data for a 2 factorial design were collected during a study of the effect of temperature, pressure, and residence time on the %yield of a reaction. " ... 

PVDE is manufactured using radical initiated batch polymerization processes in aqueous emulsion or suspension operating pressures may range from 1 to 20 MPa (10—200 atm) and temperatures from 10 to 130°C. Polymerization method, temperature, pressure, recipe ingredients, the manner in which they are added to the reactor, the reactor design, and post-reactor processing are variables that influence product characteristics and quaUty. 

Analysis of a method of maximizing the usefiilness of smaH pilot units in achieving similitude is described in Reference 67. The pilot unit should be designed to produce fully developed large bubbles or slugs as rapidly as possible above the inlet. UsuaHy, the basic reaction conditions of feed composition, temperature, pressure, and catalyst activity are kept constant. Constant catalyst activity usuaHy requires use of the same particle size distribution and therefore constant minimum fluidization velocity which is usuaHy much less than the superficial gas velocity. Mass transport from the bubble by diffusion may be less than by convective exchange between the bubble and the surrounding emulsion phase. 

The quantity of catalyst used for a given plant capacity is related to the Hquid hourly space velocity (LHSV), ie, the volume of Hquid hydrocarbon feed per hour per volume of catalyst. To determine the optimal LHSV for a given design, several factors are considered ethylene conversion, styrene selectivity, temperature, pressure, pressure drop, SHR, and catalyst life and cost. In most cases, the LHSV is ia the range of 0.4—0.5 h/L. It corresponds to a large quantity of catalyst, approximately 120 m or 120—160 t depending on the density of the catalyst, for a plant of 300,000 t/yr capacity. 

The proper design of distillation and absorption columns depends on knowledge of vapor—Hquid equiHbrium, as do flash calculations used to determine the physical state of streams at given conditions of temperature, pressure, and composition. Detailed treatments of vapor—Hquid equiHbria are available (6,7). 

Catalyst Activity. Of utmost importance in the design of most catalysts is activity, which is a measure of the ability of a catalyst to effect conversion of the reactant(s) to the desired product(s) under specified conditions. In industrial applications, catalyst activity is usually discussed in terms of the percent conversion of a reactant under given conditions of temperature, pressure, and contact time. 

When acetylene is recovered, absorption—desorption towers are used. In the first tower, acetylene is absorbed in acetone, dimethylformarnide, or methylpyroUidinone (66,67). In the second tower, absorbed ethylene and ethane are rejected. In the third tower, acetylene is desorbed. Since acetylene decomposition can result at certain conditions of temperature, pressure, and composition, for safety reasons, the design of this unit is critical. The handling of pure acetylene streams requires specific design considerations such as the use of flame arrestors. 

While process design and equipment specification are usually performed prior to the implementation of the process, optimization of operating conditions is carried out monthly, weekly, daily, hourly, or even eveiy minute. Optimization of plant operations determines the set points for each unit at the temperatures, pressures, and flow rates that are the best in some sense. For example, the selection of the percentage of excess air in a process heater is quite critical and involves a balance on the fuel-air ratio to assure complete combustion and at the same time make the maximum use of the Heating potential of the fuel. Typical day-to-day optimization in a plant minimizes steam consumption or cooling water consumption, optimizes the reflux ratio in a distillation column, or allocates raw materials on an economic basis [Latour, Hydro Proc., 58(6), 73, 1979, and Hydro. Proc., 58(7), 219, 1979]. 

Design Conditions Definitions of the temperatures, pressures, and various forces applicable to the design of piping systems are as follows ... 

Design Temperature The design temperature is the material temperature representing the most severe condition of coincident pressure and temperature. For uninsulated metallic pipe with fluid below 38°C (100°F), the metal temperature is taken as the fluid temperature. 

Impact testing is not required if the design temperature is helow —29 C (—20 F) hut at or above —46 C (—50 F) and the maximum operating pressure of the fabricated or assembled components will not exceed 25 percent of the maximum allowable design pressure at ambient temperature and the combined longitudinal stress due to pressure, deadweight, and displacement strain (see Par. 319.2.1) does not exceed 41 MPa (6000 Ibfiin ). 

For a design temperature above the test temperature, the minimum test pressure shall be as calculated by the following formula ... 

Subsection A This subsection contains the general requirements applicable to all materials and methods of construction. Design temperature and pressure are defined here, and the loadings to be considered in design are specified. For stress failure and yielding, this section of the code uses the maximum-stress theory of failure as its criterion. 

When no chemical reactions are involved in the absorption of more than one soluble component from an insoluble gas, the design conditions (pressure, temperature, and liqnid-to-gas ratio) normally are determined by the volatility or the physical sohibility of the least soluble component for which complete recovery is economical. Components of lower volatihty (higher solubility) also will be recovered completely. 

Solenoid magnetic separators are designed for batch-type, cyclic, and continuous operation. Devices which can use matrices of expanded metal, grooved plates, steel balls, or filamentaiy metals have been designed. Continuous separators with capacities to 600 t/h for iron ores (similar to the Brazilian hematite) are commercially available (Sala International Inc.). Selection of the method of operation is apphcation-dependent, being based on variables such as temperature, pressure, volume of magnetics in the feed, etc. 

The effect of different pai ameters such as temperature, pressure, modifier volume, dynamic and static extraction time on the SFE of the plant were investigated. The orthogonal array experimental design method was chosen to determine experimental plan, (5 ). In this design the effect of five parameters and each at five levels were investigated on the extraction efficiency and selectivity [4]. 

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